File name: Pandora103s1_Downsview_20180817_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013205.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180817_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180817T103051.0Z 6803.438090 365 1 32.01 2 89.75 71.59 147.78 1.52 0.00 1 0.00 1 0 29 1.686e-01 1.483e-01 1.502e-01 1.394e-01 2.977396e+04 1.120950e+04 4.987810e+02 -6.000000e+00 8.904967e+03 287.32 -2.00 20.00 -2.00 505.10 0.00e+00 5.148584e-03 3.801528e-03 4.788899e-04 -6.000000e+00 4.667126e-03 287.32 -2.00 20.00 -2.00 499.69 0.00e+00 -1.712640e+00 2.868739e+00 2.889435e-01 -6.000000e+00 3.231988e+00 231.75 -2.00 3.57 -2.00 501.31 0.00e+00 19.964 0.155 489.00 513.00 1 1.0638e+01 2.2091e-01 4.3239e-02 -6.0000e+00 2.4741e-01 2.2206e-01 5.7105e-02 5.1889e-03 -6.0000e+00 6.5241e-02 2.8231e-06 -2.1381e-02 8.8691e-03 1.0152e-04 -6.0000e+00 1.3094e-02 -7.2348e-03 3.3968e-05 12 8 8 10 0 0 -5.76 14.99 12.28 -0.00723 -0.15554 8 1 1 4 0 4000.000 22.19 14.99 19.32 900000 6870 -5488 -5869 15043 -12020 47824 -6767 21977 -2160 22692 -5749 11505 -11695 34280 -13212 -1838 -13667 3320 -8470 2674 1603 2904 -8923 15659 2250 -16815 13830 1406 18105 -13887 16617 -14584 3821 -9119 -6237 -11654 10900 10578 -11198 7442 27249 33888 5622 1592 16325 10418 -7078 29028 1794 23771 -9131 -4848 3847 15796 -14613 7891 -6197 11192 -8189 4670 12046 -12369 -4513 -7282 34907 8706 4748 6320 -5518 -6725 14678 4597 30103 -28111 1994 -15457 6962 -24758 -1819 -21078 26159 10802 20429 -1507 1947 -23084 32371 10568 15441 2480 24236 3713 -11872 -11541 -9349 21070 -15823 -8091 -21500 21599 -4913 15522 -5316 2350 -1869 24841 -19210 27531 41606 18061 19022 -11903 -12849 -2886 12555 9693 1455 18611 15621 -18987 -3985 11726 21579 -2714 43174 1985 42628 -3927 -1613 11933 37362 13204 -4851 36024 -795 -5361 27658 1804 11241 3486 -8514 7777 -11912 -5811 -29832 -16299 -4626 27051 8079 23739 900000 6627 -5960 -6565 14317 -15368 35036 -8538 21349 -2657 21757 -7090 11788 -14759 27251 -16339 -2021 -16905 3536 -10413 3023 1833 3259 -11202 15486 2551 -23088 14105 1608 17419 -17495 14918 -17462 3861 -10730 -7484 -15117 11274 10792 -13905 7625 22937 26975 5941 1774 16017 10942 -8805 25265 2000 21048 -10779 -5308 3784 13711 -17321 7829 -7287 11340 -10013 5011 11971 -15615 -5323 -8853 28189 8923 4950 6363 -6158 -7495 13076 4477 23062 -38136 2059 -18979 6747 -31633 -1823 -25120 19583 9357 16210 -1482 1876 -28806 23755 9461 12939 2307 18190 3425 -12975 -12652 -9710 15402 -15500 -6992 -20653 13547 -3894 10126 -4383 1927 -1720 18507 -22084 19974 25866 14008 14894 -12770 -13927 -2819 10481 8252 1355 15179 13440 -22699 -4014 9771 15758 -2469 25614 1762 25684 -3712 -1481 9568 23520 10227 -4329 21607 -680 -4828 18643 1581 9019 3054 -8525 6726 -12504 -5737 -36778 -17463 -4372 18484 6467 16153 SO 20180817T103508.0Z 6803.441065 369 1 32.01 2 89.02 72.33 147.76 3.40 0.00 1 0.00 1 0 22 1.080e-01 1.010e-01 9.778e-02 9.358e-02 2.038540e+04 7.267837e+03 1.408182e+03 -6.000000e+00 5.693091e+03 287.32 -2.00 20.00 -2.00 505.21 0.00e+00 -4.273513e-04 2.503750e-03 4.923284e-05 -6.000000e+00 2.992007e-03 287.32 -2.00 20.00 -2.00 499.63 0.00e+00 -2.176470e-01 1.901328e+00 6.214729e-02 -6.000000e+00 2.094584e+00 231.75 -2.00 3.57 -2.00 501.30 0.00e+00 18.565 0.125 489.00 513.00 1 1.0414e+01 1.4408e-01 3.1887e-02 -6.0000e+00 1.5989e-01 1.7911e-01 3.8521e-02 2.6663e-03 -6.0000e+00 4.2913e-02 4.2932e-06 -2.9069e-03 6.3441e-03 9.4746e-05 -6.0000e+00 8.4332e-03 5.7053e-01 -4.4232e-03 12 9 8 11 256 0 9.27 15.00 7.80 0.57053 0.55037 8 1 1 4 0 4000.000 22.29 15.00 19.33 900000 -8236 4397 -8805 423 -11511 16751 -2521 4285 9108 20444 2004 -6273 -2706 636 -814 17370 -3875 890 -618 -3709 4944 -12162 15406 -8686 7870 -9997 628 -6331 -1718 -217 5607 -1210 -3252 4936 17522 -6130 3670 2603 5720 7333 -8354 17875 22218 -2538 -3539 364 -1388 -15368 -7958 12532 -10807 7077 -8341 1829 -6300 -4420 2497 11334 -8402 -2036 12711 -1733 -3857 -12224 27985 -9637 11053 2446 -693 -6153 7060 -6603 8072 2716 11993 9773 1088 -8591 6967 15092 3270 9268 2025 -2003 754 18971 350 23617 9982 9556 1065 -8082 -2653 16329 -8294 7817 -5591 12612 15619 -17893 12038 8808 -13067 16091 2789 19696 -8173 -13712 9475 -16126 2006 1409 -23433 -2414 8695 -15209 23109 9722 13164 -9968 914 22442 2586 2975 -6886 2641 -14355 3429 -596 -16050 -7962 9782 14203 -990 17645 16150 -23801 26236 -3656 10676 -10345 12382 -1838 10091 -5291 -3171 -5995 18073 10895 -98 900000 -8942 4289 -10109 461 -14440 16272 -3013 4850 9833 19482 2240 -7511 -3077 689 -885 15822 -4387 987 -720 -4513 5523 -16002 15480 -11022 8565 -12932 728 -7809 -1980 -236 5580 -1286 -3580 5223 17125 -7604 4075 2877 6041 7522 -9926 16569 19900 -2921 -4156 414 -1593 -19918 -9439 11905 -12428 6619 -8870 1755 -6728 -4819 2617 11031 -9861 -2227 11992 -1890 -4317 -14844 22891 -11154 10247 2423 -701 -6466 6421 -6837 7316 2630 10810 8998 1063 -8962 6142 12180 2943 7915 1869 -1934 721 15449 342 18300 8711 8288 1002 -8385 -2657 13613 -8484 6507 -5041 9158 10781 -16784 8336 6355 -12120 12046 2538 15724 -8558 -14911 8055 -17459 1850 1325 -28045 -2343 7522 -16481 17474 8580 11417 -10715 862 16630 2249 2560 -6595 2317 -14833 2986 -536 -16676 -7668 7771 10512 -842 12518 11724 -26152 18148 -3400 8767 -10581 10255 -1757 8610 -5220 -3046 -5854 13694 8621 -85 SO 20180817T103922.0Z 6803.444005 373 1 32.01 2 88.29 73.06 147.72 5.26 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