File name: Pandora103s1_Downsview_20180818_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013311.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180818_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180818 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180818T103158.0Z 6804.438866 366 1 32.01 2 89.75 72.05 150.01 339.87 0.00 1 0.00 1 0 15 6.859e-02 6.415e-02 6.277e-02 6.084e-02 9.581292e+03 4.250528e+03 5.902685e+02 -6.000000e+00 3.621107e+03 287.24 -2.00 20.00 -2.00 505.16 0.00e+00 2.014198e-03 1.650389e-03 1.162409e-04 -6.000000e+00 1.897979e-03 287.24 -2.00 20.00 -2.00 499.67 0.00e+00 2.305686e+00 1.235243e+00 7.039511e-02 -6.000000e+00 1.315568e+00 231.66 -2.00 3.57 -2.00 501.33 0.00e+00 19.966 0.155 489.00 513.00 1 9.5771e+00 9.4601e-02 3.5997e-02 -6.0000e+00 1.0069e-01 1.6286e-01 2.4614e-02 2.4799e-03 -6.0000e+00 2.6572e-02 6.7127e-06 -4.6575e-03 4.4498e-03 5.7809e-05 -6.0000e+00 5.3284e-03 -1.2933e-02 2.2806e-05 12 8 8 10 0 0 13.51 15.00 5.65 -0.01293 -0.04524 8 1 1 4 0 4000.000 22.29 15.00 19.33 900000 5417 -5552 -4265 -1577 -7695 9402 4332 -1551 -150 -2508 1964 4944 -2169 -1837 -4035 -2760 1461 -1843 811 -1237 777 4584 -1420 -1938 4478 -6668 330 5114 1449 3784 1360 -1515 479 6985 1370 626 945 2921 -3395 61 7059 4980 1797 7742 -703 683 -3249 -3432 -8558 -2559 -11112 -1858 -1039 10772 4738 -2000 1545 2151 -9957 9032 -405 -1411 4775 3498 4781 2793 18587 -1206 -8181 -11081 2138 -6287 5804 -5 12987 8029 -5613 -7213 -5030 4111 -1895 1940 -2549 5988 -11613 8345 3786 13617 -5874 7951 -14473 3561 -398 10773 -969 -991 -12429 7159 14260 -1070 9088 -19130 -1489 6771 3003 -9922 8731 1362 7571 -13480 7916 -1078 806 -4461 12473 -4482 3524 -3848 -1547 -2736 14505 2334 -3539 8890 16912 8690 13880 1757 -2131 -3645 -1540 7939 8300 -9582 -10757 4556 9853 -242 2742 1359 -6501 1427 -9178 -4188 -1369 13552 -6122 11238 -1130 -11390 900000 5168 -6028 -4761 -1779 -9394 9914 4891 -1867 -177 -2967 2187 5281 -2436 -2026 -4517 -3061 1580 -2122 936 -1463 898 5098 -1671 -2303 5035 -8334 384 5613 1591 3880 1405 -1621 516 7392 1577 722 1067 3188 -3882 67 7236 5260 1979 8149 -811 776 -3797 -3951 -10161 -2781 -12650 -1881 -1031 9644 4670 -2177 1655 2296 -11857 8866 -436 -1545 4926 3639 4847 2825 15792 -1226 -8788 -11997 2014 -6459 5358 -5 11454 7297 -5650 -7225 -4880 3625 -1777 1766 -2427 5291 -12347 7336 3461 11209 -5796 6846 -15589 3277 -386 9265 -905 -895 -12128 5610 10188 -868 6668 -18902 -1301 5768 2721 -10148 7319 1199 6226 -13801 6708 -1008 745 -4344 10288 -4383 3237 -3829 -1488 -2606 11405 2017 -3226 7276 12869 7157 10880 1539 -1934 -3372 -1375 6294 6466 -8815 -10032 3757 7918 -217 2417 1229 -6374 1300 -9311 -4053 -1286 10890 -5806 8729 -972 -10870 SO 20180818T103619.0Z 6804.441887 370 1 32.01 2 89.00 72.80 150.27 341.82 0.00 1 0.00 1 0 43 4.819e-02 4.715e-02 4.009e-02 3.911e-02 1.330509e+04 2.864984e+03 4.658292e+02 -6.000000e+00 2.544261e+03 287.24 -2.00 20.00 -2.00 505.19 0.00e+00 7.677935e-04 1.054467e-03 1.002082e-04 -6.000000e+00 1.333173e-03 287.24 -2.00 20.00 -2.00 499.70 0.00e+00 1.564036e+00 7.893966e-01 1.398770e-01 -6.000000e+00 9.209442e-01 231.66 -2.00 3.57 -2.00 501.36 0.00e+00 18.535 0.124 489.00 513.00 1 9.3902e+00 6.0406e-02 3.3175e-02 -6.0000e+00 7.0554e-02 1.5313e-01 1.5530e-02 3.0602e-03 -6.0000e+00 1.8495e-02 1.0585e-05 -5.4696e-03 2.7546e-03 4.4133e-05 -6.0000e+00 3.7355e-03 -2.3003e-02 1.8077e-04 12 8 8 10 0 0 -6.47 15.00 2.93 -0.02300 -0.06094 8 1 1 4 0 4000.000 22.29 15.00 19.34 -5695 -954 -3750 1422 -3341 -5430 -4541 3605 3357 4950 -2039 -703 -1339 2073 -2853 1773 -3133 -1878 5559 45 2781 -2091 -1622 -9591 8878 1283 6648 2793 5919 -2613 -3714 3032 3798 962 3095 9626 -1393 -461 -2445 1976 -3477 3492 -7482 8055 -2562 6394 -253 7771 -1751 6184 -3317 -1211 1826 -2425 -10128 -3786 2436 2169 -590 -264 6925 -148 7138 -3942 -2441 -2462 -270 -3264 7924 -438 8141 -633 -4475 -9571 -587 -787 8064 -435 -301 -2562 -1923 -1671 5274 5218 -3933 11425 1414 -122 -7476 -1349 -5927 3804 -868 -2980 940 -8640 -3798 4270 5636 -177 -1798 4066 -708 -7103 8483 607 -7998 -755 8423 -3663 509 2505 8153 -1829 860 -6694 7349 -597 7813 -221 2282 4081 1740 4502 3039 2598 5220 2951 2310 -2585 -6391 6066 -3110 8931 6660 10317 -3132 -3436 -1985 608 -4610 8356 -4264 -3360 -6821 -2968 7158 -8000 -3082 -6921 3928 -6011 -960 -3971 1491 -3802 -6426 -5437 4064 3818 5509 -2382 -797 -1509 2219 -3156 1864 -3471 -2092 5944 52 3153 -2480 -1912 -12190 9470 1483 7263 3152 6409 -2964 -4072 3073 3850 1030 3401 10201 -1633 -526 -2803 2136 -3930 3694 -8883 8307 -2965 6834 -288 8093 -1968 6310 -3598 -1240 1769 -2419 -11047 -4036 2527 2295 -642 -284 6891 -158 7148 -4400 -2674 -2662 -279 -3409 7331 -434 7279 -612 -4513 -10260 -587 -794 7320 -416 -282 -2427 -1798 -1564 4650 4619 -3848 9774 1339 -117 -7604 -1281 -5873 3452 -839 -2971 885 -8593 -3463 3466 4394 -143 -1448 3100 -582 -6570 7163 570 -8145 -705 7033 -3415 463 2270 7044 -1744 797 -6657 6420 -574 7002 -212 2087 3569 1516 3802 2637 2274 4451 2575 2013 -2359 -6073 5014 -2735 6910 5241 7882 -2805 -3160 -1818 550 -4450 7152 -4146 -3252 -6825 -2850 6154 -7779 -2775 -6370 3270 SO 20180818T104033.0Z 6804.444826 374 1 32.01 2 88.27 73.53 150.49 343.74 0.00 1 0.00 1 0 15 3.196e-02 3.136e-02 2.824e-02 2.767e-02 8.701174e+03 1.914609e+03 5.378450e+02 -6.000000e+00 1.687161e+03 287.24 -2.00 20.00 -2.00 505.21 0.00e+00 1.375339e-03 7.486817e-04 7.729666e-05 -6.000000e+00 8.843798e-04 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