File name: Pandora103s1_Downsview_20180820_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013252.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180820_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180820 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180820T103412.0Z 6806.440417 370 1 32.01 2 89.75 72.98 143.82 300.79 0.00 1 0.00 1 0 15 4.903e-02 4.839e-02 4.348e-02 4.285e-02 6.850107e+03 2.800211e+03 5.979708e+02 -6.000000e+00 2.586708e+03 287.07 -2.00 20.00 -2.00 505.25 0.00e+00 2.954725e-03 1.156282e-03 1.605963e-04 -6.000000e+00 1.355833e-03 287.07 -2.00 20.00 -2.00 500.01 0.00e+00 1.883398e+00 8.430822e-01 2.888736e-02 -6.000000e+00 9.369674e-01 231.47 -2.00 3.57 -2.00 501.64 0.00e+00 19.970 0.155 489.00 513.00 1 9.2360e+00 6.4637e-02 3.5731e-02 -6.0000e+00 7.1777e-02 1.3202e-01 1.6770e-02 2.0929e-03 -6.0000e+00 1.8819e-02 9.6624e-06 2.1001e-03 3.1613e-03 6.0983e-05 -6.0000e+00 3.8005e-03 -2.4723e-02 1.7977e-04 12 8 8 10 0 0 -4.11 15.00 4.60 -0.02472 -0.01016 8 1 1 4 0 4000.000 22.19 15.00 19.31 1130 -4222 -1094 4665 9973 8201 -4170 -32 -2878 1939 -8508 6382 3424 879 3825 4216 -528 -810 -1313 1483 -2985 974 4487 5504 -1310 1041 434 -1568 -2151 3195 -2853 -2587 -5128 -8689 8338 642 2179 -2312 -1454 -7884 3975 -9699 3938 -3208 8106 -1374 2260 1936 3885 3206 3312 -7007 836 5927 -4858 1051 -602 1313 -2638 7428 1815 -2447 4105 -4798 -992 6188 6190 -4346 -5959 255 1249 -2927 -806 1975 -6708 -6517 1101 -8856 2044 4831 3660 -9484 5277 -1347 -253 123 6097 -3007 10483 -2630 2369 3371 -7665 6265 2953 366 9168 197 42 -11054 -8709 3511 7671 -4737 -1564 8428 503 -6765 -9094 10037 1230 4812 2705 -1342 183 2360 5983 -1965 -1343 -995 2764 -1929 -432 -3249 5129 -12435 9965 922 10035 -1702 4951 -3791 1828 -7545 -3786 3659 -1801 -707 -552 -4303 9654 3460 5592 1099 5571 -1069 1390 -4645 287 289 20 1067 -4244 -1103 4642 9694 8256 -4840 -37 -3347 2123 -10097 6465 3516 909 3801 4167 -551 -867 -1461 1636 -3428 1076 4779 5813 -1491 1163 486 -1780 -2408 3245 -2970 -2683 -5531 -10092 8571 720 2373 -2589 -1593 -9079 4073 -11430 4116 -3641 8353 -1561 2468 2093 4053 3291 3281 -7434 806 5433 -5084 1081 -647 1400 -2914 7379 1897 -2683 4248 -5408 -1070 6113 5987 -4579 -6313 250 1192 -2908 -791 1915 -7189 -6944 1061 -9159 1878 4286 3279 -9740 4715 -1288 -242 119 5541 -2967 8997 -2556 2199 3139 -8123 5835 2788 344 7700 175 37 -10418 -7906 2858 6202 -4555 -1516 7448 473 -6693 -9048 8338 1137 4371 2538 -1319 177 2247 5557 -1993 -1350 -979 2566 -1833 -399 -3115 4584 -13185 8507 858 8492 -1622 4412 -3591 1605 -7178 -3450 3144 -1682 -666 -524 -4292 8464 3227 5134 1059 5145 -1047 1305 -4479 257 257 18 SO 20180820T103829.0Z 6806.443391 374 1 32.01 2 89.01 73.72 144.45 302.03 0.00 1 0.00 1 0 22 3.551e-02 3.525e-02 3.168e-02 3.117e-02 8.357821e+03 2.139526e+03 6.841426e+02 -6.000000e+00 1.873389e+03 287.07 -2.00 20.00 -2.00 505.26 0.00e+00 2.943030e-03 8.445704e-04 1.718105e-04 -6.000000e+00 9.821593e-04 287.07 -2.00 20.00 -2.00 499.97 0.00e+00 2.486409e+00 6.235790e-01 3.755172e-02 -6.000000e+00 6.809704e-01 231.47 -2.00 3.57 -2.00 501.61 0.00e+00 18.555 0.124 489.00 513.00 1 9.0615e+00 4.7591e-02 3.1746e-02 -6.0000e+00 5.2119e-02 1.1452e-01 1.2422e-02 1.9947e-03 -6.0000e+00 1.3753e-02 1.3396e-05 -2.5318e-03 2.3003e-03 6.9922e-05 -6.0000e+00 2.7584e-03 -2.0748e-02 7.0590e-05 12 8 8 10 0 0 -12.57 15.00 2.32 -0.02075 -0.03831 8 1 1 4 0 4000.000 22.19 15.00 19.31 900000 4706 -5857 7442 -3417 1469 1440 -572 739 2864 -8686 -469 3851 528 3052 -4017 313 1875 3233 -565 1669 1691 -2091 -4551 5496 -1994 4726 -3891 2719 -5515 4208 379 1005 -2440 1816 -2713 2956 1037 3573 -1473 1972 3486 2193 -2607 -2041 -477 734 2425 -6499 1730 -4094 -5039 -4894 -424 -2106 2948 -1653 -156 -2257 1277 -1605 -384 1045 -879 -3886 -1795 5703 3251 1417 3879 -318 1937 6271 -1284 6977 90 4217 -2186 2914 3185 3088 2883 966 -1839 -6549 -608 694 864 2264 -2503 -4321 -3292 -2151 8084 1799 -2816 1408 8389 -3372 2975 -4735 6697 4793 273 -12771 1764 132 3608 -1024 353 4290 -5565 2659 -616 709 7678 930 -5209 1648 1037 137 -3272 322 -4689 956 2820 469 -426 -468 -2262 -1683 -1648 -1784 -3562 -3299 -543 -778 1516 -2332 6450 -4359 -109 -153 5967 -217 3038 831 6327 -3873 2700 -396 900000 4337 -6140 7149 -3780 1580 1582 -652 837 3152 -10475 -513 3993 556 3088 -4332 325 1953 3430 -638 1849 1869 -2395 -5336 5882 -2313 5121 -4566 2958 -6258 4158 385 1022 -2643 1978 -3167 3242 1139 3776 -1611 2074 3628 2337 -2947 -2326 -540 821 2639 -7591 1831 -4444 -5330 -5041 -414 -2126 2947 -1787 -169 -2499 1355 -1739 -412 1115 -956 -4332 -1933 5590 3199 1402 3701 -310 1831 5718 -1275 6502 90 3977 -2130 2653 2866 2766 2600 894 -1751 -6587 -585 661 817 2094 -2407 -4227 -3214 -2119 7311 1708 -2716 1264 6815 -2987 2418 -4063 5144 3847 241 -13441 1642 124 3215 -935 316 3771 -5491 2453 -591 674 6820 889 -5363 1596 996 130 -3138 292 -4470 875 2546 433 -397 -434 -2136 -1587 -1527 -1613 -3237 -2968 -478 -706 1377 -2225 5723 -4345 -105 -148 5447 -211 2854 787 5530 -3624 2335 -355 SO 20180820T104242.0Z 6806.446320 378 1 32.01 2 88.28 74.44 145.07 303.29 0.00 1 0.00 1 0 22 2.160e-02 2.144e-02 2.092e-02 2.065e-02 1.176191e+04 1.455843e+03 7.822581e+02 -6.000000e+00 1.139373e+03 287.07 -2.00 20.00 -2.00 505.28 0.00e+00 1.836254e-03 5.593094e-04 9.467328e-05 -6.000000e+00 5.973919e-04 287.07 -2.00 20.00 -2.00 500.05 0.00e+00 1.701887e+00 4.097253e-01 6.991271e-02 -6.000000e+00 4.140979e-01 231.47 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