File name: Pandora103s1_Downsview_20180822_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013251.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180822_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180822T103625.0Z 6808.441956 331 1 32.01 2 89.75 73.92 129.30 277.90 0.00 1 0.00 1 0 15 1.697e-01 1.505e-01 1.360e-01 1.271e-01 8.548632e+03 8.686839e+03 2.657329e+02 -6.000000e+00 8.946340e+03 286.90 -2.00 20.00 -2.00 505.17 0.00e+00 1.055986e-02 3.517318e-03 6.094156e-04 -6.000000e+00 4.695533e-03 286.90 -2.00 20.00 -2.00 499.77 0.00e+00 1.703209e-01 2.579648e+00 2.141582e-01 -6.000000e+00 3.267117e+00 231.29 -2.00 3.57 -2.00 501.42 0.00e+00 19.979 0.155 489.00 513.00 1 1.0355e+01 1.9867e-01 4.1423e-02 -6.0000e+00 2.4986e-01 2.0190e-01 5.1115e-02 3.5238e-03 -6.0000e+00 6.6230e-02 3.1081e-06 1.5190e-02 9.4849e-03 1.6068e-04 -6.0000e+00 1.3230e-02 -2.3299e-02 -1.5638e-04 12 8 8 10 0 0 -9.34 15.00 11.41 -0.02330 0.08206 8 1 1 4 0 4000.000 22.09 15.00 19.18 900000 31074 -23039 29626 -9741 2034 -9826 -1230 -881 -6729 -6215 -3458 15261 11167 6854 1266 15386 -5627 -1606 -17465 10357 -995 13602 -10474 11448 -10627 14384 -23288 21600 264 15273 4212 876 42351 -13848 5837 -1519 13595 673 3826 1107 -4801 20431 -811 11085 5402 -5889 31186 -1083 3661 -11836 -2637 -13518 -22463 -11725 10711 1647 -543 13788 25266 17828 843 23506 6436 8817 21424 34790 -3825 8269 -9063 17643 -10202 2140 -1356 4523 5263 -6386 -8423 -380 16825 -6126 9687 -19244 13124 -20228 23709 -3636 42265 -25575 5816 -13750 -13971 -6565 10098 -7161 15120 -11085 35512 -13037 -15183 9578 22432 20411 29686 12146 14691 22423 23403 17962 -10716 36275 -13807 35320 9892 11229 -1165 11393 -25878 -725 -13111 16080 17100 5807 44556 -5574 1698 -19142 27057 -12026 17195 10538 -3245 -35657 29146 8558 450 4990 20504 4502 23658 -21909 18127 -9612 -16654 11863 -448 15796 -4130 -13802 -8607 50253 900000 23871 -31016 24988 -12268 2324 -12819 -1484 -1050 -8289 -7436 -3964 14315 10700 6778 1321 14132 -6476 -1824 -23226 10433 -1117 13243 -12955 11595 -13375 14168 -32735 19072 272 13332 4107 901 30579 -17767 6184 -1699 12949 717 3937 1180 -5497 18688 -928 11464 5931 -7178 26227 -1224 3852 -13989 -2780 -15650 -28691 -13982 10685 1833 -621 13696 22338 16962 954 21462 6908 9145 19292 26982 -4241 8067 -10243 15191 -11517 2162 -1436 4568 5202 -6864 -9038 -374 13912 -6313 8615 -22583 11289 -24227 18631 -3686 27218 -31248 5228 -15024 -15629 -7008 9200 -7534 12478 -11430 22723 -12945 -14958 7327 15319 14704 20486 10143 11896 16572 16802 13508 -10822 23942 -15051 24352 8789 9878 -1161 10179 -33375 -726 -14481 13103 13494 5078 27242 -5564 1582 -21851 19711 -12713 13784 8897 -3039 -44764 19386 6902 399 4335 15485 3995 17621 -25329 14226 -9869 -18307 9876 -415 12165 -3719 -13328 -7918 26797 SO 20180822T104041.0Z 6808.444919 335 1 32.01 2 89.01 74.65 130.03 278.71 0.00 1 0.00 1 0 15 7.567e-02 7.322e-02 7.212e-02 7.025e-02 8.559717e+03 4.779757e+03 7.228379e+02 -6.000000e+00 3.989415e+03 286.90 -2.00 20.00 -2.00 505.22 0.00e+00 8.580240e-04 1.894738e-03 2.952343e-05 -6.000000e+00 2.092243e-03 286.90 -2.00 20.00 -2.00 499.86 0.00e+00 2.151032e+00 1.401783e+00 3.019781e-02 -6.000000e+00 1.450111e+00 231.29 -2.00 3.57 -2.00 501.51 0.00e+00 18.563 0.125 489.00 513.00 1 9.9487e+00 1.0718e-01 3.1465e-02 -6.0000e+00 1.1099e-01 1.3184e-01 2.8004e-02 2.0048e-03 -6.0000e+00 2.9270e-02 5.7864e-06 4.8283e-03 5.1122e-03 5.7484e-05 -6.0000e+00 5.8770e-03 -4.2210e-02 2.4173e-04 12 8 8 10 0 0 -7.96 15.00 4.32 -0.04221 -0.00872 8 1 1 4 0 4000.000 22.09 15.00 19.18 900000 7052 -4917 -2074 451 1459 -1932 6864 -4671 7714 -8517 4391 2964 10548 -10103 9364 10751 11814 -6891 6995 5549 -4749 9441 -5131 1257 -2026 13486 7851 6597 -5534 -4539 -14807 10966 -738 126 -866 4881 -16854 -7102 680 -2956 -4556 4137 7875 -3636 143 -1368 6495 1813 -7280 -5706 16214 -2560 -8929 -5945 5792 2214 -1299 -4829 1519 5195 16508 1054 6704 -9138 -7400 12480 -7461 5541 -9809 -1280 -2110 3656 -2683 1407 6096 3468 -8435 6001 3538 3053 -1306 -8008 -2710 20232 441 8523 6180 1850 -7710 -6055 9996 8878 10920 -8361 -4260 -6910 8722 6860 3088 5946 -14638 -5208 15311 -5278 2494 3672 -829 -4880 -5869 7484 -12135 12040 5913 1599 -4342 794 -8097 3929 -11543 2171 -4149 12994 2635 -3374 1774 -18 3573 6293 -1303 13786 2195 8567 1828 -10119 -4524 -11817 -5354 -3365 592 -1781 3075 -206 5112 -8367 22720 1949 13708 5304 10751 -5897 900000 6526 -5287 -2262 493 1607 -2248 7432 -5658 8174 -10355 4655 3137 10185 -11803 9052 10364 11561 -8366 7540 6047 -5720 9884 -6195 1436 -2395 13635 8337 6938 -6253 -4925 -17766 10408 -817 145 -1010 5302 -22248 -8403 737 -3307 -5204 4388 8147 -4256 162 -1561 6765 1942 -8314 -6190 13771 -2557 -9497 -6323 5714 2320 -1420 -5443 1595 5241 15016 1119 6723 -10596 -8284 11273 -8043 5211 -10528 -1244 -2068 3420 -2711 1387 5702 3239 -8611 5260 3152 2730 -1229 -8085 -2610 15829 422 7538 5556 1720 -7842 -6077 8700 7959 9602 -8648 -4100 -6607 6947 5430 2477 4589 -13995 -4725 12058 -5282 2327 3340 -771 -4642 -5666 6472 -12878 10184 5327 1501 -4325 762 -8572 3687 -12359 1988 -3944 10323 2336 -3203 1601 -16 3161 5389 -1207 10980 1906 6860 1549 -9590 -4134 -11941 -5169 -3222 553 -1716 2834 -197 4664 -8701 17373 1787 10880 4454 8526 -5571 SO 20180822T104453.0Z 6808.447836 339 1 32.01 2 88.28 75.38 130.74 279.51 0.00 1 0.00 1 0 15 5.137e-02 4.931e-02 5.367e-02 5.241e-02 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