File name: Pandora103s1_Downsview_20180826_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013307.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180826_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180826 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180826T104053.0Z 6812.445058 248 1 32.01 2 89.75 75.85 92.64 253.93 0.00 1 0.00 1 0 22 5.370e-02 5.285e-02 5.473e-02 5.370e-02 6.806358e+03 3.562737e+03 3.947756e+02 -6.000000e+00 2.827529e+03 286.57 -2.00 20.00 -2.00 505.27 0.00e+00 1.521950e-03 1.441957e-03 1.596435e-04 -6.000000e+00 1.483541e-03 286.57 -2.00 20.00 -2.00 500.00 0.00e+00 4.020212e+00 1.064378e+00 5.805393e-02 -6.000000e+00 1.030270e+00 230.92 -2.00 3.57 -2.00 501.64 0.00e+00 19.989 0.156 489.00 513.00 1 9.3311e+00 8.1249e-02 3.5985e-02 -6.0000e+00 7.8830e-02 8.7800e-02 2.1196e-02 2.2879e-03 -6.0000e+00 2.0823e-02 7.6343e-06 -4.3900e-03 3.9982e-03 4.8758e-05 -6.0000e+00 4.1739e-03 1.0910e-02 -1.7400e-04 12 8 8 10 0 0 0.23 15.00 4.22 0.01091 -0.01954 8 1 1 4 0 4000.000 22.19 15.00 19.31 900000 5205 -2587 3569 7602 2374 -1966 1570 -4527 -2990 3771 -6143 7511 -5191 3821 -6612 6181 -5563 5413 -7976 9322 -174 5848 -1517 2341 3381 4180 555 2838 -4023 7978 -11671 -2100 2061 -5975 -757 3354 -2157 -1457 1615 315 133 3270 6224 -374 -2568 6158 4002 6627 146 -1123 -9275 425 -7273 -13283 6566 5417 -1456 2230 7159 3 -6033 686 -4333 -1448 -9223 -3694 1300 -1708 -4026 1557 832 4973 -2410 4756 4260 11586 4477 6434 6485 1854 -4932 -637 3642 -7103 8385 1071 7636 -7366 7588 -3976 6726 -659 -5514 -8421 7723 -2762 8822 -7642 1061 -38 -6452 2018 3100 8203 -1023 -1048 -1936 -3728 -6765 1172 -7151 -1379 -1238 2714 -2432 -4624 -2837 1709 2039 -1444 6830 12508 -654 4631 1599 8361 7794 -11222 1244 -5160 1736 -3361 12711 4789 3993 -3604 5058 -3212 4509 584 6006 748 -7382 -5361 -1291 5627 388 -450 -8211 9871 900000 4710 -2584 3500 7445 2498 -2203 1736 -5352 -3468 4021 -7099 7514 -5774 3839 -7314 6063 -6222 5616 -9720 9654 -197 6249 -1740 2599 3747 4588 629 3115 -4566 7700 -13428 -2217 2144 -7044 -875 3710 -2475 -1637 1736 340 144 3466 6481 -420 -2977 6562 4310 6844 158 -1192 -10276 417 -7590 -14858 6288 5430 -1591 2356 7153 4 -6800 729 -4841 -1568 -10633 -3950 1297 -1731 -4125 1481 789 4546 -2393 4479 4065 10129 4069 5619 5605 1666 -4753 -593 3261 -7114 7326 1009 6726 -7450 6596 -3863 5924 -635 -5658 -8821 6731 -2589 7172 -7083 882 -32 -5627 1657 2638 7005 -979 -996 -1825 -3498 -6482 1055 -7121 -1316 -1191 2524 -2379 -4646 -2841 1648 1940 -1394 5955 10114 -600 4094 1465 7171 6735 -11610 1139 -5062 1573 -3122 9963 4022 3388 -3379 4485 -3133 4134 564 5525 727 -7825 -5596 -1295 5232 371 -420 -8114 8220 SO 20180826T104515.0Z 6812.448090 252 1 32.01 2 88.99 76.60 93.36 254.67 0.00 1 0.00 1 0 15 4.977e-02 4.815e-02 4.689e-02 4.621e-02 5.816920e+03 2.993399e+03 3.831647e+02 -6.000000e+00 2.620898e+03 286.57 -2.00 20.00 -2.00 505.26 0.00e+00 1.518241e-03 1.246324e-03 6.804705e-05 -6.000000e+00 1.375040e-03 286.57 -2.00 20.00 -2.00 500.07 0.00e+00 2.918557e+00 9.096474e-01 4.507865e-02 -6.000000e+00 9.542577e-01 230.92 -2.00 3.57 -2.00 501.70 0.00e+00 18.513 0.124 489.00 513.00 1 9.4656e+00 6.9761e-02 3.1464e-02 -6.0000e+00 7.3024e-02 9.3754e-02 1.7970e-02 1.9897e-03 -6.0000e+00 1.9271e-02 8.9205e-06 4.0142e-03 3.4240e-03 3.7376e-05 -6.0000e+00 3.8668e-03 -4.3555e-02 2.0588e-04 12 8 8 10 0 0 16.30 14.99 2.66 -0.04356 -0.01571 8 1 1 4 0 4000.000 22.19 14.99 19.31 900000 -7634 -5035 -1704 3960 -1376 3465 6976 -4036 5804 652 -1431 -1481 -1235 -1257 6482 1189 -2275 1131 3088 8815 -5132 4472 732 -8177 -3653 4410 1096 -399 -4491 4017 -1476 3037 3917 4377 1815 -5389 -1085 -9895 -2393 4839 4314 13260 1690 4212 -7231 2367 968 -944 8189 -535 874 -3865 -593 -1361 -5205 1660 4977 -1514 -1543 2747 1047 -3267 3352 -1870 2871 -4440 -808 3862 -1461 -3267 2917 -1011 -2333 -7565 -425 8842 2633 12232 -1211 -1082 -4432 -6282 -10960 -2996 -4986 -673 -905 12316 3933 11485 -1133 -2782 -1805 -538 -1295 2640 7992 -7834 658 -4670 -1608 4251 -3230 -751 -4318 6366 -3895 -836 1878 6824 3042 -5906 3821 -7548 -4615 7765 5775 2363 837 4137 -4902 -3614 -748 13226 3493 3762 1527 1786 714 16214 -7347 2453 -2484 -7681 1781 3632 2321 619 3473 4224 763 -258 6235 -2310 -3373 207 4862 -2785 -8196 -7989 900000 -7857 -5221 -1786 4043 -1507 3701 7311 -4717 6092 705 -1561 -1593 -1302 -1311 6264 1222 -2476 1233 3366 9071 -6048 4793 815 -10003 -4292 4767 1217 -442 -4945 3937 -1524 3044 4047 4706 2026 -6367 -1210 -11854 -2629 4943 4454 12686 1832 4510 -8694 2581 1055 -1031 7998 -549 856 -3884 -577 -1370 -5657 1735 5088 -1644 -1662 2823 1100 -3600 3459 -2015 2904 -4719 -815 3684 -1444 -3228 2711 -985 -2336 -8100 -423 7836 2413 10082 -1129 -1007 -4297 -6233 -11420 -2926 -5019 -649 -871 10352 3577 9730 -1098 -2798 -1810 -523 -1235 2358 6577 -7325 552 -4074 -1377 3555 -3063 -723 -4325 5666 -3750 -768 1687 5960 2804 -6011 3563 -7880 -4692 7069 5419 2284 807 3782 -4791 -3446 -700 10932 3174 3414 1413 1640 666 12986 -7233 2150 -2261 -7307 1568 3240 2140 587 3247 3951 740 -254 5803 -2341 -3440 201 4356 -2615 -8066 -7952 SO 20180826T104922.0Z 6812.450949 256 1 32.01 2 88.26 77.31 94.05 255.35 0.00 1 0.00 1 0 15 3.843e-02 3.812e-02 3.325e-02 3.284e-02 5.464512e+03 2.107055e+03 3.917142e+02 -6.000000e+00 2.023904e+03 286.56 -2.00 20.00 -2.00 505.25 0.00e+00 1.977258e-03 8.879227e-04 1.085364e-04 -6.000000e+00 1.061861e-03 286.56 -2.00 20.00 -2.00 500.07 0.00e+00 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