File name: Pandora103s1_Downsview_20180827_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013243.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180827_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180827T104204.0Z 6813.445880 233 1 32.01 2 89.74 76.35 82.80 249.11 0.00 1 0.00 1 0 15 1.669e-01 1.507e-01 1.529e-01 1.444e-01 1.096195e+04 9.797385e+03 1.300543e+03 -6.000000e+00 8.781050e+03 286.48 -2.00 20.00 -2.00 505.15 0.00e+00 6.309113e-03 3.965861e-03 2.713699e-04 -6.000000e+00 4.611808e-03 286.48 -2.00 20.00 -2.00 499.88 0.00e+00 -2.880395e+00 2.944237e+00 7.297638e-02 -6.000000e+00 3.212933e+00 230.82 -2.00 3.57 -2.00 501.52 0.00e+00 19.975 0.155 489.00 513.00 1 1.0776e+01 2.2657e-01 3.6335e-02 -6.0000e+00 2.4565e-01 2.4938e-01 5.9014e-02 1.9755e-03 -6.0000e+00 6.5176e-02 2.7140e-06 8.2343e-04 1.0488e-02 1.5374e-04 -6.0000e+00 1.3009e-02 1.2133e-02 -4.2165e-04 12 8 8 10 0 0 12.41 15.00 3.93 0.01213 0.01784 8 1 1 4 0 4000.000 22.19 15.00 19.29 900000 -3642 18400 -2829 10729 2830 11380 69 14677 3366 15391 -15054 -12968 -4134 -5801 3748 -15743 5462 -16962 -2320 -5438 -5709 14332 -17831 28202 9663 6363 17536 959 -3484 -12725 4013 7728 -2328 10565 -5279 6751 4276 37880 -13955 23631 -5620 24846 -7224 -1670 -4979 -482 6590 -958 12570 -14098 -852 6457 39380 19219 13574 -8177 33955 -17504 6675 3671 -4126 21222 11958 -6194 -2554 -19464 7644 15122 34767 -7298 14142 24290 21458 -6365 -34919 1457 -15378 -27797 -357 25481 -16324 38171 -8183 16679 34218 -3400 -3426 3967 8514 9001 3570 -1307 7700 12814 9211 14887 16645 8175 -23026 -17660 5227 5198 2602 -22514 15154 12726 60094 16421 18763 -30014 -4085 3268 -9080 4272 32612 -12888 4677 40256 -564 12557 29329 8251 -10004 -13983 3675 23787 6230 35922 -24678 -3645 661 15699 5211 51 -13094 -6065 5282 -6293 10231 -268 13494 20713 3437 7947 31420 1067 -11382 -12499 23150 -24420 900000 -3814 15960 -3128 10792 3128 11796 81 15029 3807 15156 -19455 -16174 -4639 -6505 3803 -19275 5525 -21849 -2662 -6437 -6737 13914 -23532 24071 9937 6747 16627 1055 -3858 -14692 3880 7257 -2467 10359 -6204 7033 4481 28422 -16973 19941 -6310 21134 -8478 -1888 -5879 -547 6927 -1067 12100 -17058 -878 6055 26734 16027 12418 -9552 27048 -22941 6901 3884 -4721 19222 11877 -7308 -2877 -25314 7517 13686 25817 -7951 12434 19487 17879 -7041 -51307 1486 -17918 -35839 -350 19446 -18632 26075 -8718 14108 24815 -3545 -3554 3793 7715 8107 3415 -1338 7372 11604 8384 12421 13219 6843 -25382 -18051 4267 4324 2319 -26896 12939 11081 32823 13301 14764 -38328 -4156 3141 -9901 4110 23920 -14667 4564 28197 -576 11071 21472 7199 -10324 -15169 3383 18051 5589 24116 -29414 -3560 609 12161 4385 45 -12964 -5725 4571 -6127 8575 -251 11076 15868 3107 6867 21600 965 -11294 -12123 15649 -26035 SO 20180827T104626.0Z 6813.448912 237 1 32.01 2 88.97 77.11 83.51 249.89 0.00 1 0.00 1 0 15 9.263e-02 8.989e-02 9.069e-02 8.818e-02 1.448649e+04 6.312819e+03 1.003209e+03 -6.000000e+00 4.876623e+03 286.48 -2.00 20.00 -2.00 505.28 0.00e+00 2.383759e-04 2.395053e-03 8.026871e-05 -6.000000e+00 2.563686e-03 286.48 -2.00 20.00 -2.00 499.88 0.00e+00 1.180339e+00 1.744164e+00 7.142501e-02 -6.000000e+00 1.791150e+00 230.82 -2.00 3.57 -2.00 501.56 0.00e+00 18.483 0.123 489.00 513.00 1 1.0263e+01 1.3335e-01 3.1774e-02 -6.0000e+00 1.3685e-01 1.2511e-01 3.5017e-02 2.5646e-03 -6.0000e+00 3.6461e-02 4.5651e-06 5.2562e-03 6.2865e-03 7.1283e-05 -6.0000e+00 7.2270e-03 -5.1091e-02 4.0048e-04 12 8 8 10 0 0 90.19 15.00 7.37 -0.05109 -0.01463 8 1 1 4 0 4000.000 22.19 15.00 19.28 13345 -10009 7970 -6433 -9199 4280 4564 -12798 8894 3781 11138 1419 -4477 -2002 14998 1283 3088 -862 -5230 -1484 957 -9662 1532 -3934 4675 12083 -6712 7069 -9776 11846 -4627 3404 4763 -1770 -17154 23919 -9512 18348 3432 2145 -11007 12207 9620 8504 -8023 5175 -5836 -3388 11337 -3755 -19395 2571 414 -1828 15982 -1122 10172 5204 6151 -8812 15791 -7304 4558 -6696 14969 12181 -2741 13919 -3896 13445 -11706 13407 -3473 1941 -1331 7799 -10863 4716 -14630 2541 -4267 18654 6628 -3918 -13139 10087 9140 -5214 3450 1515 4935 1935 18569 -1069 830 10149 -765 619 -3766 631 -2694 -10786 19794 -1183 16809 -276 9190 -3804 -13197 7318 3847 -9779 -932 -1821 2783 3338 7800 -3507 -13761 2057 4279 -6002 877 3966 7620 4396 -6708 18007 -17281 -3619 2757 3019 -11173 12495 -5370 -2181 -4556 -4222 -15375 5958 2085 2588 25781 -6566 2299 -8677 860 13076 20264 523 900000 11292 -10786 7478 -7233 -10878 4524 4918 -16512 9293 4089 11007 1524 -5010 -2150 13549 1326 3174 -947 -6198 -1719 1079 -12079 1714 -4651 5121 12317 -8165 7477 -11870 11137 -4975 3397 4784 -1980 -23134 21742 -11772 17072 3637 2274 -13242 11796 9634 8709 -9751 5544 -6906 -3857 10997 -4108 -23814 2474 399 -1816 13797 -1188 9881 5338 6223 -10216 14394 -8389 4686 -7662 13756 11288 -2873 12236 -4031 11561 -12661 11412 -3519 1898 -1362 7231 -11733 4273 -15804 2306 -4137 14620 5865 -3872 -14446 8945 8163 -5308 3196 1424 4507 1847 15326 -1057 777 8335 -671 520 -3232 508 -2231 -9873 14176 -1107 13815 -270 8108 -3725 -13948 6398 3543 -10384 -910 -1790 2605 3118 7103 -3626 -15686 1972 3910 -5886 794 3519 6588 3919 -6671 14040 -18845 -3475 2466 2618 -10944 9696 -4957 -1999 -4394 -4110 -16879 5406 1982 2461 19696 -6864 2200 -9163 812 10668 15119 472 900000 SO 20180827T105038.0Z 6813.451829 241 1 32.01 2 88.23 77.83 84.20 250.63 0.00 1 0.00 1 0 22 7.714e-02 7.497e-02 7.113e-02 6.936e-02 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