File name: Pandora103s1_Downsview_20180828_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013331.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v5d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180828_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180828 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180828T104306.0Z 6814.446597 239 1 32.01 2 89.75 76.83 72.81 244.02 0.00 1 0.00 1 0 28 7.607e-02 7.344e-02 6.609e-02 6.500e-02 1.555507e+04 4.593760e+03 8.460800e+02 -6.000000e+00 4.001827e+03 286.40 -2.00 20.00 -2.00 505.32 0.00e+00 -6.515946e-04 1.754808e-03 1.035868e-04 -6.000000e+00 2.100886e-03 286.40 -2.00 20.00 -2.00 500.27 0.00e+00 -2.722369e-01 1.254554e+00 1.431899e-01 -6.000000e+00 1.460070e+00 230.73 -2.00 3.57 -2.00 501.90 0.00e+00 19.998 0.156 489.00 513.00 1 9.8560e+00 9.5881e-02 3.7429e-02 -6.0000e+00 1.1170e-01 1.2757e-01 2.4810e-02 3.5184e-03 -6.0000e+00 2.9524e-02 6.2796e-06 6.6557e-03 4.6138e-03 6.3917e-05 -6.0000e+00 5.9146e-03 3.9032e-03 -1.6403e-04 12 8 8 10 0 0 7.84 15.00 7.56 0.00390 0.05007 8 1 1 4 0 4000.000 22.19 15.00 19.24 900000 -1097 -2359 -866 -2667 -2750 -6349 -9475 2251 5096 15066 4374 6257 -12123 4319 11606 4893 -5877 273 -8374 2742 -12564 -2597 -3523 8439 5994 6455 1964 5583 -4356 -1817 -7023 -6047 5828 -2944 1917 -4184 12892 8673 5136 3761 3965 -2911 -5031 -2575 -55 -120 5064 -7421 6028 -2983 -1984 -654 6950 -2800 -2325 22554 1641 4385 -1337 12067 686 8266 -4930 3696 2286 -1426 -443 3027 -7612 6345 -6802 6267 -2838 6436 1728 11836 9398 -5408 -13021 -191 -4097 -10103 585 10734 4507 -7997 -5582 -15049 -1776 15 16329 1296 14076 -4208 3857 -4997 5752 2664 -7428 -3477 -4289 14769 6980 24901 4293 -3578 4701 -2153 -9083 9404 -5496 12617 -6934 1353 3040 2265 -4275 8887 -3424 3185 4048 -3030 -9914 11488 12614 5441 9925 -10769 -7220 -18483 11761 -982 10566 -4237 -3109 -12541 6591 -7963 7856 4950 10878 -9372 -7130 6726 2998 1071 3276 -6773 -3683 10872 900000 -1034 -2329 -879 -2828 -2972 -7271 -11344 2408 5236 13792 4395 6082 -13849 4165 10435 4749 -6507 295 -10012 2936 -15623 -2926 -4009 8609 6270 6683 2114 5681 -4667 -1845 -7507 -6511 5830 -3346 2098 -4794 12326 8519 5153 3814 4034 -3200 -5708 -2888 -60 -132 5191 -8453 5885 -3069 -1958 -626 6186 -2824 -2429 19012 1711 4442 -1421 11219 718 8086 -5482 3755 2315 -1468 -445 2914 -8007 5743 -7013 5756 -2898 6111 1709 10346 8200 -5383 -13849 -179 -4032 -10624 559 9471 4284 -8595 -5824 -17050 -1761 15 13808 1292 12330 -4258 3456 -4684 4697 2199 -6638 -2966 -3761 11279 6156 19465 4167 -3723 4425 -2127 -9639 8494 -5802 11187 -7416 1329 2937 2241 -4606 8452 -3608 3066 3749 -2948 -10373 9875 10728 4967 8653 -11393 -7405 -21052 9714 -900 8624 -3989 -2951 -13451 5960 -8382 7211 4727 9870 -10411 -7762 6385 2933 1049 3060 -6817 -3581 9282 SO 20180828T104718.0Z 6814.449514 243 1 32.01 2 89.01 77.56 73.47 244.84 0.00 1 0.00 1 0 29 3.281e-02 3.231e-02 2.375e-02 2.363e-02 1.423857e+04 1.621321e+03 9.636078e+02 -6.000000e+00 1.726458e+03 286.40 -2.00 20.00 -2.00 505.44 0.00e+00 2.500022e-03 6.408801e-04 1.596695e-04 -6.000000e+00 9.061428e-04 286.40 -2.00 20.00 -2.00 500.83 0.00e+00 1.427461e+00 4.478778e-01 8.880940e-02 -6.000000e+00 6.286547e-01 230.73 -2.00 3.57 -2.00 502.36 0.00e+00 18.584 0.125 489.00 513.00 1 8.8463e+00 3.4264e-02 3.2531e-02 -6.0000e+00 4.8109e-02 2.1431e-02 8.7371e-03 2.8008e-03 -6.0000e+00 1.2690e-02 1.7873e-05 7.9246e-04 1.6971e-03 1.0658e-04 -6.0000e+00 2.5487e-03 -1.8345e-02 8.4655e-05 12 8 8 10 0 0 -0.65 15.00 6.68 -0.01834 -0.01285 8 1 1 4 0 4000.000 22.19 15.00 19.23 900000 -2657 -5539 9248 3808 6295 1715 487 2772 -504 -97 -1988 -2857 -2270 2575 -6429 -4517 -668 2527 -2377 4934 -2647 4771 221 2075 -2102 3127 160 -1361 -1128 -859 -2537 -5373 575 -573 5349 3092 3783 -977 -3186 -3713 1280 -1386 2757 1139 2298 4625 1828 2776 3353 -1507 122 -7423 -2522 -2125 -666 -1046 -1301 8045 -1428 2786 -1563 5871 -183 4947 -1949 -799 -1144 1337 -3033 536 -6948 -821 -1005 2201 -586 4554 -4317 -5673 -6486 -1548 -2581 -455 -2964 -2117 -2477 312 3511 -1218 -3020 2189 5820 1659 3659 1166 2630 -4198 3036 -3510 1799 -2536 -5348 -2854 -3229 2065 -3882 3894 -2325 848 -1813 5080 -825 1379 -2412 6367 5286 -888 809 5631 -1591 2832 -2620 -1724 613 1476 1014 5705 -75 -6500 4120 663 1356 842 1095 -2705 -427 -1016 2752 649 3109 -1056 2674 -4587 4627 1518 2232 -558 -1909 -2769 -3193 -1692 900000 -2324 -5143 7779 3488 5742 1674 489 2738 -509 -96 -1974 -2825 -2194 2350 -6399 -4454 -650 2466 -2490 4814 -2781 4666 227 2107 -2238 3157 166 -1412 -1120 -820 -2456 -5422 569 -600 5395 3155 3780 -1010 -3326 -3891 1287 -1450 2810 1197 2408 4735 1903 2822 3324 -1517 117 -7517 -2430 -2092 -674 -1096 -1388 7844 -1517 2830 -1669 5880 -195 4986 -2070 -823 -1163 1316 -3076 516 -7186 -808 -1006 2175 -596 4307 -4334 -5690 -6508 -1476 -2505 -436 -2926 -2104 -2508 308 3342 -1202 -3012 2080 5411 1641 3573 1139 2438 -4001 2609 -3144 1501 -2176 -4765 -2577 -3114 2002 -4069 3770 -2351 818 -1798 4814 -843 1391 -2532 6136 5154 -932 854 5722 -1712 2854 -2712 -1733 605 1468 1017 5486 -77 -7012 4025 671 1333 814 1051 -2688 -421 -1040 2770 674 3206 -1150 2826 -5235 4849 1641 2387 -605 -2045 -2918 -3356 -1774 SO 20180828T105128.0Z 6814.452407 247 1 32.01 2 88.28 78.28 74.12 245.64 0.00 1 0.00 1 0 29 1.582e-02 1.535e-02 3.253e-03 3.214e-03 1.902335e+04 2.240418e+02 1.221076e+03 -6.000000e+00 8.324701e+02 286.40 -2.00 20.00 -2.00 505.57 0.00e+00 4.928214e-03 8.766730e-05 2.656118e-04 -6.000000e+00 4.369309e-04 286.40 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