File name: Pandora103s1_Downsview_20180901_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013303.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180901_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180901T104736.0Z 6818.449722 236 1 32.01 2 89.75 78.85 34.80 208.28 0.00 1 0.00 1 0 36 1.286e-01 1.235e-01 1.170e-01 1.124e-01 5.568230e+03 7.233715e+03 8.298838e+02 -6.000000e+00 6.761697e+03 286.06 -2.00 20.00 -2.00 505.30 0.00e+00 -2.330794e-03 3.029821e-03 1.481667e-04 -6.000000e+00 3.554241e-03 286.06 -2.00 20.00 -2.00 499.97 0.00e+00 3.801776e+00 2.219913e+00 3.685194e-02 -6.000000e+00 2.478821e+00 230.36 -2.00 3.57 -2.00 501.65 0.00e+00 19.999 0.156 489.00 513.00 1 1.0157e+01 1.7047e-01 3.5759e-02 -6.0000e+00 1.8950e-01 8.4308e-02 4.3954e-02 1.9595e-03 -6.0000e+00 5.0285e-02 3.5323e-06 -3.3873e-03 8.1945e-03 7.8737e-05 -6.0000e+00 1.0038e-02 -6.2514e-02 7.1679e-04 12 8 8 10 0 0 83.48 15.00 5.80 -0.06251 -0.08601 8 1 1 4 0 4000.000 22.09 15.00 19.08 423 -8945 -14633 -1285 935 -1638 18410 15846 12127 -19759 21836 -12505 -11496 2177 2289 807 -5542 -2455 -2235 2996 17898 -18011 5309 13178 -3296 -12386 -1805 24607 -8433 -1138 1072 19328 -3392 17452 -17647 530 1941 5215 3457 12799 8246 27425 248 20359 -2092 -631 8575 10818 -4026 6615 -4075 20722 2919 -17117 18480 -7589 14850 -14325 13532 -11545 20005 3112 -3968 7027 9803 5917 -19869 11097 4209 -16728 -15027 6316 17724 4535 1915 6972 5419 8853 1853 -2206 -25775 204 -5036 31266 12622 -275 -8631 13578 6031 16589 17695 -667 283 19248 34896 2023 3793 -14891 24233 -21743 11928 18622 -258 -11001 -6473 8264 3404 -6229 9924 2217 13840 -2426 -6164 11548 -2054 7456 -20755 -15603 -10464 27115 -26569 30421 5431 16178 -4830 3515 25811 19119 -4228 12905 -133 -4384 -4712 7350 7230 6733 -7068 4389 -944 -5962 2497 12162 6130 2866 7148 2971 -8325 -9463 12218 -25388 900000 401 -9389 -16752 -1349 988 -1808 17148 15378 12244 -26883 19535 -15434 -13863 2262 2353 842 -6222 -2748 -2590 3367 17419 -24833 5832 13420 -3961 -16267 -2127 22365 -10347 -1245 1113 16832 -3732 16343 -24223 618 2199 5636 3743 12474 8355 23151 274 18711 -2412 -719 8878 10797 -4556 6594 -4342 16819 2752 -19549 15380 -8437 13651 -17601 12652 -13612 17306 3183 -4363 6938 9349 5754 -24256 9882 3965 -18980 -16496 5645 14335 4231 1862 6429 4941 7604 1681 -2067 -30332 189 -4935 21736 10658 -266 -9060 11475 5456 13548 14334 -652 279 15822 24164 1867 3348 -15270 16643 -22712 8936 13303 -230 -11495 -6741 7499 3192 -6269 8393 2024 11495 -2389 -6345 10068 -2041 6770 -25004 -18079 -11491 20371 -32817 21255 4769 12939 -4775 3202 18992 14956 -4118 10721 -125 -4196 -4441 6115 6000 5722 -7089 4024 -924 -6213 2418 10782 5805 2820 6768 2918 -8956 -9991 10216 -30384 900000 SO 20180901T105154.0Z 6818.452708 240 1 32.01 2 88.98 79.59 35.16 209.97 0.00 1 0.00 1 0 22 5.101e-02 4.991e-02 4.537e-02 4.471e-02 4.202108e+03 2.803337e+03 1.558268e+02 -6.000000e+00 2.680062e+03 286.06 -2.00 20.00 -2.00 505.24 0.00e+00 -5.711243e-04 1.206498e-03 3.460258e-05 -6.000000e+00 1.407712e-03 286.06 -2.00 20.00 -2.00 500.03 0.00e+00 1.912261e+00 8.763863e-01 5.673866e-02 -6.000000e+00 9.787715e-01 230.36 -2.00 3.57 -2.00 501.69 0.00e+00 18.522 0.124 489.00 513.00 1 9.5413e+00 6.7122e-02 3.1545e-02 -6.0000e+00 7.4873e-02 1.1887e-01 1.7452e-02 1.9897e-03 -6.0000e+00 1.9788e-02 9.1991e-06 6.1301e-03 3.3362e-03 2.1517e-05 -6.0000e+00 3.9662e-03 -2.1457e-02 -1.1897e-06 12 8 8 10 0 0 -4.03 15.00 1.28 -0.02146 0.02106 8 1 1 4 0 4000.000 22.09 15.00 19.09 900000 652 -10989 1257 5225 1949 6931 -1974 -1311 1431 -4224 6388 -7570 1764 9733 -3095 -3501 -1228 7476 -7416 -549 -4203 3762 -1330 1053 -1678 5038 638 1793 -6117 866 -7762 2517 4425 -122 1893 165 1977 -410 3610 8649 4148 -282 5048 -2268 -8500 -2876 11053 418 8790 -4385 4395 -6162 -571 -601 3804 2872 -5389 -2977 6601 5383 -3192 220 5371 7303 -3530 7520 -2100 -2600 1436 2431 -6115 -4401 -5611 2120 -1277 -17 -6113 -1404 8102 -1721 -4850 -2090 -3342 3363 10370 -4783 1612 -2831 -387 -8074 7802 -2099 -3558 -8416 8249 -287 5241 -900 7545 -7739 9012 -8454 337 -724 6312 3159 -4765 -4602 10378 4978 1638 3865 -7472 9705 -2241 6018 -3031 8440 -2601 3970 1514 4840 3622 -306 1995 -1625 -3542 1384 2726 6117 4135 -8525 -3788 -10182 9813 -2125 1491 -5057 -4651 1319 8294 -3284 1627 -3993 8077 -5545 1127 1053 273 -3197 900000 624 -12160 1288 5294 2076 7194 -2266 -1499 1574 -4813 6493 -8682 1816 9177 -3306 -3793 -1335 7737 -9037 -624 -4954 4097 -1523 1186 -1943 5430 714 1944 -6851 878 -8555 2549 4580 -137 2117 185 2144 -449 3743 8508 4280 -307 5268 -2570 -10263 -3269 10812 446 8437 -4615 4109 -6253 -549 -594 3746 2931 -6015 -3235 6475 5319 -3448 231 5357 7095 -3744 7014 -2116 -2607 1363 2246 -6146 -4394 -5760 2053 -1272 -16 -6063 -1314 6873 -1607 -4720 -1993 -3241 3100 9034 -4833 1526 -2785 -372 -8383 7027 -2123 -3667 -8932 7259 -268 4500 -799 6023 -7088 7107 -8189 316 -712 5814 2954 -4707 -4455 8711 4485 1548 3615 -7854 8643 -2244 5611 -3112 7706 -2595 3641 1393 4260 3256 -288 1836 -1548 -3428 1269 2478 5367 3614 -8251 -3462 -9835 7921 -1987 1375 -5028 -4665 1256 7397 -3299 1568 -4072 7294 -5607 1035 941 244 -2996 SO 20180901T105604.0Z 6818.455602 244 1 32.01 2 88.24 80.31 35.52 211.57 0.00 1 0.00 1 0 22 3.423e-02 3.379e-02 3.097e-02 3.058e-02 7.204976e+03 1.998585e+03 6.648768e+02 -6.000000e+00 1.798511e+03 286.06 -2.00 20.00 -2.00 505.25 0.00e+00 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