File name: Pandora103s1_Downsview_20180903_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013259.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180903_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180903 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180903T104947.0Z 6820.451238 297 1 32.01 2 89.75 79.86 26.66 160.47 0.00 1 0.00 1 0 22 3.338e-02 3.317e-02 2.885e-02 2.863e-02 2.117780e+04 2.130889e+03 1.418027e+03 -6.000000e+00 1.752774e+03 285.89 -2.00 20.00 -2.00 505.47 0.00e+00 2.734416e-03 7.749447e-04 1.441965e-04 -6.000000e+00 9.206181e-04 285.89 -2.00 20.00 -2.00 500.69 0.00e+00 1.577130e+00 5.469859e-01 1.160536e-01 -6.000000e+00 6.388978e-01 230.18 -2.00 3.57 -2.00 502.25 0.00e+00 20.016 0.156 489.00 513.00 1 8.8218e+00 4.1787e-02 3.7148e-02 -6.0000e+00 4.8890e-02 3.4229e-02 1.0587e-02 3.6352e-03 -6.0000e+00 1.2890e-02 1.4606e-05 4.3388e-03 1.9413e-03 1.2554e-04 -6.0000e+00 2.5915e-03 -3.3218e-02 2.0776e-04 12 8 8 10 0 0 18.51 14.99 7.89 -0.03322 -0.00312 8 1 1 4 0 4000.000 22.09 14.99 19.29 900000 -4428 -3568 1906 -890 8957 1235 2266 3305 -1629 5240 -1046 3145 2050 -3573 -5403 -721 -6436 1175 -140 1810 -2362 3835 -4823 2028 461 3493 2102 2371 -6988 -1964 -3154 2573 1578 4249 3902 -2557 867 421 -1737 944 -1653 -4864 5259 -4319 5080 2655 3703 -2484 -426 -4848 -2482 -2014 -3747 977 -3031 1294 2329 5278 -1086 461 -733 7213 1459 670 1245 704 -3102 -1405 -1584 6510 -1944 1057 486 -1583 -2899 1478 -1318 -9649 4493 -3768 -41 -3289 -2850 -1602 934 3707 2635 -1195 1839 1131 6324 -1635 5560 -2116 611 2489 589 -3099 553 2671 -391 -1873 -2935 -351 3302 7820 -6675 -1776 -4284 -335 -2081 1826 -3442 7618 -570 3100 -133 4837 2353 -933 -2471 -136 -5912 2320 3080 1226 -348 -911 1732 -2908 750 -5155 -2930 -3145 6494 -3059 -2377 845 -1275 6011 1885 3539 2006 1550 -1177 467 1966 -2292 -2058 -989 900000 -4021 -3331 1764 -871 8120 1236 2277 3295 -1682 4964 -1042 2966 1922 -3510 -5411 -698 -6763 1187 -145 1846 -2512 3840 -5270 2095 486 3565 2167 2389 -7374 -1917 -3121 2453 1585 4345 4045 -2787 901 435 -1811 960 -1740 -5355 5327 -4871 5261 2806 3826 -2685 -442 -5073 -2464 -1956 -3716 955 -3209 1351 2433 5348 -1163 486 -788 7227 1547 711 1292 720 -3241 -1431 -1592 5960 -1937 1034 486 -1641 -3026 1440 -1286 -10078 4053 -3672 -39 -3233 -2814 -1591 916 3536 2515 -1166 1728 1074 5803 -1653 5207 -2054 550 2096 488 -2619 443 2076 -319 -1632 -2779 -343 3183 7186 -6939 -1736 -4329 -333 -2134 1805 -3573 7072 -574 3082 -140 4903 2407 -959 -2496 -131 -6103 2243 2970 1210 -349 -914 1703 -2979 721 -5164 -2874 -3102 5966 -3179 -2486 866 -1361 6070 1999 3715 2139 1655 -1283 494 2001 -2386 -2135 -1030 SO 20180903T105356.0Z 6820.454120 301 1 32.00 2 89.02 80.58 26.42 162.55 0.00 1 0.00 1 0 22 1.375e-02 1.344e-02 4.393e-03 4.351e-03 2.833692e+04 3.282769e+02 1.822020e+03 -6.000000e+00 7.218652e+02 285.89 -2.00 20.00 -2.00 505.51 0.00e+00 4.298568e-03 1.175192e-04 2.480221e-04 -6.000000e+00 3.791663e-04 285.89 -2.00 20.00 -2.00 501.14 0.00e+00 1.916380e+00 8.116507e-02 1.621456e-01 -6.000000e+00 2.633544e-01 230.17 -2.00 3.57 -2.00 502.59 0.00e+00 18.603 0.125 489.00 513.00 1 6.9605e+00 6.1893e-03 3.4880e-02 -6.0000e+00 2.0150e-02 -4.7308e-02 1.5538e-03 4.5375e-03 -6.0000e+00 5.3173e-03 1.0821e-04 1.0193e-03 2.8004e-04 1.6479e-04 -6.0000e+00 1.0679e-03 -2.0101e-03 -3.5472e-05 12 8 8 10 0 0 98.07 15.00 3.88 -0.00201 0.00506 8 1 1 4 0 4000.000 22.09 15.00 19.30 900000 -4202 -2872 -937 -549 1196 1017 2254 1098 1283 462 525 -480 -856 -2326 -2046 -1249 -717 67 314 818 4 902 618 1752 873 1668 1708 483 -2262 -2535 -1897 -664 73 1593 1186 856 -451 0 -195 -873 -247 1636 1848 875 1752 1107 1879 1091 -587 -1170 -1495 -2455 -1483 -1989 -500 183 979 598 642 1216 696 1214 1312 1702 606 301 -267 -366 -1962 -1118 -2084 -635 -391 466 -567 -362 -718 -1366 -1930 -1388 -823 -201 -598 -302 -294 -594 -287 199 236 -119 1139 1041 2146 1473 1437 533 816 -1451 -1817 -3328 -3076 -2983 -195 515 1920 460 -647 -2238 -1063 -439 3 617 9 879 1760 1962 2887 1708 216 393 -900 -253 435 1563 820 1743 797 1041 172 -148 -195 -1595 -1602 -1266 -1007 -1660 188 1084 1375 1052 854 410 600 1064 1609 631 -923 -2033 -2682 -2545 900000 -3702 -2587 -868 -525 1150 921 2055 1018 1178 419 471 -430 -757 -2070 -1816 -1112 -651 62 300 778 4 860 594 1687 856 1623 1660 469 -2165 -2348 -1744 -612 70 1577 1203 863 -455 0 -193 -869 -247 1634 1875 912 1832 1167 1948 1125 -604 -1175 -1460 -2375 -1419 -1970 -511 192 1036 636 680 1279 743 1304 1414 1822 647 316 -277 -378 -2033 -1131 -2125 -645 -403 486 -597 -373 -721 -1358 -1911 -1358 -805 -197 -592 -304 -301 -612 -292 198 232 -117 1126 1054 2151 1428 1314 464 679 -1217 -1509 -2767 -2585 -2633 -181 513 1963 481 -676 -2340 -1105 -430 3 611 9 860 1707 1942 2946 1805 230 408 -912 -248 423 1533 819 1740 809 1051 176 -152 -196 -1591 -1605 -1274 -1031 -1771 201 1157 1498 1175 970 472 691 1215 1820 714 -1042 -2280 -3020 -2901 SO 20180903T105753.0Z 6820.456864 305 1 34.05 2 88.31 81.26 26.21 164.57 0.00 1 0.00 1 0 29 1.149e-02 1.117e-02 7.601e-04 7.541e-04 3.054741e+04 5.792449e+01 1.971585e+03 -6.000000e+00 6.030571e+02 285.89 -2.00 20.00 -2.00 505.52 0.00e+00 4.317606e-03 2.064965e-05 2.554106e-04 -6.000000e+00 3.167686e-04 285.89 -2.00 20.00 -2.00 501.08 0.00e+00 1.808334e+00 1.423279e-02 1.682851e-01 -6.000000e+00 2.199846e-01 230.17 -2.00 3.57 -2.00 502.57 0.00e+00 16.820 0.093 489.00 513.00 1 4.8574e+00 1.0873e-03 3.1142e-02 -6.0000e+00 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