File name: Pandora103s1_Downsview_20180907_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013248.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180907_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180907 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180907T105416.0Z 6824.454352 352 1 32.01 2 89.75 81.93 60.93 94.00 0.00 1 0.00 1 0 64 1.545e-01 1.425e-01 1.373e-01 1.293e-01 -5.549338e+02 7.540516e+03 2.036241e+02 -6.000000e+00 8.101796e+03 285.55 -2.00 20.00 -2.00 505.22 0.00e+00 3.270710e-05 3.550326e-03 2.461748e-05 -6.000000e+00 4.259703e-03 285.55 -2.00 20.00 -2.00 499.83 0.00e+00 6.460463e+00 2.616102e+00 3.285369e-02 -6.000000e+00 2.969422e+00 229.80 -2.00 3.57 -2.00 501.50 0.00e+00 20.022 0.156 489.00 513.00 1 1.0080e+01 2.0076e-01 3.5664e-02 -6.0000e+00 2.2703e-01 6.6033e-02 5.2639e-02 2.0538e-03 -6.0000e+00 6.0145e-02 3.0312e-06 -1.5993e-02 9.7840e-03 2.3768e-05 -6.0000e+00 1.2033e-02 2.9928e-02 -4.4210e-04 12 8 8 10 0 0 5.72 15.00 12.07 0.02993 -0.08101 8 1 1 4 0 4000.000 22.09 15.00 19.15 900000 -10804 7609 -7543 16304 1766 30228 -5493 10328 -21600 -128 6074 12162 16094 18191 16072 20576 -258 -11849 -12186 -14333 10898 -1355 11950 818 35136 1981 -2532 -27357 38259 -15302 22910 -5589 7304 10202 13820 -7876 10127 -5230 11004 14003 -5375 3649 -15954 -2412 -6786 12321 -15413 45822 -14581 4868 -18407 23312 9538 -2844 14009 4292 24410 7725 -11780 7993 11795 -17175 2274 -13784 6429 -13252 24395 -3109 17176 13986 12069 -719 1532 6452 -11398 483 28071 -6395 3228 2492 30863 17583 -7180 -11460 -6684 26531 -2367 15728 -19973 3144 21478 13289 -12598 5672 -22816 9858 21084 -5225 1009 -6727 40640 -670 31 -11663 -2014 -11955 11451 -2524 27362 11441 18532 1467 17657 -15701 16623 -12583 38196 -13478 -5034 -19388 2361 -11962 19768 4885 2438 -7080 20628 -3678 9544 199 16623 19251 -15211 24705 -10074 5595 4204 8793 -7895 15775 -25238 -4555 2443 15819 -3057 10973 31478 16651 -1793 -13217 900000 -11772 6968 -8211 14701 1896 25178 -6596 10852 -31112 -148 6538 12182 15340 16713 14886 18179 -281 -14714 -15721 -19390 11606 -1620 12570 956 29731 2319 -3085 -42207 30977 -19994 19868 -6316 7353 10277 14107 -10156 10874 -6407 11361 13833 -6340 3957 -21047 -2820 -8363 12719 -20729 33724 -18869 5116 -23444 19143 8710 -2887 12290 4290 20734 7826 -14383 7982 11259 -21688 2390 -16916 6456 -15842 19843 -3228 14484 11986 10325 -689 1443 5860 -12503 475 20735 -6389 2882 2222 20889 13607 -7102 -11816 -6630 19343 -2285 12717 -22680 2854 16369 11017 -13641 5230 -27583 8557 16172 -5048 891 -6216 23347 -572 27 -11775 -1930 -12708 9557 -2357 18762 9085 13952 1326 13911 -17309 13530 -13609 25488 -14861 -5100 -22195 2154 -12349 14856 4257 2207 -7042 15714 -3542 8055 184 13235 14765 -15895 17325 -9759 4675 3660 7549 -8098 13057 -31309 -4639 2336 13434 -3138 9867 23010 13647 -1698 -13745 SO 20180907T105833.0Z 6824.457326 356 1 32.01 2 88.98 82.67 60.19 94.75 0.00 1 0.00 1 0 32 6.436e-02 6.286e-02 5.885e-02 5.770e-02 1.503341e+04 4.172617e+03 1.049534e+03 -6.000000e+00 3.375474e+03 285.55 -2.00 20.00 -2.00 505.29 0.00e+00 1.473874e-03 1.562509e-03 4.837381e-05 -6.000000e+00 1.773250e-03 285.55 -2.00 20.00 -2.00 500.03 0.00e+00 3.070712e-01 1.134487e+00 7.246955e-02 -6.000000e+00 1.228221e+00 229.80 -2.00 3.57 -2.00 501.68 0.00e+00 18.536 0.124 489.00 513.00 1 9.8736e+00 8.6699e-02 3.1917e-02 -6.0000e+00 9.4053e-02 1.3728e-01 2.2296e-02 2.6224e-03 -6.0000e+00 2.4654e-02 7.0464e-06 1.5337e-03 4.1016e-03 8.1234e-05 -6.0000e+00 4.9878e-03 -4.0395e-02 2.9711e-04 12 8 8 10 0 0 2.37 15.00 3.16 -0.04040 -0.02976 8 1 1 4 0 4000.000 22.09 15.00 19.16 -2678 -7267 10053 -1213 -153 -6079 -2729 -1634 -469 -2008 -12728 1611 -6422 4735 -1535 12821 -7883 4541 -5221 11014 6953 3718 234 -4365 5669 -5940 1100 2046 -3969 8074 -4672 8142 1623 6609 1916 -620 -3819 3603 9362 -5024 3558 5304 9361 -14417 7600 -8334 1368 845 1176 -10332 9175 -2414 4789 -5481 3788 -2515 -3579 7014 -4590 3522 -816 7965 6064 -4648 1851 5381 5254 -929 7034 2772 -2231 4717 -1652 -2048 -765 10554 -2258 4727 14673 12780 -4985 -8932 333 -5764 5591 -9049 14578 4368 2594 3619 883 -6330 4124 1330 2106 1841 7346 -5137 11850 -5376 -3370 176 3958 3334 1623 6914 4004 3159 -14952 7476 -6954 7864 2077 3552 -4702 -7736 -11341 -1156 -5938 825 -4866 -5001 8925 23026 6102 1636 3932 -9839 -3473 -5249 6535 5807 -2027 4498 -5130 -2811 2618 -9907 2043 10616 -1039 3515 9751 -6922 -667 -3404 -3828 -397 -6589 997 1696 -2623 -7518 9075 -1274 -164 -7012 -3115 -1872 -532 -2285 -15742 1711 -7267 4719 -1608 11663 -8847 4625 -6048 11103 7273 4012 261 -5087 6039 -7109 1222 2243 -4528 7833 -4957 7616 1641 6617 2099 -705 -4421 3820 9253 -5636 3664 5399 9265 -18204 7848 -10099 1503 920 1256 -12074 8568 -2442 4428 -5596 3632 -2670 -3948 7060 -5161 3629 -874 7884 6154 -5233 1943 5369 5138 -949 6588 2665 -2215 4378 -1646 -2080 -781 9616 -2272 4326 12028 10576 -4888 -9174 314 -5810 5127 -9691 12409 4076 2435 3341 839 -6534 3922 1299 1980 1665 6045 -4610 8829 -4637 -2816 144 3257 2944 1536 6319 3736 2916 -16158 6521 -7117 7067 1982 3339 -4772 -8084 -12458 -1174 -6345 812 -4932 -4927 7527 17021 5379 1508 3549 -10136 -3338 -5147 5695 4962 -1830 3790 -4735 -2578 2346 -10186 1888 9171 -1016 3305 8672 -7248 -655 -3414 -3790 -370 -6359 889 1519 SO 20180907T110243.0Z 6824.460220 360 1 32.01 2 88.24 83.39 59.47 95.49 0.00 1 0.00 1 0 15 3.447e-02 3.411e-02 3.085e-02 3.042e-02 9.953312e+03 2.080003e+03 6.297646e+02 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