File name: Pandora103s1_Downsview_20180911_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013126.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180911_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180911 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180911T105845.0Z 6828.457465 398 1 32.01 2 89.75 84.04 110.34 70.77 0.00 1 0.00 1 0 15 1.053e-01 9.995e-02 1.000e-01 9.653e-02 4.637660e+03 6.224536e+03 3.781665e+02 -6.000000e+00 5.515560e+03 285.22 -2.00 20.00 -2.00 505.25 0.00e+00 2.097074e-03 2.607727e-03 5.329369e-05 -6.000000e+00 2.901038e-03 285.22 -2.00 20.00 -2.00 499.87 0.00e+00 4.159447e+00 1.904566e+00 2.326317e-02 -6.000000e+00 2.020101e+00 229.43 -2.00 3.57 -2.00 501.53 0.00e+00 20.029 0.157 489.00 513.00 1 9.9177e+00 1.4581e-01 3.5665e-02 -6.0000e+00 1.5449e-01 1.0154e-01 3.7485e-02 2.0099e-03 -6.0000e+00 4.0840e-02 4.1205e-06 1.4404e-02 7.3402e-03 3.3176e-05 -6.0000e+00 8.1907e-03 -7.0376e-03 -9.9518e-05 12 8 8 10 0 0 -1.41 14.99 6.74 -0.00704 0.09288 8 1 1 4 0 4000.000 21.98 14.99 18.95 900000 -8390 4257 21178 -12394 4719 -17680 12506 -6647 7870 1465 -9075 973 -1162 7567 4557 3258 7136 2949 -3 -4906 12362 -10190 14248 -1176 2455 13347 7364 13593 4093 14140 -9756 10125 6048 -1689 70 98 -11340 -4554 -21130 2698 314 1524 -8946 5963 429 3741 -6141 -620 12268 -3872 -12238 11898 5039 11608 2578 6392 -6379 2667 7179 6629 14614 -17460 12760 -15207 17712 -7156 -1473 -7106 14880 -2085 3737 -5306 9451 11780 9792 -3395 8200 -4862 18994 -8950 -2049 -2273 -6732 713 -8171 16789 -12172 2791 -1927 -4341 -706 18093 -10864 16873 14648 7467 6846 -6097 -14495 -1506 -4787 5614 3524 -6397 11645 -9903 13151 -12772 12545 -7522 17740 -6014 1435 -9087 19874 -10715 4507 16685 -3911 32002 -11729 18870 9416 108 759 21337 26459 -1980 -23731 4230 -4719 13516 -10025 18806 1355 -4680 -5024 -8597 -9474 2151 -5172 -1489 -5577 3025 17235 -4887 16314 10651 476 -4991 900000 -9065 4239 18607 -15377 5058 -24034 12790 -8138 8214 1600 -10850 1038 -1246 7415 4619 3399 7399 3278 -3 -5895 12579 -12882 14297 -1380 2777 13525 7835 13159 4154 12820 -11229 9870 6430 -1991 81 111 -14158 -5247 -28338 2881 346 1681 -11054 6436 488 4082 -7253 -681 11552 -4107 -13702 10416 4779 10707 2686 6534 -7389 2812 7181 6672 13709 -22367 12139 -18711 15515 -7808 -1500 -7548 12527 -2045 3481 -5451 8561 10504 8747 -3343 7073 -4717 14550 -9016 -1946 -2166 -6740 673 -8431 13555 -12912 2548 -1841 -4268 -682 14837 -11716 13597 11765 6252 5603 -5506 -13875 -1268 -4248 4705 3163 -6436 9752 -10019 10425 -12906 10078 -7486 14046 -6058 1353 -9499 15797 -11571 4215 13701 -3842 21808 -11973 14338 7952 100 701 16165 18978 -1868 -27812 3734 -4432 10492 -9676 13771 1204 -4535 -4958 -8892 -9991 2034 -5269 -1474 -5773 2883 14169 -4847 12768 8648 429 -4833 SO 20180911T110257.1Z 6828.460383 402 1 32.15 2 88.99 84.76 109.66 71.56 0.00 1 0.00 1 0 22 3.966e-02 3.944e-02 4.541e-02 4.468e-02 9.057974e+03 3.022857e+03 6.602107e+02 -6.000000e+00 2.077098e+03 285.22 -2.00 20.00 -2.00 505.21 0.00e+00 2.162639e-03 1.195645e-03 1.248301e-04 -6.000000e+00 1.092033e-03 285.22 -2.00 20.00 -2.00 499.95 0.00e+00 3.892724e-01 8.910093e-01 4.418753e-02 -6.000000e+00 7.594891e-01 229.43 -2.00 3.57 -2.00 501.58 0.00e+00 18.566 0.125 489.00 513.00 1 9.6065e+00 6.7914e-02 3.1713e-02 -6.0000e+00 5.8098e-02 1.6355e-01 1.7908e-02 2.0743e-03 -6.0000e+00 1.5334e-02 9.1596e-06 -3.9492e-03 3.3010e-03 6.8343e-05 -6.0000e+00 3.0806e-03 -3.3077e-02 1.4391e-04 12 8 8 10 0 0 -4.55 15.01 4.52 -0.03308 -0.06047 8 1 1 4 0 4000.000 22.09 15.01 18.96 900000 615 -23 -3382 3562 -4398 1078 -1093 -233 8058 1062 4781 111 -3423 1540 -3832 2542 -1565 2858 2739 880 -2955 -2240 -5269 -47 -51 -3091 6224 5590 4137 39 4501 -1325 4790 59 7457 7105 -2630 -10469 -4331 -4648 -1627 431 1082 3013 -2261 3577 1776 702 5856 2014 -5593 -3054 -10359 -1929 2395 -47 -6627 -200 -1013 2942 -2514 -2225 6648 -3590 429 237 -4362 -4918 12813 1495 -5452 2407 475 -89 2585 496 -1407 1686 -1503 4460 7746 4288 811 2273 1546 1182 -109 1290 6480 -228 -6002 3735 -8140 -2084 -1848 2150 1253 9484 -3903 -1208 -4121 3000 -2337 -3738 -363 895 -278 -2331 -2430 -3938 4260 5125 1201 3452 -6638 -2205 8458 -326 -228 -3526 -4244 -998 3632 2033 6357 -1371 1417 6119 121 -219 4142 -3937 -1490 555 -5953 -1295 -1206 -3059 934 6092 -4132 1644 3093 -1347 -375 2383 -5307 1717 1636 7388 900000 597 -23 -3638 3715 -5051 1198 -1263 -269 8513 1177 5023 120 -3772 1592 -4147 2593 -1689 3046 3006 987 -3430 -2577 -6231 -54 -59 -3613 6610 5914 4284 41 4371 -1372 4798 64 7847 7462 -2983 -12639 -4854 -5187 -1766 464 1170 3240 -2582 3862 1932 759 5915 2050 -5914 -3069 -11056 -1923 2380 -50 -7583 -216 -1093 3032 -2738 -2435 6684 -3975 451 245 -4615 -5170 11205 1432 -5539 2279 463 -89 2536 488 -1370 1564 -1424 3966 6704 3870 759 2118 1472 1135 -106 1222 5794 -217 -6099 3520 -8741 -2087 -1791 1941 1105 7505 -3435 -1014 -3555 2475 -2133 -3651 -351 851 -263 -2199 -2278 -3804 3873 4674 1146 3225 -6835 -2187 7673 -325 -224 -3497 -4135 -920 3193 1839 5534 -1286 1293 5297 111 -202 3600 -3601 -1312 475 -5441 -1161 -1106 -2888 858 5382 -4045 1526 2843 -1294 -356 2173 -5079 1486 1392 5971 SO 20180911T110702.1Z 6828.463218 406 1 32.15 2 88.26 85.47 109.00 72.33 0.00 1 0.00 1 0 22 2.425e-02 2.352e-02 2.403e-02 2.377e-02 1.101675e+04 1.625476e+03 8.080745e+02 -6.000000e+00 1.270008e+03 285.22 -2.00 20.00 -2.00 505.25 0.00e+00 2.335937e-03 6.391657e-04 1.331717e-04 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