File name: Pandora103s1_Downsview_20180915_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013234.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180915_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180915T110315.0Z 6832.460590 405 1 32.00 2 89.74 86.16 150.21 32.32 0.00 1 0.00 1 0 15 4.645e-02 4.603e-02 4.417e-02 4.358e-02 1.866861e+04 3.196468e+03 1.134648e+03 -6.000000e+00 2.429372e+03 284.88 -2.00 20.00 -2.00 505.32 0.00e+00 3.960239e-03 1.174733e-03 2.416071e-04 -6.000000e+00 1.277918e-03 284.88 -2.00 20.00 -2.00 500.22 0.00e+00 7.125255e-01 8.555280e-01 1.235611e-01 -6.000000e+00 8.895449e-01 229.06 -2.00 3.57 -2.00 501.83 0.00e+00 20.037 0.157 489.00 513.00 1 9.3090e+00 6.5425e-02 3.7531e-02 -6.0000e+00 6.8037e-02 1.1621e-01 1.6831e-02 3.4348e-03 -6.0000e+00 1.7965e-02 9.3887e-06 6.3626e-04 3.0287e-03 1.1534e-04 -6.0000e+00 3.6086e-03 -8.4417e-03 -2.9499e-05 12 8 8 10 0 0 91.03 14.99 2.30 -0.00844 -0.00403 8 1 1 4 0 4000.000 22.19 14.99 19.28 900000 -6289 752 376 352 827 1845 4864 -11167 4792 -1969 3536 -2345 8078 -3303 -1678 764 1338 -374 -953 828 -936 -3029 -2381 5527 -359 1718 875 3652 -2347 6726 -6799 2781 -5634 1606 8218 823 979 -1665 -2320 -3269 2289 126 -1985 -57 -1622 -3584 1939 -3469 11576 3964 2475 -6366 3325 -2997 147 -3476 4050 -2788 4221 2424 7385 6995 8967 5030 -4530 -4345 -3641 6207 -5042 -5515 2748 -11184 -4722 180 -7698 8796 -7446 7147 -1764 3738 1417 11401 6832 3487 906 -3665 8549 -684 2772 -1155 -731 -4559 2633 -656 -3952 -3167 -156 -3667 2548 -352 7272 -6913 1010 4159 4879 -4816 2072 -552 -1371 6158 -3928 -1223 9121 8843 -101 914 -3744 -1169 -7733 2472 -2606 7388 -7503 1496 -1186 1945 -2975 1817 3915 -9352 -222 -606 9415 3141 2511 -2468 -117 184 5145 -1315 -3004 2528 4453 4231 1420 -8286 5818 -4833 -308 -3649 900000 -6242 718 377 364 868 1959 5097 -13717 4988 -2142 3594 -2488 7603 -3429 -1710 765 1360 -399 -1047 893 -1025 -3382 -2644 5733 -397 1858 950 3806 -2487 6272 -7187 2711 -6170 1718 8411 896 1047 -1803 -2499 -3545 2369 135 -2201 -63 -1835 -4132 2095 -3892 11005 3931 2408 -6608 3128 -3068 152 -3846 4229 -3113 4372 2544 7429 7118 8965 5201 -5066 -4748 -3882 5953 -5323 -5742 2631 -12354 -4964 184 -8491 8078 -7783 6377 -1699 3392 1321 9706 6105 3263 882 -3734 7666 -662 2564 -1109 -708 -4677 2535 -635 -3770 -2864 -132 -3136 2013 -281 5424 -6139 885 3756 4496 -4873 1930 -517 -1298 5532 -3962 -1208 8149 7900 -98 893 -3925 -1209 -8435 2382 -2557 6409 -7523 1396 -1141 1820 -2928 1695 3583 -9754 -207 -552 7747 2742 2232 -2372 -112 177 4788 -1321 -3091 2477 4288 4071 1397 -8832 5275 -4740 -286 -3539 SO 20180915T110720.6Z 6832.463433 409 1 33.27 2 89.01 86.87 149.83 34.03 0.00 1 0.00 1 0 29 1.705e-02 1.650e-02 1.131e-03 1.122e-03 2.436056e+04 8.153645e+01 1.583328e+03 -6.000000e+00 8.915016e+02 284.88 -2.00 20.00 -2.00 505.52 0.00e+00 4.018055e-03 3.056056e-05 2.203016e-04 -6.000000e+00 4.689255e-04 284.88 -2.00 20.00 -2.00 501.13 0.00e+00 1.584164e+00 2.096725e-02 1.481022e-01 -6.000000e+00 3.253782e-01 229.06 -2.00 3.57 -2.00 502.63 0.00e+00 18.609 0.125 489.00 513.00 1 5.3218e+00 1.6037e-03 3.4320e-02 -6.0000e+00 2.4908e-02 -6.7418e-02 4.0141e-04 4.1279e-03 -6.0000e+00 6.5364e-03 5.7724e-04 1.4128e-03 7.3737e-05 1.6084e-04 -6.0000e+00 1.3217e-03 1.0226e-02 -6.7629e-05 12 8 8 10 0 0 96.90 14.99 6.38 0.01023 0.02003 17 3 1 4 0 1956.600 22.19 14.99 19.28 -5939 -5413 -3578 -1360 -124 752 1469 1926 2000 1214 351 -13 -960 -1861 -2153 -2084 -1856 -615 723 1113 972 1080 987 1223 1686 1714 1687 1617 354 -1771 -2822 -2840 -1778 -87 1720 1834 1545 481 61 -456 -80 19 938 1458 2418 2452 2275 1780 1323 72 -1297 -2398 -3259 -2845 -1727 24 1196 1744 1327 1321 1330 1783 1641 1950 1607 885 176 -289 -804 -1321 -1974 -1815 -964 -559 100 -1 -720 -1817 -1838 -2076 -1729 -868 -382 -641 -597 -297 -203 -758 -465 -170 95 1195 2000 2681 2222 1792 1035 232 -1548 -2909 -3779 -3474 -2174 74 1105 1351 436 -701 -1844 -1402 -457 -82 600 1251 1697 2154 2869 2660 2009 599 -203 -1001 -688 425 1148 1265 1407 871 315 699 295 -795 -1165 -2045 -2151 -1671 -668 235 730 1098 628 683 575 1030 1278 1304 370 -1285 -2881 -3090 -2746 -5298 -4527 -3050 -1189 -111 682 1357 1804 1882 1141 326 -12 -884 -1705 -1962 -1900 -1710 -575 691 1085 949 1055 969 1204 1675 1718 1692 1622 354 -1734 -2704 -2725 -1719 -86 1647 1785 1494 464 59 -437 -77 19 915 1440 2410 2471 2297 1789 1320 71 -1263 -2292 -3089 -2689 -1668 24 1213 1787 1367 1357 1365 1842 1716 2043 1684 921 181 -295 -818 -1335 -1978 -1818 -968 -569 103 -1 -732 -1821 -1817 -2042 -1688 -846 -374 -634 -602 -304 -208 -774 -467 -168 94 1191 2026 2699 2166 1664 920 200 -1339 -2512 -3251 -3030 -1967 71 1122 1325 434 -695 -1824 -1392 -462 -84 614 1270 1711 2166 2932 2823 2185 655 -218 -1049 -702 431 1179 1310 1467 918 333 741 315 -835 -1206 -2143 -2270 -1794 -735 261 815 1177 690 759 646 1154 1427 1450 410 -1423 -3182 -3416 -3072 SO 20180915T111127.2Z 6832.466287 413 1 34.43 2 88.27 87.58 149.43 35.71 0.00 1 0.00 1 0 22 1.297e-02 1.270e-02 1.692e-03 1.682e-03 2.234642e+04 1.199220e+02 1.463524e+03 -6.000000e+00 6.785102e+02 284.88 -2.00 20.00 -2.00 505.49 0.00e+00 3.546547e-03 4.589701e-05 1.994418e-04 -6.000000e+00 3.569265e-04 284.88 -2.00 20.00 -2.00 501.11 0.00e+00 1.427748e+00 3.154603e-02 1.347772e-01 -6.000000e+00 2.483398e-01 229.06 -2.00 3.57 -2.00 502.59 0.00e+00 16.718 0.091 489.00 513.00 1 6.3169e+00 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