File name: Pandora103s1_Downsview_20180920_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T013302.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180920_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180920 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180920T110853.5Z 6837.464508 377 1 35.02 2 89.74 88.85 138.41 292.80 0.00 1 0.00 1 0 15 1.021e-01 9.668e-02 3.132e-02 3.059e-02 4.950212e+03 1.860914e+03 4.404266e+02 -6.000000e+00 5.329456e+03 284.25 -2.00 20.00 -2.00 505.28 0.00e+00 3.940839e-03 8.145288e-04 2.389088e-04 -6.000000e+00 2.809702e-03 284.25 -2.00 20.00 -2.00 500.34 0.00e+00 1.874863e+00 5.888945e-01 4.515325e-02 -6.000000e+00 1.967141e+00 228.46 -2.00 3.57 -2.00 501.91 0.00e+00 20.056 0.157 489.00 513.00 1 8.9821e+00 4.4826e-02 3.6331e-02 -6.0000e+00 1.5028e-01 9.5347e-02 1.1936e-02 2.1378e-03 -6.0000e+00 3.9931e-02 1.2081e-05 -1.8698e-03 2.2808e-03 6.9313e-05 -6.0000e+00 7.9704e-03 -1.7926e-02 3.7934e-04 12 9 9 12 4 4 99.82 38.21 17.47 -0.01793 -0.03090 12 2 1 4 0 2917.420 44.36 38.21 41.20 17582 16039 -15029 -6585 11807 9747 14630 4324 -11292 -3476 -2368 13900 3665 -5618 2632 7541 5065 2969 22914 -4463 -7893 10421 -369 8824 -11321 16554 7513 -4425 1874 -9457 21247 -527 -13731 8614 -5958 4622 -7378 1363 1848 5367 -10739 -13880 -1251 15784 6736 -66 727 -8538 4707 -791 -360 5874 -12184 10779 -12604 8947 -8490 -4203 -4296 11934 7952 1324 -5175 -10170 12197 14509 7395 16 -7512 948 -6503 -14162 4976 -137 13942 -4529 9818 -6476 4824 -7514 -14415 10331 14808 -3376 -7617 -6032 9406 3587 13987 1311 4592 -6914 -14778 2855 947 15646 20326 -20582 11011 10809 -15076 -1536 -9813 6139 -6253 -7444 -1489 246 -11126 9195 -7896 7835 7846 8447 11661 8026 2217 32041 -12151 14570 -15286 8890 -1995 8130 16898 8059 8068 12989 -574 -5949 -4829 -12517 1040 6198 -487 6167 -9949 -5808 8390 2193 8192 -1698 17696 -11501 -2817 -792 -1813 -6799 8699 31127 900000 13566 12731 -16695 -7041 10863 9315 13636 4513 -13710 -3858 -2546 12604 3615 -5958 2552 6967 4841 2967 19501 -5034 -9171 10141 -399 8738 -13759 15429 7617 -5015 1957 -10529 17025 -522 -15717 8272 -6877 4864 -8598 1438 1916 5318 -12453 -16739 -1354 14690 6943 -73 796 -10092 4818 -835 -365 5452 -13231 9396 -14202 8518 -9836 -4718 -4817 11347 7842 1403 -5877 -12112 11608 13274 7099 16 -8127 930 -6743 -15827 4664 -137 12354 -4772 8772 -6612 4368 -7623 -15639 8898 12261 -3345 -7963 -6268 8404 3370 11799 1249 4255 -7272 -17171 2817 937 13105 15875 -23231 8911 8543 -15109 -1365 -9766 5504 -6535 -7868 -1463 233 -11587 7935 -8228 7146 7263 7849 10546 7545 2228 24318 -14070 12780 -17563 7923 -1958 7319 14131 7344 7367 11280 -566 -6218 -4975 -13565 968 5430 -452 5457 -10603 -6057 7708 2165 7674 -1753 15218 -13196 -2978 -816 -1847 -7037 7544 21640 900000 SO 20180920T111313.8Z 6837.467521 381 1 33.65 2 88.96 89.60 139.10 293.87 0.00 1 0.00 1 0 22 2.838e-02 2.804e-02 9.515e-03 9.468e-03 1.242853e+04 6.373260e+02 7.495844e+02 -6.000000e+00 1.480370e+03 284.25 -2.00 20.00 -2.00 505.44 0.00e+00 3.402907e-03 2.548066e-04 1.832478e-04 -6.000000e+00 7.793317e-04 284.25 -2.00 20.00 -2.00 500.73 0.00e+00 1.825886e+00 1.789072e-01 1.011724e-01 -6.000000e+00 5.412070e-01 228.46 -2.00 3.57 -2.00 502.29 0.00e+00 18.517 0.124 489.00 513.00 1 8.0040e+00 1.3679e-02 3.2592e-02 -6.0000e+00 4.1426e-02 2.3460e-02 3.4704e-03 2.8012e-03 -6.0000e+00 1.0867e-02 4.0268e-05 3.0892e-03 6.8654e-04 8.6560e-05 -6.0000e+00 2.1997e-03 -4.7518e-03 4.9352e-05 12 9 9 12 12 12 99.93 38.20 4.47 -0.00475 0.01668 11 2 1 4 0 3058.350 44.36 38.20 41.20 -5945 -6419 -1424 267 1538 590 241 -5340 4239 1170 -496 4599 2268 -4569 -2934 -2773 -1225 -3663 541 -1781 1331 -816 -13 7897 1878 3984 1215 3094 -1186 220 -3865 -9 2198 -2641 -1004 -4201 -328 1349 2661 -327 -1081 1715 -64 1466 5730 -857 2750 2868 -626 692 4241 -2945 2357 -2649 -3149 -447 1609 4363 1818 1610 -1032 936 -298 3171 4885 1940 -782 -551 666 -1965 -5647 -1518 -2802 -1594 -820 -1559 311 -2120 -4792 5405 -5368 1257 -2141 2673 -537 1038 -136 3069 1482 1325 210 287 -2269 1191 2665 -2290 1205 1513 -1433 -339 -373 -4277 332 4025 3956 -1973 -1668 -4635 -1556 -752 7988 1269 -3646 372 4979 -1082 1833 -223 4004 -2047 5416 933 -2552 4437 -1593 595 2060 2477 -1418 -3425 -2920 -804 -1029 -3155 -3388 980 -1180 1167 -994 3983 3511 5740 669 1468 18 -3417 -191 -3956 -2265 -3764 -704 -5389 -5927 -1298 250 1464 578 242 -5731 4165 1169 -493 4316 2146 -4538 -2846 -2686 -1182 -3708 545 -1863 1349 -845 -14 7559 1922 4018 1255 3127 -1225 215 -3807 -8 2084 -2729 -1066 -4646 -345 1380 2658 -332 -1109 1729 -66 1524 5806 -930 2877 2962 -659 705 4042 -2918 2185 -2582 -3177 -458 1660 4434 1890 1667 -1094 981 -318 3280 4941 1986 -806 -558 661 -1971 -5776 -1496 -2823 -1613 -837 -1595 305 -2077 -4762 4848 -5321 1181 -2088 2505 -526 1014 -134 2918 1416 1262 203 281 -2330 1186 2553 -2221 1093 1327 -1266 -290 -316 -3809 295 3661 3765 -2009 -1679 -4712 -1516 -733 7334 1262 -3830 378 4848 -1118 1873 -237 4092 -2180 5262 922 -2571 4228 -1629 597 2048 2454 -1450 -3590 -3039 -801 -1009 -3141 -3377 955 -1209 1188 -1045 4059 3630 5844 718 1571 20 -3811 -203 -4248 -2341 -3935 -726 SO 20180920T111717.9Z 6837.470346 385 1 33.71 2 88.23 90.30 139.73 294.89 0.00 1 0.00 1 0 29 1.326e-02 1.293e-02 3.744e-04 3.721e-04 1.588346e+04 2.478311e+01 1.061341e+03 -6.000000e+00 6.916225e+02 284.25 -2.00 20.00 -2.00 505.45 0.00e+00 4.142984e-03 1.007126e-05 2.212527e-04 -6.000000e+00 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