File name: Pandora103s1_Downsview_20180921_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T015656.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180921_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180921 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180921T111002.4Z 6838.465305 367 1 32.71 2 89.74 89.39 129.42 285.00 0.00 1 0.00 1 0 22 1.769e-01 1.548e-01 5.595e-02 5.196e-02 4.890914e+03 3.336330e+03 1.531161e+03 -6.000000e+00 9.229049e+03 284.13 -2.00 20.00 -2.00 505.22 0.00e+00 2.894288e-03 1.383835e-03 1.669108e-04 -6.000000e+00 4.863430e-03 284.13 -2.00 20.00 -2.00 499.88 0.00e+00 5.444457e+00 1.033378e+00 1.407884e-01 -6.000000e+00 3.396113e+00 228.34 -2.00 3.57 -2.00 501.46 0.00e+00 20.056 0.157 489.00 513.00 1 9.3348e+00 7.8660e-02 3.7083e-02 -6.0000e+00 2.5961e-01 7.4671e-02 2.0579e-02 2.2728e-03 -6.0000e+00 6.8685e-02 6.4721e-06 -1.0281e-02 3.8559e-03 8.6439e-05 -6.0000e+00 1.3789e-02 -1.1623e-01 1.2229e-03 12 9 9 12 4 4 97.11 37.60 24.03 -0.11623 -0.18755 10 2 1 4 0 3270.790 43.72 37.60 40.60 28248 -5068 16411 9321 -6039 4160 -10586 9007 -7957 -5650 29347 -8062 -8739 -31595 38321 7387 16918 2735 11035 12483 21402 -9299 3669 7634 2252 20516 28261 -11374 -3253 10958 -9166 -17723 30221 6002 1674 -1127 -2392 11629 20213 10207 4319 11103 -653 -22941 1518 1421 -2838 11488 -4906 -8197 -9590 2307 -16470 -2068 15588 -10400 6716 27581 11095 -1966 2297 16064 -17572 28544 -1232 -24028 -24554 4622 5825 17590 -346 -14631 -1066 1466 11568 6963 -1755 19089 25030 8670 -3595 -9434 1782 6034 36374 -20717 4697 13158 -13783 37632 2280 23801 -3913 -1627 21334 46785 9200 -8343 19366 31367 -36495 7005 -30105 3780 -21539 17857 -10522 -10864 -17121 -11035 32541 2433 8103 -10033 10761 -2499 39578 11203 31389 -7030 8340 3838 30843 -292 -6692 3278 24459 5518 4962 34087 29360 15553 43075 55805 1347 18197 -11180 2008 -8680 -6461 -16841 1492 -22042 -12280 -1676 10785 4993 -2498 38768 -1063 900000 21055 -5246 14197 9025 -7020 4465 -13403 9597 -10038 -6910 25040 -9747 -10499 -46549 28313 7347 15449 2926 11259 12865 20232 -11825 4112 8236 2581 19833 25260 -14874 -3876 10919 -10667 -22263 24111 6266 1909 -1346 -2863 11942 18837 10337 4611 11158 -744 -32825 1736 1638 -3400 11821 -5820 -9830 -11273 2333 -19524 -2118 13741 -12266 6909 23475 11062 -2205 2454 15074 -22975 23825 -1363 -32608 -32738 4554 5606 14862 -341 -16469 -1059 1436 10438 6564 -1757 15157 18467 7429 -3457 -9664 1644 5342 24219 -24243 4294 11005 -14847 24509 2094 17915 -3936 -1617 16741 27956 7714 -8056 13891 19493 -43029 5443 -34489 3274 -24835 14133 -10811 -10972 -18038 -10989 21670 2213 7079 -10560 9297 -2462 26163 9858 22662 -7250 7266 3426 20925 -270 -6689 2980 18140 4920 4428 23058 20827 12362 25661 29070 1183 13734 -11574 1872 -9090 -6712 -19516 1451 -27097 -13837 -1710 9727 4685 -2445 24722 -990 900000 SO 20180921T111421.3Z 6838.468302 371 1 32.65 2 88.96 90.13 130.14 285.90 0.00 1 0.00 1 0 15 8.053e-02 7.813e-02 2.766e-02 2.706e-02 6.739206e+03 1.783544e+03 4.335261e+02 -6.000000e+00 4.200772e+03 284.13 -2.00 20.00 -2.00 505.31 0.00e+00 4.846662e-03 7.239925e-04 2.578136e-04 -6.000000e+00 2.213848e-03 284.13 -2.00 20.00 -2.00 500.09 0.00e+00 4.263892e+00 5.353616e-01 7.877864e-02 -6.000000e+00 1.548525e+00 228.34 -2.00 3.57 -2.00 501.72 0.00e+00 18.524 0.124 489.00 513.00 1 8.9457e+00 4.0814e-02 3.2410e-02 -6.0000e+00 1.1833e-01 5.7508e-02 1.0576e-02 2.2824e-03 -6.0000e+00 3.1387e-02 1.2845e-05 6.4184e-03 2.0488e-03 7.3809e-05 -6.0000e+00 6.2817e-03 -1.8832e-02 4.8542e-04 12 9 9 12 12 4 99.95 37.58 8.65 -0.01883 0.02569 10 2 1 4 0 3263.920 43.72 37.58 40.60 -8530 -7706 4742 6253 21204 5228 -10663 10922 -2356 5726 -1137 -2975 3504 -1106 -14828 -6066 14476 1168 -1312 10056 3828 -4742 -5206 1363 4286 11800 14020 -6354 2378 2348 -9738 -5400 -6854 6468 -2072 13087 -4902 -979 3025 1431 -3015 -3111 -4673 -3852 16186 -8539 12219 -11166 12101 6257 8642 -13849 5104 5631 7280 -5925 6778 -5208 2298 1915 -10910 5838 -3028 -10980 9917 -6111 6977 -2285 5644 -3017 5989 382 3176 -4045 -1867 4977 -6805 -669 -6244 10643 9820 5271 -4328 7771 811 1602 14080 169 -2629 -5227 -3187 16217 -5649 7137 -15478 193 736 14148 6833 -7475 -5671 2837 18452 2141 -5336 -14267 -644 -3576 13544 -7582 871 6379 5611 -4284 -915 5657 9495 -1266 8951 6665 5103 -7928 10607 -12849 -4699 -8774 -7745 10755 9770 -6578 -2179 16841 4391 7505 -8778 4397 -10104 -3878 13414 -5898 -134 2263 -8399 -9302 4793 18839 6957 4462 -3019 4265 900000 -8711 -8022 4569 6162 18441 5416 -13118 10969 -2668 5874 -1226 -3225 3507 -1141 -17392 -6580 13098 1240 -1464 10077 4058 -5469 -6030 1495 4610 11797 13668 -7455 2469 2337 -10781 -5790 -7685 6693 -2382 12900 -5659 -1073 3150 1506 -3339 -3488 -5398 -4481 15672 -10486 12164 -13711 11649 6183 8061 -15677 4773 5345 7061 -6750 6938 -5986 2442 2030 -13130 6023 -3407 -13254 9641 -6788 6697 -2370 5346 -3045 5495 373 3048 -4228 -1917 4679 -6967 -634 -6196 8921 8333 4700 -4233 6818 769 1509 11673 159 -2520 -5139 -3101 13369 -5840 6456 -16965 177 652 10701 5405 -6645 -4953 2337 13699 1948 -5289 -15252 -592 -3322 10665 -7476 809 5709 5115 -4322 -896 5245 8600 -1276 8058 6016 4581 -7944 8931 -13785 -4682 -9113 -7983 9227 8493 -6727 -2099 13178 3833 6309 -8701 3948 -10693 -3911 11601 -6210 -134 2219 -9189 -10302 4626 15656 6304 4020 -2890 3847 900000 SO 20180921T111833.0Z 6838.471215 375 1 33.92 2 88.21 90.86 130.83 286.78 0.00 1 0.00 1 0 22 5.106e-02 4.966e-02 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