File name: Pandora103s1_Downsview_20180923_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T015720.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180923_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180923 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180923T111219.4Z 6840.466891 346 1 30.75 2 89.74 90.47 109.88 274.26 0.00 1 0.00 1 0 36 2.594e-02 2.555e-02 8.151e-03 8.106e-03 1.360256e+04 5.452304e+02 9.316200e+02 -6.000000e+00 1.351067e+03 283.88 -2.00 20.00 -2.00 505.46 0.00e+00 2.909159e-03 2.193610e-04 1.683430e-04 -6.000000e+00 7.129331e-04 283.88 -2.00 20.00 -2.00 500.92 0.00e+00 1.606899e+00 1.528521e-01 8.880856e-02 -6.000000e+00 4.999196e-01 228.10 -2.00 3.57 -2.00 502.45 0.00e+00 20.063 0.157 489.00 513.00 1 7.4882e+00 1.1676e-02 3.6759e-02 -6.0000e+00 3.8178e-02 7.5256e-03 2.9839e-03 2.9341e-03 -6.0000e+00 1.0159e-02 5.5618e-05 4.2193e-03 5.8377e-04 1.0973e-04 -6.0000e+00 2.0239e-03 -9.1028e-03 2.4364e-04 12 9 9 12 4 4 93.88 35.18 6.01 -0.00910 0.02016 8 1 1 4 0 3842.340 41.42 35.18 38.24 -5528 -6913 -3819 1714 1656 2548 4274 3608 2078 1303 -1917 2866 -426 1226 -657 -6139 -5292 -3843 315 728 -3182 3390 1934 95 5035 -120 -2964 -770 587 -4583 -541 -2980 -4702 3090 3573 655 1827 86 1788 630 -466 3064 -4 1812 78 3905 -97 4498 4306 825 -348 -1672 -592 -3627 1539 2965 -428 4123 -219 3133 -1692 1140 1050 3257 3290 -3965 136 171 520 -6936 -1320 -4002 577 -1345 1856 -504 -2882 -1187 330 -4641 -1381 -2538 -2437 -3267 2942 1763 -660 -1389 1017 894 892 218 1289 2310 1618 1142 -565 3468 -2939 -48 -4396 -2417 -4984 1887 2194 -92 1097 513 -2861 2935 -335 927 -808 4611 -1343 4774 3306 1149 1483 1477 -2571 -2282 1234 3110 877 2866 -2218 -1497 -1379 2634 -1644 -2547 -1402 -141 77 -1975 1706 -493 848 2816 0 1359 -804 -918 2426 -49 -859 -1821 -1325 -4054 900000 -4810 -6220 -3470 1542 1526 2376 4011 3446 2011 1251 -1864 2640 -399 1115 -605 -5972 -5182 -3822 311 724 -3276 3290 1904 96 4894 -123 -3104 -786 577 -4528 -505 -2864 -4699 3007 3587 677 1845 87 1764 624 -468 3008 -4 1855 82 3987 -103 4488 4243 820 -339 -1606 -556 -3545 1484 2932 -447 4156 -230 3162 -1789 1186 1099 3337 3342 -4238 137 171 513 -7223 -1290 -4034 564 -1363 1849 -508 -2893 -1149 312 -4576 -1323 -2483 -2394 -3263 2819 1723 -658 -1384 982 863 867 218 1295 2285 1560 1067 -518 2980 -2633 -41 -3901 -2154 -4776 1804 2173 -93 1092 504 -2877 2838 -341 946 -843 4587 -1412 4772 3417 1232 1582 1547 -2734 -2363 1227 3081 896 2884 -2350 -1573 -1444 2676 -1723 -2624 -1412 -140 76 -2052 1761 -526 906 3002 0 1491 -905 -1038 2657 -55 -945 -1970 -1403 -4421 900000 SO 20180923T111633.0Z 6840.469826 350 1 33.91 2 88.98 91.20 110.61 275.00 0.00 1 0.00 1 0 29 1.213e-02 1.193e-02 2.391e-04 2.379e-04 1.608211e+04 1.578962e+01 1.091118e+03 -6.000000e+00 6.317126e+02 283.88 -2.00 20.00 -2.00 505.44 0.00e+00 3.494325e-03 6.463034e-06 1.924081e-04 -6.000000e+00 3.334676e-04 283.88 -2.00 20.00 -2.00 501.03 0.00e+00 1.595163e+00 4.448906e-03 1.013348e-01 -6.000000e+00 2.339278e-01 228.10 -2.00 3.57 -2.00 502.54 0.00e+00 18.567 0.125 489.00 513.00 1 2.5489e+00 3.3881e-04 3.2864e-02 -6.0000e+00 1.7862e-02 -5.2072e-02 8.7293e-05 3.0456e-03 -6.0000e+00 4.7581e-03 9.4822e-03 2.5552e-03 1.6785e-05 1.4026e-04 -6.0000e+00 9.4635e-04 6.1570e-04 1.2436e-04 12 9 9 12 4 4 91.63 35.17 2.51 0.00062 0.01834 264 49 1 4 0 127.920 41.42 35.17 38.25 -3814 -3036 -1544 -191 521 1015 1506 1867 1673 993 370 -48 -609 -1115 -1384 -1406 -1112 -116 767 952 745 572 471 730 1059 1306 1219 1273 100 -1438 -2340 -2227 -1456 198 1395 1409 741 89 -259 -570 -425 -117 510 971 1475 1655 1494 1052 762 -86 -1156 -2105 -2669 -2358 -1122 231 1004 1151 852 635 579 1004 1229 1312 1055 502 -4 -301 -566 -1136 -1522 -1301 -845 -48 430 206 -636 -1366 -1564 -1688 -1394 -901 -825 -699 -237 18 -126 -391 -602 -454 -241 813 1792 2094 1737 1049 454 -189 -1061 -2081 -2589 -2346 -1124 496 1230 944 -14 -1090 -1574 -1113 -306 195 645 867 910 1213 1788 1958 1585 722 97 -657 -466 301 729 799 880 543 539 972 501 -298 -863 -1489 -1565 -883 -120 294 473 698 650 477 579 849 963 671 -166 -1468 -2364 -2398 900000 -3347 -2697 -1407 -170 475 941 1425 1787 1608 949 350 -45 -568 -1030 -1273 -1299 -1039 -111 752 947 704 543 448 697 1023 1265 1181 1230 96 -1410 -2257 -2159 -1432 191 1387 1415 740 89 -256 -560 -419 -116 513 991 1523 1720 1551 1085 778 -87 -1139 -2037 -2559 -2272 -1108 235 992 1150 853 635 580 1013 1249 1336 1071 505 -4 -296 -554 -1102 -1541 -1321 -821 -47 429 205 -621 -1313 -1571 -1689 -1392 -904 -792 -677 -233 18 -125 -387 -592 -443 -236 806 1800 2094 1688 1037 434 -177 -983 -1910 -2371 -2189 -1089 482 1249 976 -14 -1125 -1615 -1153 -307 198 658 885 930 1243 1863 2088 1705 771 101 -676 -473 307 753 829 919 570 564 1022 527 -309 -885 -1537 -1622 -932 -130 307 501 752 711 527 645 947 1073 747 -183 -1603 -2557 -2600 900000 SO 20180923T112023.7Z 6840.472496 354 1 9.34 2 88.29 91.86 111.27 275.67 0.00 1 0.00 1 0 15 1.027e-02 1.012e-02 2.179e-03 2.175e-03 1.286809e+04 1.421088e+02 8.693512e+02 -6.000000e+00 5.352048e+02 283.88 -2.00 20.00 -2.00 505.37 0.00e+00 2.600016e-03 5.885572e-05 1.504193e-04 -6.000000e+00 2.823215e-04 283.88 -2.00 20.00 -2.00 500.78 0.00e+00 1.591017e+00 4.126478e-02 8.372911e-02 -6.000000e+00 1.978690e-01 228.10 -2.00 3.57 -2.00 502.33 0.00e+00 16.787 0.092 489.00 513.00 1 5.7269e+00 3.1472e-03 2.8003e-02 -6.0000e+00 1.5113e-02 -9.6950e-03 8.1589e-04 2.5095e-03 -6.0000e+00 4.0182e-03 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