File name: Pandora103s1_Downsview_20180927_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T015658.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20180927_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20180927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180927T111655.3Z 6844.470085 278 1 30.69 2 89.74 92.63 67.17 257.08 0.00 1 0.00 1 0 22 5.879e-02 5.697e-02 2.383e-02 2.362e-02 1.061180e+04 1.500368e+03 7.753210e+02 -6.000000e+00 3.055755e+03 283.38 -2.00 20.00 -2.00 505.39 0.00e+00 2.719909e-03 6.339877e-04 1.345721e-04 -6.000000e+00 1.614276e-03 283.38 -2.00 20.00 -2.00 500.81 0.00e+00 4.849886e-01 4.422733e-01 6.658670e-02 -6.000000e+00 1.133423e+00 227.62 -2.00 3.57 -2.00 502.34 0.00e+00 20.077 0.158 489.00 513.00 1 8.6961e+00 3.3614e-02 3.6391e-02 -6.0000e+00 8.6532e-02 5.2371e-02 8.8061e-03 2.5802e-03 -6.0000e+00 2.3051e-02 1.8098e-05 4.6900e-03 1.7496e-03 9.1999e-05 -6.0000e+00 4.5863e-03 -1.7680e-02 2.3487e-04 12 9 9 12 4 4 99.06 36.13 5.04 -0.01768 0.01485 8 1 1 4 0 3835.820 42.30 36.13 39.06 -6676 -880 -3525 456 -2406 -5092 7923 8751 4171 2621 -1716 2146 3783 -1347 -3020 -3903 -1002 1699 7193 -1555 3889 -2840 6274 4436 9235 -3901 4291 -4999 8287 4931 -7221 -2358 -7140 -308 -2066 4957 3713 -845 -3033 180 3336 2899 -5343 1167 2646 -8445 1385 2959 -4324 -10388 -2202 -548 543 2573 798 1315 -5752 2754 -3051 2560 6645 -8363 3708 1193 -8806 4707 1455 12326 5095 250 873 1105 -6555 10437 -8546 5751 4137 -3089 390 2531 -7561 -2645 7839 8474 74 8431 -7865 4237 -4666 -9120 25581 -10001 3302 12135 7329 -5221 7606 -8099 -3367 -5334 -8231 -4958 3804 -1210 730 3623 4716 -10552 -7904 912 -4682 -2547 2419 2856 11583 11878 14403 6659 -5193 -5053 -9271 9745 7224 2290 1199 -3215 -155 1415 -6189 1897 -6003 5161 -2390 1132 1542 -3059 1566 -1347 -1583 2299 1422 1281 -3150 88 8852 -3374 4002 4410 -4148 -2090 900000 -6010 -763 -3262 423 -2356 -5219 7322 8117 4040 2537 -1701 2028 3464 -1277 -2888 -3776 -955 1625 6740 -1606 3798 -2965 5996 4337 8707 -4187 4241 -5380 7641 4489 -7232 -2265 -7343 -311 -2202 4958 3705 -870 -3150 179 3242 2857 -5788 1205 2731 -9743 1447 3004 -4641 -11541 -2185 -521 503 2363 773 1319 -6334 2815 -3291 2600 6493 -9543 3788 1248 -10069 4643 1453 10945 4813 244 835 1061 -6863 9444 -9427 5470 3894 -3053 370 2337 -7720 -2603 7005 7589 73 7755 -8461 4027 -4799 -9784 19731 -11103 3290 11068 6813 -5305 6607 -7965 -3097 -4897 -7726 -4602 3396 -1204 739 3583 4557 -11593 -8378 900 -4984 -2697 2461 2905 10834 11134 13399 6774 -5899 -5628 -10512 8974 6760 2278 1218 -3411 -160 1436 -6737 1922 -6511 4893 -2401 1093 1483 -3147 1586 -1423 -1698 2410 1514 1372 -3544 96 8890 -3785 4094 4364 -4372 -2162 900000 SO 20180927T112113.4Z 6844.473072 282 1 32.87 2 88.97 93.37 67.90 257.88 0.00 1 0.00 1 0 29 1.136e-02 1.116e-02 2.696e-03 2.684e-03 7.594622e+03 1.654211e+02 5.608791e+02 -6.000000e+00 5.906601e+02 283.37 -2.00 20.00 -2.00 505.43 0.00e+00 3.376424e-03 7.255264e-05 1.726355e-04 -6.000000e+00 3.118220e-04 283.37 -2.00 20.00 -2.00 500.97 0.00e+00 1.720854e+00 5.034078e-02 5.328733e-02 -6.000000e+00 2.187634e-01 227.62 -2.00 3.57 -2.00 502.49 0.00e+00 18.547 0.124 489.00 513.00 1 6.6363e+00 3.8397e-03 3.1907e-02 -6.0000e+00 1.6707e-02 -6.9145e-03 9.9300e-04 2.1172e-03 -6.0000e+00 4.4428e-03 1.6057e-04 2.5200e-03 2.0181e-04 8.1191e-05 -6.0000e+00 8.8647e-04 2.4376e-02 8.0846e-05 12 9 9 12 4 4 27.71 36.15 1.57 0.02438 0.04186 10 2 1 4 0 3286.040 42.30 36.15 39.08 -3226 -2898 -225 759 -1376 286 1597 1019 1781 622 441 434 -1443 -1314 -1213 -1007 -302 1154 864 52 622 -1226 121 383 2076 342 544 1151 950 -1296 -1147 -1692 -1111 715 594 1536 -643 344 -709 144 -809 29 -16 604 845 1796 39 1221 1855 -741 -413 -1030 -2494 -633 -696 58 529 668 -273 96 986 711 1894 654 1351 -492 -154 -76 -304 -2041 -928 -1017 -821 500 363 -38 784 -1970 -988 -1927 -993 -987 -1297 -243 436 731 364 -1037 319 -611 192 793 1193 2470 987 899 934 -1097 -101 -1456 -2417 -2903 -372 1099 90 883 328 -916 -1520 -245 141 175 -394 -274 1604 1725 625 1613 1216 -302 -694 -590 71 -387 914 1927 -424 9 273 1386 891 152 -559 -2646 -611 -130 91 -528 -1112 514 98 861 859 1227 949 1094 48 -1582 -1767 -2314 900000 -2776 -2532 -199 691 -1302 271 1530 991 1719 598 418 409 -1361 -1223 -1122 -933 -281 1091 842 51 612 -1227 120 380 2052 343 546 1143 924 -1236 -1074 -1600 -1067 704 604 1555 -655 343 -708 142 -807 29 -16 617 872 1846 40 1242 1854 -741 -401 -982 -2381 -601 -682 59 542 687 -283 98 1006 734 1946 678 1383 -504 -155 -76 -301 -2022 -902 -994 -810 495 364 -38 760 -1921 -949 -1860 -953 -957 -1266 -236 427 721 359 -1031 313 -602 189 791 1208 2476 983 875 888 -1037 -93 -1327 -2211 -2710 -353 1080 91 892 329 -913 -1512 -245 143 180 -411 -288 1662 1796 665 1718 1292 -320 -726 -606 72 -400 944 1977 -445 9 284 1437 922 155 -566 -2710 -615 -133 96 -563 -1205 557 107 938 941 1347 1046 1197 52 -1694 -1864 -2457 900000 SO 20180927T112523.3Z 6844.475964 286 1 34.57 2 88.22 94.09 68.61 258.65 0.00 1 0.00 1 0 29 8.389e-03 8.226e-03 6.299e-04 6.278e-04 8.932982e+03 3.907149e+01 6.190803e+02 -6.000000e+00 4.362018e+02 283.37 -2.00 20.00 -2.00 505.39 0.00e+00 3.510942e-03 1.698783e-05 1.897006e-04 -6.000000e+00 2.302972e-04 283.37 -2.00 20.00 -2.00 500.91 0.00e+00 1.326272e+00 1.184749e-02 6.583192e-02 -6.000000e+00 1.616040e-01 227.62 -2.00 3.57 -2.00 502.44 0.00e+00 16.611 0.089 489.00 513.00 1 4.7406e+00 9.0386e-04 2.7391e-02 -6.0000e+00 1.2341e-02 -1.7423e-02 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