File name: Pandora103s1_Downsview_20181009_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T015632.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20181009_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181009 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181009T113059.0Z 6856.479850 445 1 32.01 2 89.76 99.04 92.86 92.92 0.00 1 0.00 1 0 47 1.609e-01 1.418e-01 6.230e-02 5.842e-02 1.803337e+04 4.473903e+03 1.589991e+03 -6.000000e+00 8.309513e+03 281.87 -2.00 20.00 -2.00 505.38 0.00e+00 1.912298e-03 1.579692e-03 1.509978e-04 -6.000000e+00 4.400611e-03 281.87 -2.00 20.00 -2.00 500.00 0.00e+00 4.907612e+00 1.183422e+00 2.898471e-02 -6.000000e+00 3.098761e+00 226.17 -2.00 3.57 -2.00 501.65 0.00e+00 20.155 0.160 489.00 513.00 1 9.3090e+00 9.0140e-02 3.6299e-02 -6.0000e+00 2.3647e-01 3.5793e-02 2.3321e-02 2.5538e-03 -6.0000e+00 6.3028e-02 6.7864e-06 -1.0930e-02 4.0735e-03 1.2303e-04 -6.0000e+00 1.2555e-02 9.6841e-02 -4.7006e-04 12 9 9 12 4 4 99.53 34.87 16.93 0.09684 0.02102 8 1 1 4 0 4000.000 40.91 34.87 37.79 12764 5088 16551 -3125 -2269 -396 13056 -7801 10665 46663 14299 -23496 -13496 -4400 5360 -7228 11358 -13837 11201 -12104 -5350 5102 18160 1794 1756 17053 15380 -19343 -2089 -1463 46913 12823 -6050 26330 -8418 16615 -2054 3735 5611 -3830 -23138 -13137 18950 11899 26782 -9560 -11803 -5125 23994 5191 3083 24107 -12176 -720 -18240 16429 -6320 12428 8495 -17455 10460 -3080 -8549 -5783 1820 -6270 -9563 15950 -2931 14381 27592 717 19281 6156 8775 3449 -15841 1681 -6096 34661 4310 33346 44013 7201 -21207 -2375 -7580 10529 8297 23662 19390 23610 -20165 10325 -4354 2683 -8831 16478 -2327 19494 -12999 17905 20727 5537 -16250 -4790 -10628 31322 10571 -7405 9349 -7004 22955 10618 -6910 -23004 14565 -5257 421 -8688 -7374 -11804 19908 -6350 14433 -11457 3608 2832 -8276 -2294 46704 9267 -11606 -28587 18324 32003 21140 -2334 16354 20948 3064 165 -10680 -16077 35417 -2910 10837 -7894 7325 11836 900000 10636 4560 13589 -3241 -2427 -425 12569 -9400 10832 33265 13729 -32117 -16552 -4858 5309 -8058 10611 -16820 11017 -15421 -6424 5527 17321 2007 1977 16702 15299 -26905 -2437 -1643 31425 11787 -6738 21937 -10323 16489 -2439 4121 6000 -4427 -32024 -16527 17624 11987 23663 -12153 -15362 -6190 21483 5482 3229 19841 -13884 -725 -22014 14681 -7302 12203 8699 -22845 10340 -3475 -10249 -6762 1970 -7249 -11178 14228 -3100 12697 21000 701 15795 5790 8178 3415 -18622 1615 -6174 23301 3859 22497 26943 6330 -24815 -2350 -7935 9184 7306 17698 15040 17676 -23523 9063 -4331 2387 -8381 11705 -1928 12824 -11498 11693 13536 4437 -17255 -4744 -11235 21751 8805 -7281 7926 -7108 17551 9162 -7059 -27408 12119 -5442 421 -9484 -7793 -12666 15246 -6223 11717 -12106 3302 2627 -8532 -2227 28344 8004 -11958 -34442 13986 21546 16279 -2323 13734 17088 3032 170 -12335 -19691 26297 -3133 10129 -8697 6789 10343 900000 SO 20181009T113513.1Z 6856.482790 449 1 32.15 2 89.01 99.77 92.14 93.64 0.00 1 0.00 1 0 22 9.483e-02 8.746e-02 3.500e-02 3.388e-02 2.162765e+03 2.012577e+03 1.736215e+02 -6.000000e+00 4.883495e+03 281.87 -2.00 20.00 -2.00 505.29 0.00e+00 4.916729e-03 8.988883e-04 1.111344e-04 -6.000000e+00 2.590039e-03 281.87 -2.00 20.00 -2.00 499.80 0.00e+00 5.614129e+00 6.702924e-01 2.377217e-02 -6.000000e+00 1.834060e+00 226.17 -2.00 3.57 -2.00 501.48 0.00e+00 18.689 0.127 489.00 513.00 1 8.9024e+00 5.1022e-02 3.1808e-02 -6.0000e+00 1.3969e-01 6.4159e-02 1.3511e-02 1.7734e-03 -6.0000e+00 3.7699e-02 1.1934e-05 2.5667e-02 2.5085e-03 4.2298e-05 -6.0000e+00 7.3883e-03 1.0445e+00 -7.5485e-03 12 9 9 12 772 260 43.68 34.90 4.81 1.04453 1.22257 8 1 1 4 0 4000.000 41.03 34.90 37.83 900000 -12052 12208 -2043 1314 16889 -7800 -7213 444 16293 639 -8264 12589 -3391 2285 35107 -9599 -2252 369 -8700 7062 -844 2913 3563 6139 -2045 -730 -7251 -5634 -3451 -6020 -177 5065 7224 -3522 2357 34 -479 -6763 10305 -7036 -1742 -2650 11423 -2391 4378 -11446 -3704 14675 531 1027 -2892 5626 -9152 -2106 -9545 3532 -4011 10513 119 -4841 -1411 18169 -844 5928 -2618 9963 2379 -9603 13122 -340 18106 7762 -2053 4887 -5637 2188 -10217 4068 -7831 8997 8157 -11719 20312 345 12346 8405 16419 20477 22773 -11106 15057 3228 881 5204 11548 -10139 9311 -17771 1756 11530 13806 6205 9078 11209 -8721 -3481 -4237 -13030 -14585 -1021 7439 5933 -11188 5281 -10429 -1419 -7848 10410 -15986 3410 3524 5828 1606 3365 548 1017 -4744 5044 -1444 -4697 9061 843 3315 -10195 -11799 -12346 -17504 -2851 -11085 1949 14395 -1568 5345 15487 5311 19334 -2749 19874 -1890 12041 900000 -13738 11478 -2269 1438 16233 -9657 -8881 500 15397 694 -9639 11785 -3669 2337 26338 -11370 -2567 418 -10717 7445 -962 3207 3939 6654 -2395 -840 -8742 -6403 -3700 -6590 -185 5225 7642 -4202 2624 39 -533 -7884 10148 -8267 -1966 -3062 11673 -2816 4818 -14524 -4288 13925 560 1040 -2974 5283 -10127 -2259 -11362 3757 -4587 10371 129 -5516 -1565 16667 -925 5992 -2813 9276 2352 -10521 11283 -329 14735 7050 -2083 4658 -5838 2038 -10524 3616 -7764 7597 6989 -12163 15490 322 10293 7241 12976 15467 16805 -11459 12273 3014 843 4696 9606 -10176 7511 -18119 1442 8518 10104 5060 7521 9270 -8662 -3222 -3868 -12837 -14792 -929 6366 5245 -11824 4779 -11052 -1390 -8215 9028 -17594 3056 3105 5000 1458 3033 508 941 -4637 4474 -1375 -4603 7596 751 2848 -9924 -11844 -12847 -19550 -2794 -11913 1854 12141 -1554 4992 13158 4963 15462 -2637 14867 -1737 9819 SO 20181009T113929.0Z 6856.485752 453 1 32.01 2 88.25 100.51 91.40 94.36 0.00 1 0.00 1 0 29 5.421e-02 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