File name: Pandora103s1_Downsview_20181114_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T015603.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20181114_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181114 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181114T121737.0Z 6892.512234 497 1 32.01 2 89.77 116.01 147.40 48.79 0.00 1 0.00 1 0 22 2.495e-01 1.864e-01 2.093e-01 1.855e-01 1.077729e+04 1.278137e+04 2.638643e+02 -6.000000e+00 1.266258e+04 277.28 -2.00 20.00 -2.00 505.27 0.00e+00 -2.093741e-03 5.012348e-03 2.160423e-04 -6.000000e+00 6.744009e-03 277.28 -2.00 20.00 -2.00 499.83 0.00e+00 1.583035e+00 3.687926e+00 1.758805e-01 -6.000000e+00 4.770935e+00 222.65 -2.00 3.57 -2.00 501.52 0.00e+00 20.306 0.163 489.00 513.00 1 1.0813e+01 2.8197e-01 3.9153e-02 -6.0000e+00 3.6408e-01 1.3779e-01 7.1822e-02 3.5430e-03 -6.0000e+00 9.6323e-02 1.9848e-06 8.6277e-04 1.3199e-02 9.2056e-05 -6.0000e+00 1.9429e-02 -1.1101e-01 1.2339e-03 12 8 8 10 0 0 11.00 14.99 6.17 -0.11101 -0.10503 8 1 1 4 0 4000.000 21.69 14.99 18.42 -12253 -19178 543 532 10488 -14849 10444 -20807 17499 -16747 -5789 -2849 15422 -22520 -5382 7229 3814 -2993 -12885 14439 22064 7725 -10028 19417 28301 15281 5885 34145 6769 -6899 -1606 32554 -18331 18407 -13202 14477 13763 30882 -3333 12304 -19767 20971 4655 15041 -2242 -12562 8749 27290 -22441 -6054 31924 6294 33447 7729 1274 -18555 -2243 -5893 43142 -8172 101278 1937 29739 3537 30396 -2615 14753 5205 17145 33626 -29870 -3068 8105 7725 -25419 1480 16250 -12991 4418 41224 25904 55340 -8748 37429 13656 -731 21638 -16604 10620 -13781 3394 -14294 21393 -17800 -9941 -1544 15371 8910 22305 18630 6130 -24958 37262 16460 3552 7001 -14007 43959 42856 10424 -10127 -15082 -15110 78595 -11311 12210 20548 54245 -18192 35171 10893 117573 -14320 -481 -21749 35317 13393 -1521 -15991 2707 -1783 -5385 35087 -9256 -9667 17212 34902 -10628 40443 -7629 -9722 10310 25265 -6666 41616 -19614 -3085 -40490 42691 15187 900000 -13685 -23354 569 579 10581 -19465 10981 -29788 17326 -22625 -6936 -3285 14692 -30364 -6122 7330 4062 -3514 -17156 14920 21154 8500 -13036 19112 25725 15663 6558 28827 7183 -7985 -1739 25664 -24073 17825 -17803 14925 14064 26418 -3889 12225 -26684 19267 5043 14907 -2640 -16297 9158 23562 -30567 -6839 24224 5926 24026 7182 1304 -23758 -2501 -6814 31084 -9509 41993 2062 24342 3699 24318 -2807 13164 5026 14612 24087 -38818 -3109 7481 7291 -33184 1469 13619 -14095 4027 26383 19262 31493 -9174 25638 11916 -737 17576 -19287 9463 -15484 3258 -16510 17761 -21100 -10554 -1459 11950 7168 15485 13161 4896 -27636 24171 13795 3463 6596 -15858 28076 27402 9166 -10996 -17283 -17330 37103 -12437 10806 17099 33142 -21872 24913 9465 36780 -15391 -458 -25491 24039 11218 -1457 -17557 2497 -1688 -5142 22612 -9032 -9538 13548 23824 -11304 26883 -8106 -10601 9344 19984 -7152 28173 -23494 -3081 -56222 26505 12291 900000 SO 20181114T122152.0Z 6892.515185 501 1 32.01 2 89.08 116.75 146.84 50.22 0.00 1 0.00 1 0 50 1.130e-01 1.062e-01 1.238e-01 1.193e-01 -4.054006e+03 6.258820e+03 8.213602e+02 -6.000000e+00 5.727371e+03 277.28 -2.00 20.00 -2.00 505.15 0.00e+00 1.627716e-03 3.158131e-03 7.826453e-05 -6.000000e+00 3.056586e-03 277.28 -2.00 20.00 -2.00 499.76 0.00e+00 2.156681e+00 2.300891e+00 1.643286e-02 -6.000000e+00 2.176096e+00 222.65 -2.00 3.57 -2.00 501.43 0.00e+00 18.973 0.133 489.00 513.00 1 1.0493e+01 1.7639e-01 3.2510e-02 -6.0000e+00 1.6577e-01 1.5737e-01 4.6326e-02 1.9577e-03 -6.0000e+00 4.4367e-02 3.1935e-06 4.2087e-02 8.9551e-03 9.5937e-05 -6.0000e+00 8.8149e-03 9.8281e-02 -1.3960e-03 12 8 8 10 0 0 4.51 15.00 8.84 0.09828 0.39021 8 1 1 4 0 4000.000 21.69 15.00 18.44 900000 -4859 7378 8071 -3066 6139 2936 9374 -7157 2975 11267 -2274 -1256 609 -10962 5866 -6665 -4062 -7667 17320 -3399 7231 6491 -7698 7805 2846 2152 -8604 -648 -12338 15595 -1089 15713 -11446 -1227 11403 -5584 2388 24252 -12579 -3989 -1895 18226 -3969 -2802 -8172 16078 -6893 1564 3841 -1771 -5596 -5492 -8503 -1009 -5508 5976 24039 3926 -2495 11005 5641 -13549 15726 -16110 299 9895 4513 24670 -588 10462 -9105 -8645 -8328 -8370 -19466 23997 6968 2432 7624 10841 7391 3346 9806 833 -1334 22904 -16516 4586 673 12955 19207 16482 -2418 -4126 -17653 10239 14166 -3881 4823 15119 -1468 -917 25118 14093 17525 -3176 -17949 4936 -5372 -6341 -3971 -16535 -9860 4615 -23124 6474 1086 -20705 -5876 12303 -6587 14561 21726 15460 6448 31385 15895 15676 589 -13913 -7847 13474 442 -71 -2514 -5553 -3557 22320 18334 2056 11392 3284 -17954 432 16832 5900 1689 -11118 1625 -2308 900000 -5363 7515 8340 -3591 6707 3335 9961 -8753 3238 11180 -2527 -1360 643 -12973 5988 -7901 -4838 -9513 16823 -4028 7724 7006 -9598 8354 3179 2398 -10304 -687 -14354 13931 -1168 15016 -14683 -1421 11496 -6540 2548 20751 -15364 -4520 -2124 17060 -4643 -3243 -9858 15116 -7943 1614 3740 -1769 -5710 -5653 -9345 -1067 -6214 6053 20327 4000 -2702 10534 5700 -16425 14190 -19373 301 8947 4249 18771 -563 9035 -9605 -9235 -8968 -8893 -22380 17792 6034 2194 6578 9161 6469 3055 8517 793 -1295 17572 -18519 4209 645 11207 15996 14210 -2484 -4277 -20594 8882 11465 -3636 4119 11840 -1390 -896 19320 11820 13881 -2999 -19311 4306 -5284 -6429 -4016 -19131 -10756 4390 -28767 6011 1043 -24050 -5835 10127 -6501 11882 16607 12507 5684 21642 12694 12616 544 -14430 -7509 10315 380 -62 -2329 -5399 -3428 16884 14390 1883 9601 3017 -20301 406 13143 4927 1429 -10620 1396 -2111 SO 20181114T122602.0Z 6892.518079 505 1 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