File name: Pandora103s1_Downsview_20181117_L2Fit_fwvt1c8d20171203p1-8.txt File generation date: 20241101T015706.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v8d20171203.txt Level 1 file used: Pandora103s1_Downsview_20181117_L1_smca1c8d20171203p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0006 492.1218 492.2430 492.3641 492.4852 492.6063 492.7274 492.8485 492.9696 493.0906 493.2117 493.3327 493.4537 493.5746 493.6956 493.8165 493.9375 494.0584 494.1793 494.3002 494.4210 494.5419 494.6627 494.7835 494.9043 495.0251 495.1458 495.2666 495.3873 495.5080 495.6287 495.7494 495.8700 495.9907 496.1113 496.2319 496.3525 496.4730 496.5936 496.7141 496.8347 496.9552 497.0757 497.1961 497.3166 497.4370 497.5574 497.6778 497.7982 497.9186 498.0389 498.1593 498.2796 498.3999 498.5202 498.6404 498.7607 498.8809 499.0011 499.1213 499.2415 499.3617 499.4818 499.6020 499.7221 499.8422 499.9623 500.0823 500.2024 500.3224 500.4424 500.5624 500.6824 500.8023 500.9223 501.0422 501.1621 501.2820 501.4019 501.5217 501.6416 501.7614 501.8812 502.0010 502.1208 502.2405 502.3603 502.4800 502.5997 502.7194 502.8390 502.9587 503.0783 503.1979 503.3175 503.4371 503.5567 503.6762 503.7958 503.9153 504.0348 504.1543 504.2737 504.3932 504.5126 504.6320 504.7514 504.8708 504.9901 505.1095 505.2288 505.3481 505.4674 505.5867 505.7059 505.8252 505.9444 506.0636 506.1828 506.3019 506.4211 506.5402 506.6594 506.7785 506.8975 507.0166 507.1356 507.2547 507.3737 507.4927 507.6117 507.7306 507.8496 507.9685 508.0874 508.2063 508.3252 508.4440 508.5629 508.6817 508.8005 508.9193 509.0381 509.1568 509.2756 509.3943 509.5130 509.6317 509.7503 509.8690 509.9876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181117T122129.0Z 6895.514919 482 1 32.01 2 89.78 117.10 145.34 349.71 0.00 1 0.00 1 0 36 1.451e-01 1.341e-01 1.426e-01 1.363e-01 4.014784e+03 8.228730e+03 4.987342e+02 -6.000000e+00 7.350320e+03 276.92 -2.00 20.00 -2.00 505.35 0.00e+00 1.107807e-04 3.586495e-03 5.656680e-05 -6.000000e+00 3.922920e-03 276.92 -2.00 20.00 -2.00 500.04 0.00e+00 3.913123e+00 2.630723e+00 1.513614e-02 -6.000000e+00 2.790823e+00 222.53 -2.00 3.57 -2.00 501.74 0.00e+00 20.334 0.164 489.00 513.00 1 1.0312e+01 2.0089e-01 3.6573e-02 -6.0000e+00 2.1269e-01 7.3750e-02 5.2069e-02 2.0325e-03 -6.0000e+00 5.6721e-02 2.7739e-06 2.9786e-02 1.0178e-02 4.7626e-05 -6.0000e+00 1.1318e-02 1.0722e-03 9.9187e-05 12 8 8 10 0 0 0.79 15.00 9.36 0.00107 0.20768 8 1 1 4 0 4000.000 21.58 15.00 18.30 23488 23480 23144 -7765 -7473 -1219 6908 1778 -6023 3371 6475 -3918 54 -11328 -7173 -25298 -20725 9572 22840 -4059 -6852 7543 -21935 23794 -2804 2958 23495 8026 5409 9784 -11695 24438 -13241 23335 8714 10843 -13409 2823 4359 9144 28380 -3702 16149 -6265 18723 -16094 8662 -24033 28478 17538 4597 10463 -6670 -5524 18677 -10162 13561 22787 17841 767 -4715 6662 -11821 4393 -14144 -473 -3157 -3915 9275 9813 3782 6927 -5575 18477 -6474 -5204 -22300 7943 -558 15672 -8392 -5787 15391 10 1850 30812 11673 -803 11555 -6578 6827 4353 22371 -876 13096 -13838 -8932 -2377 29309 32223 5896 12257 -10042 15708 -2629 -14191 13560 -4305 4230 -2609 -7277 24629 35633 -1958 -7516 -8190 1197 29610 -13711 -7771 -19473 -8843 -8477 31861 12533 -9594 -20474 13797 -2276 14232 -8514 5021 -13710 2632 3443 -16932 17750 -2187 10757 -7420 40670 9360 -4116 -1239 -18112 4065 -210 2514 30248 13457 900000 18204 18962 19417 -8943 -8769 -1371 7244 1947 -6980 3521 6487 -4268 56 -13048 -8001 -34311 -27822 9857 20761 -4774 -8281 7944 -30885 21682 -3286 3268 21044 8028 5333 9177 -13622 20762 -16961 21495 9152 10986 -16934 3001 4534 9113 23711 -4252 15523 -7522 17632 -20918 8733 -32541 22533 14874 4305 9180 -7039 -5999 16564 -12075 12812 19541 15947 810 -5282 6698 -14126 4420 -16651 -479 -3246 -3998 8191 8569 3523 6350 -5869 15488 -6748 -5210 -25887 6841 -520 12600 -8566 -5776 12672 10 1764 22186 10041 -777 9945 -6795 6319 4178 17865 -853 10893 -14502 -8687 -2117 18943 20361 4924 10112 -10746 13290 -2621 -15499 11114 -4175 3844 -2578 -7626 19176 25079 -1978 -8072 -8949 1195 22188 -15280 -8025 -22168 -9136 -8846 22634 10715 -10148 -23914 11629 -2247 11793 -8585 4392 -14246 2357 3154 -19363 14752 -2231 9788 -8069 28047 8782 -4419 -1293 -21949 3869 -202 2330 21699 11582 900000 SO 20181117T122520.1Z 6895.517593 486 1 32.14 2 89.16 117.77 145.44 351.31 0.00 1 0.00 1 0 15 7.287e-02 7.016e-02 6.911e-02 6.786e-02 7.106481e+03 4.313268e+03 7.351953e+02 -6.000000e+00 3.690984e+03 276.92 -2.00 20.00 -2.00 505.22 0.00e+00 3.952818e-04 1.799320e-03 4.801735e-05 -6.000000e+00 1.969036e-03 276.92 -2.00 20.00 -2.00 500.03 0.00e+00 6.412413e-01 1.329874e+00 5.802447e-03 -6.000000e+00 1.400044e+00 222.53 -2.00 3.57 -2.00 501.66 0.00e+00 19.174 0.137 489.00 513.00 1 9.9980e+00 1.0127e-01 3.3020e-02 -6.0000e+00 1.0672e-01 1.4554e-01 2.6620e-02 1.8986e-03 -6.0000e+00 2.8422e-02 5.7405e-06 5.3650e-04 4.9795e-03 7.9591e-05 -6.0000e+00 5.6834e-03 2.1172e-02 5.8623e-05 12 8 8 10 0 0 17.03 14.99 3.16 0.02117 0.02489 8 1 1 4 0 4000.000 21.58 14.99 18.31 -1812 5095 -16760 9313 -7188 -1553 1998 -3812 -3275 -5667 2323 -2047 10551 -9482 4081 -4484 7517 2879 2906 -575 7491 7864 9283 -295 14298 -4463 5012 -5944 2444 -6526 -1931 5679 707 7898 3897 5526 -4162 -3051 -8647 27173 -3606 -1263 -7098 5525 4510 -1781 -4419 299 -13188 2043 -5428 7336 -4086 -2169 -10340 -5125 667 12159 5701 -858 8452 5285 12098 -117 -2556 6566 12627 -12354 3916 -7006 1758 2411 6020 -1593 4600 18494 5342 1262 -7503 341 -1321 -8030 1524 4260 1712 -8499 -7301 4571 12370 -5351 -4097 5964 269 3512 47 4382 -3213 14379 6599 238 -2886 -8844 -5839 -5011 577 -173 -2878 1090 -36 -2534 6349 3258 -7560 -11143 7219 10751 2078 -4621 1252 -557 8144 685 -8162 14305 -3166 11484 7703 11271 -11999 7028 -7042 -3626 -10028 11546 449 5041 5522 15467 -7871 9340 4718 -6805 -4649 12746 -2615 2968 -4566 -6519 -4489 -9016 900000 -1762 4698 -19775 8896 -8261 -1720 2186 -4468 -3818 -6664 2480 -2253 10113 -10848 4053 -4841 7305 3006 3137 -651 7823 8185 9509 -332 14067 -5272 5368 -7042 2608 -7252 -1995 5459 726 7887 4211 5919 -4824 -3445 -10160 22267 -3977 -1369 -8227 5732 4779 -2012 -5090 324 -16029 2089 -5759 6663 -4071 -2128 -11329 -5551 700 11510 5725 -911 8170 5307 11425 -124 -2756 6366 11306 -13884 3724 -7283 1654 2260 5508 -1595 4406 15372 4911 1178 -7543 316 -1244 -8161 1419 3887 1627 -9007 -7646 4246 10589 -5432 -4123 5523 268 3398 46 3987 -3055 11187 5399 202 -2506 -8269 -5519 -4974 563 -171 -2873 1024 -33 -2442 5720 3067 -7973 -12211 6616 9538 2029 -4865 1238 -549 7226 638 -8186 11656 -3082 9682 6739 9482 -12574 6152 -7022 -3409 -9839 9102 393 4290 4817 12459 -8039 8177 4345 -7026 -4725 10988 -2617 2795 -4530 -6386 -4202 -8787 900000 SO 20181117T122917.0Z 6895.520336 490 1 32.01 2 88.54 118.46 145.52 352.95 0.00 1 0.00 1 0 15 4.476e-02 4.394e-02 4.576e-02 4.518e-02 4.009035e+03 2.705826e+03 3.511336e+02 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