File name: Pandora103s1_Downsview_20181123_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T015655.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20181123_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181123T122912.0Z 6901.520278 337 1 32.01 2 89.78 119.10 90.64 293.64 0.00 1 0.00 1 0 43 2.107e-01 1.659e-01 1.772e-01 1.632e-01 2.011167e+04 1.171102e+04 8.913017e+02 -6.000000e+00 1.064591e+04 276.24 -2.00 20.00 -2.00 505.28 0.00e+00 1.823097e-04 4.372997e-03 1.157215e-04 -6.000000e+00 5.699203e-03 276.24 -2.00 20.00 -2.00 500.11 0.00e+00 1.516467e+00 3.189617e+00 8.004447e-02 -6.000000e+00 4.086974e+00 222.46 -2.00 3.57 -2.00 501.74 0.00e+00 20.343 0.164 489.00 513.00 1 1.0603e+01 2.4557e-01 3.7273e-02 -6.0000e+00 3.1073e-01 8.7988e-02 6.1858e-02 2.8689e-03 -6.0000e+00 8.4051e-02 2.3625e-06 3.3539e-02 1.1258e-02 1.1047e-04 -6.0000e+00 1.6476e-02 7.6813e-02 -9.6495e-04 12 8 8 10 0 0 -8.86 15.00 14.43 0.07681 0.30945 8 1 1 4 0 4000.000 21.69 15.00 18.43 900000 -21720 13549 7432 22802 -1463 9115 -19036 21475 -13443 -9309 6685 46697 37866 2770 -9549 -3404 983 14349 14693 -12692 11712 -8509 6341 1724 24175 5762 15265 -21420 -11909 17920 47301 -524 -11585 -10296 2351 14499 -7102 19260 5320 -30634 18149 47702 -4903 -3838 -7 16277 -11879 34200 -14186 21483 -17529 9323 -1910 65681 -3703 7252 18582 2774 18825 7529 23 -6666 8237 7741 -9480 -15830 7146 3567 36565 521 11497 -8584 6167 -26216 13828 -19581 27452 -18323 3500 534 4594 -16025 -3168 6930 -13378 37462 -4987 17784 1531 1300 -14126 54637 17212 4932 7147 9336 -21461 5489 -13960 -11874 -1572 17039 -5734 385 36320 3138 21818 -15337 39842 -7276 6804 -18800 49437 -17619 13132 -3454 40855 -12619 12847 -13962 41153 13562 4373 3542 6525 -5124 11836 10877 12697 -1301 -3076 23032 -12278 94117 -13585 57592 -20656 26842 -10190 -3302 -13745 22870 -1708 16262 -13177 14375 -17953 -1652 31900 900000 -26526 12270 7306 19720 -1631 9288 -25398 19104 -16452 -10834 6570 30856 27034 2778 -10953 -3792 1085 14072 14333 -16120 11767 -10423 6785 1926 21687 6127 14407 -27513 -13691 15562 31739 -582 -14838 -13022 2593 14053 -8344 17398 5496 -45106 16873 33899 -5827 -4524 -8 15468 -14549 26222 -16692 17448 -20387 8458 -2003 37418 -4188 7421 16962 2927 17028 7652 26 -7788 8250 7646 -10828 -18973 6799 3453 25525 515 10373 -9564 6037 -34588 12070 -23019 20314 -20872 3231 511 4259 -18303 -3260 6533 -15280 26030 -5136 14648 1480 1280 -16352 32262 13892 4259 5769 7157 -21737 4218 -12874 -11024 -1401 13682 -6024 387 25709 2989 17164 -17407 27167 -7846 6391 -22464 30560 -20779 11809 -3733 28972 -14655 11344 -15442 26453 11464 4082 3338 6002 -5257 10266 9577 10876 -1239 -2942 17184 -12915 36894 -15278 33155 -25490 21405 -11739 -3589 -16608 19443 -1832 14571 -15403 12593 -21093 -1662 23622 SO 20181123T123325.0Z 6901.523206 341 1 32.01 2 89.11 119.84 91.30 294.35 0.00 1 0.00 1 0 15 1.106e-01 1.015e-01 9.403e-02 9.091e-02 2.960539e+03 5.290093e+03 4.675797e+02 -6.000000e+00 5.588734e+03 276.24 -2.00 20.00 -2.00 505.15 0.00e+00 8.115333e-03 2.405325e-03 4.756096e-04 -6.000000e+00 2.983523e-03 276.24 -2.00 20.00 -2.00 499.93 0.00e+00 1.498416e+00 1.813957e+00 7.741665e-02 -6.000000e+00 2.124170e+00 222.46 -2.00 3.57 -2.00 501.54 0.00e+00 19.071 0.135 489.00 513.00 1 1.0113e+01 1.3893e-01 3.4953e-02 -6.0000e+00 1.6192e-01 1.5976e-01 3.6515e-02 1.9106e-03 -6.0000e+00 4.3078e-02 4.3688e-06 5.2008e-03 6.7111e-03 1.0590e-04 -6.0000e+00 8.6252e-03 -4.6834e-03 1.7842e-04 12 8 8 10 0 0 -6.16 15.01 6.32 -0.00468 0.03139 8 1 1 4 0 4000.000 21.69 15.01 18.45 -7928 19220 -1075 14969 4907 7124 12776 -1968 -7018 555 -15294 -11330 23021 -4538 17511 -5231 12903 -5892 2041 336 -778 5349 28326 -14107 1804 11200 -363 -2649 -7948 2593 -3660 19766 -747 -2323 -8975 6641 -3693 6374 -4490 455 -19546 8961 22542 -3857 1359 3345 6177 8766 37 -10749 16278 6084 -7598 -3239 -10677 6139 -14776 14154 17789 1732 14109 -2170 2631 -6883 -5182 3926 -2851 -12726 10145 15604 -14589 17601 -13251 10645 4818 479 -9405 -11714 3001 3517 173 5319 -5951 -7901 -8720 4274 4854 1744 9379 -5745 5820 -2464 716 11746 9734 -15572 12349 -9893 28662 -456 -5625 -5230 -11108 -10381 37844 -7237 445 734 20153 2094 834 9254 -2229 8987 5773 -15038 -1330 10988 -15051 6160 -5991 2679 4156 11092 -6280 14814 518 3224 -9369 19462 97 12191 8660 -7539 -427 6894 -106 -1436 31815 1135 8740 -15505 3693 -8878 21517 3150 -4741 -3114 24364 -15718 -8410 16023 -1135 14084 5198 7517 13000 -2322 -8627 620 -19475 -13682 19562 -4948 15296 -5701 11926 -6703 2208 371 -862 5586 23665 -17890 1983 11263 -406 -3007 -9188 2579 -3792 16424 -775 -2563 -10900 6911 -4179 6450 -4985 479 -25164 8869 19906 -4471 1517 3676 6561 8949 41 -12691 14293 5750 -8105 -3359 -12333 6253 -18811 13672 16528 1867 13519 -2456 2852 -8148 -5961 4052 -3077 -14913 9409 13453 -16629 14753 -15111 9778 4718 482 -10110 -12626 2784 3226 165 4837 -6023 -8168 -9171 3970 4453 1633 8095 -5736 5235 -2455 709 10486 8719 -17469 10329 -9962 19316 -396 -5077 -4757 -11066 -10690 24781 -7221 404 651 14776 1863 770 8054 -2206 8069 5370 -17200 -1344 9849 -17098 5585 -5996 2424 3712 9407 -6335 12194 490 2956 -9702 15333 91 9895 7138 -7168 -378 5802 -98 -1358 22027 1064 7601 -17031 3383 -9217 16633 2868 -4520 -2818 16573 -15823 SO 20181123T123731.0Z 6901.526053 345 1 32.01 2 88.47 120.55 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