File name: Pandora103s1_Downsview_20181225_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T021755.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20181225_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181225T125719.0Z 6933.539803 249 1 32.01 2 89.79 123.60 66.62 272.73 0.00 1 0.00 1 0 15 7.833e-02 7.522e-02 8.080e-02 7.900e-02 -3.024374e+03 4.163220e+03 4.227984e+02 -6.000000e+00 3.908505e+03 273.10 -2.00 20.00 -2.00 505.18 0.00e+00 1.127961e-03 2.097856e-03 3.025678e-05 -6.000000e+00 2.096804e-03 273.10 -2.00 20.00 -2.00 499.83 0.00e+00 2.758604e+00 1.566077e+00 1.675486e-02 -6.000000e+00 1.508077e+00 222.56 -2.00 3.57 -2.00 501.51 0.00e+00 20.428 0.166 489.00 513.00 1 9.8164e+00 1.2009e-01 3.6760e-02 -6.0000e+00 1.1481e-01 1.5310e-01 3.1511e-02 2.0215e-03 -6.0000e+00 3.0596e-02 5.0186e-06 6.9329e-03 5.9892e-03 5.2373e-05 -6.0000e+00 6.1080e-03 -2.9028e-03 1.2279e-04 12 8 8 10 0 0 -9.46 15.00 2.97 -0.00290 0.04519 8 1 1 4 0 4000.000 21.58 15.00 18.29 -1129 5703 704 5401 -4403 6370 1954 -2157 -13186 -3212 -15244 -2475 -1091 6587 -9197 -10780 11309 10071 -1454 -3822 909 2859 10357 6011 3312 -2275 -818 -6443 5725 247 8930 -4455 1962 -8101 -8478 11590 9662 3893 3437 1870 -162 9233 -8202 -1670 -195 5145 -894 1852 958 4375 392 3346 2371 3184 -7442 6440 -2611 12667 1050 2160 12452 8902 4844 4328 3192 -6347 12547 9709 -2741 -11172 3394 -10080 -451 -3618 1320 -3976 -5364 12018 -596 -7678 -6414 -16172 7022 1508 13424 8374 -6967 11949 2414 -4233 -4768 12815 564 -7779 -1865 5521 5174 895 -9969 16453 -7189 -2709 -11753 24988 3263 11723 11176 -5593 -917 5240 -10493 -3834 11212 19632 6320 -8692 5305 -4139 12752 -9454 -3989 5066 -5987 4230 -6279 12527 4640 -6972 7041 2383 -1202 13698 -4786 -8220 -7655 -331 -8749 5855 8030 -7920 -6110 11226 6966 5797 -5078 13996 -12373 -3110 -11370 1168 -1117 5397 727 5537 -5065 6728 2198 -2545 -17237 -3739 -19603 -2778 -1187 6547 -10582 -12650 10873 10105 -1681 -4549 1029 3177 10678 6492 3695 -2673 -942 -7767 5933 258 8424 -4815 2043 -9748 -10543 11817 9874 4143 3618 1979 -175 9176 -9761 -1888 -219 5488 -1001 1985 1016 4360 391 3157 2228 3007 -8072 6324 -2850 11947 1101 2222 11595 8636 4896 4375 3220 -6881 11102 8713 -2741 -11887 3101 -10555 -435 -3662 1284 -4005 -5322 9887 -550 -7566 -6286 -17594 6107 1392 11176 7351 -7085 10088 2236 -4194 -4777 11032 557 -8368 -1875 5118 4736 829 -9948 12416 -6790 -2492 -12224 18909 3063 9943 9305 -5353 -832 4544 -10816 -3780 9734 15885 5838 -9312 4970 -4217 10830 -9767 -3855 4431 -5847 3793 -6238 10348 4133 -6906 6096 2170 -1119 10776 -4413 -7710 -7120 -293 -8667 5119 6947 -8041 -6087 9463 6170 5232 -5099 11542 -12774 -2830 -10975 1003 SO 20181225T130113.0Z 6933.542512 253 1 32.01 2 89.20 124.28 67.31 273.35 0.00 1 0.00 1 0 15 6.357e-02 6.339e-02 5.943e-02 5.836e-02 6.888822e+02 3.091359e+03 5.122597e+01 -6.000000e+00 3.171766e+03 273.10 -2.00 20.00 -2.00 505.21 0.00e+00 -1.238688e-03 1.523723e-03 1.444150e-04 -6.000000e+00 1.702159e-03 273.10 -2.00 20.00 -2.00 499.92 0.00e+00 1.723502e+00 1.141789e+00 1.961626e-02 -6.000000e+00 1.224932e+00 222.56 -2.00 3.57 -2.00 501.58 0.00e+00 19.335 0.141 489.00 513.00 1 9.7600e+00 8.6953e-02 3.3557e-02 -6.0000e+00 9.3237e-02 1.4566e-01 2.3338e-02 1.8441e-03 -6.0000e+00 2.4880e-02 6.8661e-06 -4.6805e-03 4.4226e-03 2.4404e-05 -6.0000e+00 4.9557e-03 -1.6993e-02 1.2727e-04 12 8 8 10 0 0 -8.51 15.00 2.24 -0.01699 -0.04946 8 1 1 4 0 4000.000 21.58 15.00 18.29 -6439 -6982 -4047 3543 4961 1686 2318 2994 -4438 -2223 -3126 6643 -5892 2683 -10750 7884 1378 7174 5057 10126 -299 2568 3348 3524 2742 10322 3005 -1437 4106 -3312 8366 -4463 2103 -6008 -2187 -13679 5747 -3905 1785 -9976 -2396 -7970 8305 -9097 3857 2715 -9272 2892 -670 15074 5630 4496 4797 2515 -11422 3236 681 2940 2755 -1496 -4393 8809 -3830 6225 -4337 9214 483 5096 1530 8648 2411 -7212 -1006 2243 3702 -15062 3430 -5361 2686 -5983 1232 -4942 5199 -2251 -2733 2942 3985 3034 125 6915 2390 9343 5249 6055 -5182 2205 -3689 1031 -1437 7723 -2349 2589 -4603 15824 974 -6171 -12545 2892 -2050 7632 1565 -2400 -5623 -5308 -864 -2764 18991 272 5688 -3443 15263 3652 -333 -8193 -7877 -5450 8486 2320 2133 -17656 -643 -3492 4540 4789 6708 -6737 -5146 7451 12287 -6717 5997 1197 -2895 6169 5248 3904 -6129 1929 -7331 8935 -6610 -7222 -4174 3537 5052 1805 2520 3294 -5281 -2571 -3579 6822 -6751 2778 -12511 7627 1429 7177 5345 10467 -343 2859 3696 3874 3052 10721 3332 -1655 4425 -3690 7983 -4781 2134 -6800 -2501 -17891 6168 -4524 1929 -11893 -2632 -9246 8289 -10852 4103 2936 -11233 3073 -724 13708 5430 4227 4384 2329 -12330 3151 702 3008 2822 -1583 -4746 8393 -4151 6121 -4703 8632 482 4776 1468 7649 2223 -7265 -961 2106 3493 -17134 3194 -5285 2411 -5802 1113 -4786 4606 -2151 -2653 2741 3692 2833 120 6210 2250 8280 4934 5723 -5421 2107 -3666 955 -1325 6339 -2088 2206 -4317 12755 946 -6469 -13766 2672 -1943 6552 1446 -2346 -5752 -5470 -857 -2794 15610 269 5326 -3459 12545 3300 -308 -8225 -7974 -5383 7304 2115 1933 -19438 -601 -3300 3874 4013 5452 -6270 -4854 6385 10187 -6774 5383 1126 -2846 5597 4828 3634 -6198 1749 -7033 7214 SO 20181225T130458.0Z 6933.545116 257 1 32.01 2 88.65 124.93 67.97 273.95 0.00 1 0.00 1 0 15 4.771e-02 4.556e-02 4.723e-02 4.641e-02 7.265364e+02 2.483984e+03 3.349259e+02 -6.000000e+00 2.380618e+03 273.10 -2.00 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