File name: Pandora103s1_Downsview_20181227_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T021742.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20181227_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20181227 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181227T125757.0Z 6935.540243 260 1 32.01 2 89.79 123.49 52.83 244.94 0.00 1 0.00 1 0 15 1.690e-01 1.465e-01 1.550e-01 1.459e-01 -2.013200e+03 7.836630e+03 5.810336e+02 -6.000000e+00 8.434711e+03 272.98 -2.00 20.00 -2.00 505.28 0.00e+00 2.955561e-03 3.875085e-03 1.697923e-04 -6.000000e+00 4.520654e-03 272.98 -2.00 20.00 -2.00 500.04 0.00e+00 5.004585e+00 2.881212e+00 9.632108e-02 -6.000000e+00 3.240152e+00 222.64 -2.00 3.57 -2.00 501.71 0.00e+00 20.428 0.166 489.00 513.00 1 1.0242e+01 2.2014e-01 3.7575e-02 -6.0000e+00 2.4689e-01 8.0811e-02 5.7555e-02 2.2647e-03 -6.0000e+00 6.5391e-02 2.6346e-06 -5.4750e-03 1.1383e-02 7.6666e-05 -6.0000e+00 1.3160e-02 -1.0199e-01 1.0856e-03 12 8 8 10 0 0 -6.79 15.00 3.74 -0.10199 -0.13997 8 1 1 4 0 4000.000 21.69 15.00 18.45 -1062 7897 37865 17197 -14477 -5344 11018 8311 -13784 -7684 7696 17750 -10977 -14653 31463 -17145 10130 -22410 -12820 1398 9200 1230 3215 -10401 14035 -8540 28188 5424 4511 1726 -14108 12800 5068 5206 11610 20843 1715 38108 -9342 -95 -16660 6423 6527 23223 -13640 2903 -1919 11294 22579 -4247 -4201 42260 -16882 23106 22461 -13589 19980 -3906 -3133 -25698 8502 -2525 15443 -8400 30248 -10745 4660 4874 5397 11516 15637 12990 17789 18500 655 12064 2433 24895 -11723 14132 -8205 -3507 -12620 8237 -37561 9712 -8267 11244 -11016 -6450 8383 -15850 7769 13365 18 810 4233 21107 -6005 7066 -14492 7693 23288 -5921 15535 -4 22529 -11329 -609 6884 50376 10044 3344 37426 -6427 11954 -4585 -4674 4848 15045 686 16482 6374 -12647 -3157 -16610 4636 -23743 -3979 66209 16195 -5305 -24296 62377 5481 4273 1606 6083 6477 -10196 -6439 -9525 5197 1301 -4465 -21385 24912 9237 9636 18331 -1028 7108 26509 15305 -17935 -6178 11132 8733 -17920 -9293 7867 16293 -13071 -17775 24322 -21109 9701 -30078 -16220 1568 9544 1378 3531 -13051 14061 -10663 24645 5869 4819 1810 -16712 11730 5083 5436 11877 19670 1917 29605 -11274 -104 -21317 6632 6816 20933 -17726 3229 -2223 11363 20049 -4758 -4541 28443 -19613 18363 18490 -16408 17923 -4438 -3519 -35526 8434 -2801 14478 -9871 24321 -12549 4593 4718 5139 10158 13040 11114 14663 15362 654 10702 2302 18558 -12272 11492 -8272 -3413 -13423 7185 -51371 8493 -8567 9626 -11635 -6531 7390 -17885 7153 11782 18 790 3940 16294 -5825 5883 -14641 6347 17042 -5961 12969 -3 16980 -11538 -553 5882 29131 8703 3154 25893 -6803 10659 -4811 -4899 4575 12646 652 13311 5665 -13689 -3144 -18803 4290 -28757 -3983 34300 13407 -5280 -28451 31562 4724 3792 1508 5586 5998 -11179 -6822 -10397 4965 1301 -4744 -26552 19380 8055 8164 14304 SO 20181227T130156.0Z 6935.543009 264 1 32.01 2 89.19 124.18 53.48 245.81 0.00 1 0.00 1 0 15 1.106e-01 1.035e-01 1.079e-01 1.046e-01 2.162202e+03 5.820290e+03 4.276314e+01 -6.000000e+00 5.518034e+03 272.98 -2.00 20.00 -2.00 505.15 0.00e+00 2.809835e-03 2.734542e-03 1.634720e-04 -6.000000e+00 2.962514e-03 272.98 -2.00 20.00 -2.00 499.94 0.00e+00 1.979366e+00 2.044838e+00 4.069549e-02 -6.000000e+00 2.134268e+00 222.64 -2.00 3.57 -2.00 501.56 0.00e+00 19.303 0.140 489.00 513.00 1 1.0280e+01 1.5565e-01 3.3639e-02 -6.0000e+00 1.6241e-01 1.3791e-01 4.1032e-02 1.9316e-03 -6.0000e+00 4.3401e-02 3.7498e-06 8.2621e-03 7.8493e-03 3.5789e-05 -6.0000e+00 8.6249e-03 6.3880e-03 -1.0203e-04 12 8 8 10 0 0 -1.68 15.00 6.88 0.00639 0.06370 8 1 1 4 0 4000.000 21.69 15.00 18.45 -7137 1983 -8458 -1628 4707 -2923 -3240 564 16815 -8674 19489 2726 -12857 -19539 9844 -6668 -2019 -15004 10449 -604 8974 17472 11556 6110 5325 6332 1055 -2268 -6280 7997 3475 5977 -2980 7374 -5252 -7764 10356 869 -361 12481 19518 1249 18457 11961 -10099 -4115 -4454 -8808 6347 -2512 393 -589 -2456 -12982 9489 -9079 -3902 1215 -4428 -930 2299 -16431 -1053 16262 3527 9587 13424 14534 16685 -9261 9280 6334 1344 6601 12965 9271 -9395 -1253 -5002 -2511 -4413 16053 -9947 733 -9421 3054 -15981 15341 -259 12411 -2238 -11155 471 -11148 15349 10212 7335 758 -14729 -14807 473 -2917 -3571 6094 -4059 -6421 1868 802 -6029 6327 29129 -10857 15960 -7965 12203 -5238 17562 23086 -1157 -5232 -2445 1667 11974 30492 -857 25368 -20531 -964 -8043 12502 9741 24581 3884 9378 688 15346 -7588 10703 8869 25364 -12798 -15189 -1002 -2191 28736 -20206 -6903 9684 -1078 -14618 -7396 1918 -9405 -1765 4903 -3338 -3788 641 16281 -10546 17709 2877 -15499 -24722 9299 -7405 -2171 -18827 10566 -685 9240 16575 11583 6484 5740 6761 1180 -2599 -7259 7686 3415 5763 -3203 7506 -6248 -9460 10423 944 -391 11841 17344 1335 16921 11831 -12505 -4814 -5187 -10538 6445 -2705 397 -584 -2443 -14442 8793 -10447 -4362 1298 -4973 -1001 2399 -20712 -1147 14940 3624 9109 12040 12722 14151 -9899 8186 5774 1299 6167 11514 8421 -9932 -1199 -4921 -2399 -4312 12997 -10368 692 -9941 2872 -18013 12709 -249 10538 -2201 -12169 469 -12444 13046 8939 6454 691 -15146 -14863 406 -2632 -3364 5478 -4101 -6572 1730 734 -5836 5509 20808 -11605 13366 -8474 10716 -5464 14821 18500 -1156 -5329 -2381 1533 9949 21501 -821 18862 -23774 -919 -8194 10507 8322 17756 3361 7602 604 11950 -7581 9105 7760 19109 -13950 -16958 -982 -2182 21265 -23731 -6941 8016 -968 -14983 SO 20181227T130548.0Z 6935.545695 268 1 32.01 2 88.61 124.86 54.11 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