File name: Pandora103s1_Downsview_20190112_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T023927.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190112_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190112T125655.0Z 6951.539526 514 1 32.01 2 89.78 120.96 125.77 55.36 0.00 1 0.00 1 0 43 9.529e-02 8.967e-02 9.418e-02 9.135e-02 8.957516e+03 6.092473e+03 3.925761e+02 -6.000000e+00 4.734286e+03 271.98 -2.00 20.00 -2.00 505.21 0.00e+00 3.199047e-03 2.384657e-03 3.057764e-04 -6.000000e+00 2.544504e-03 271.98 -2.00 20.00 -2.00 499.83 0.00e+00 1.532432e+00 1.850915e+00 1.097957e-01 -6.000000e+00 1.839353e+00 223.28 -2.00 3.57 -2.00 501.48 0.00e+00 20.433 0.166 489.00 513.00 1 1.0006e+01 1.4073e-01 3.8331e-02 -6.0000e+00 1.3993e-01 1.6122e-01 3.6862e-02 2.7930e-03 -6.0000e+00 3.7365e-02 4.3125e-06 -9.9642e-03 6.6803e-03 9.3824e-05 -6.0000e+00 7.4295e-03 1.9729e-03 2.0142e-07 12 8 8 10 0 0 8.54 15.00 4.50 0.00197 -0.06714 8 1 1 4 0 4000.000 21.48 15.00 18.25 -3029 4554 -15645 -4067 5366 2556 1873 24470 3325 5108 -8646 -2371 2735 -715 22 -11745 -6331 -5169 -4359 -7001 13419 4383 5298 -15808 3157 -1187 6923 -3836 2899 3248 7686 -6710 -4840 -204 8545 -8255 10361 23999 7481 19629 -1776 -4807 -1787 20784 -4627 -2844 4461 5017 4030 -1070 12358 11466 -8896 -11907 9763 -6600 6064 -1084 2019 -6360 1584 -44 3181 15608 3314 -12919 -3748 -13056 3117 -10210 3416 7684 974 -10069 26370 -9635 -1757 8794 4612 3609 10372 -6696 11522 90 5955 4902 -10244 -4913 -7798 12698 -12398 15552 -4024 7112 3437 5759 -19533 5508 17420 7006 1307 32202 -5448 -3221 -2637 -5379 4822 -5301 -3811 13499 1626 20060 -6562 -4373 596 -4067 -5061 1828 2455 3055 20089 9153 -13397 1666 -3367 2385 -11222 8854 13230 10478 6498 4109 -20562 8549 -1147 -436 7787 6702 8920 -9731 -7072 12479 5039 3136 10649 7323 -3610 -2728 -16381 -11406 -3082 4276 -18229 -4406 5514 2757 2073 22206 3730 5603 -10630 -2692 2917 -775 23 -13822 -7080 -5797 -4989 -8473 13410 4762 5697 -20820 3474 -1376 7410 -4535 3184 3446 7453 -7332 -5224 -215 8670 -10194 10666 21276 7672 17647 -1948 -5438 -1984 18775 -5420 -3309 4848 5374 4292 -1176 11606 10482 -9635 -13097 8790 -7224 6084 -1191 2162 -7336 1678 -47 3345 14594 3481 -15693 -4082 -15239 3070 -11311 3254 6943 942 -10952 20504 -10717 -1784 7830 4187 3275 8758 -6681 9718 85 5343 4506 -10952 -4965 -8032 10635 -13202 12717 -4048 6541 3254 5183 -21730 4655 12741 5527 1064 19356 -4797 -2903 -2497 -5383 4363 -5203 -3609 10718 1468 15479 -6632 -4362 568 -4054 -5117 1755 2366 2900 15848 7833 -13926 1488 -3200 2160 -11582 7541 10744 8711 5642 3605 -22271 6884 -1006 -380 6417 5727 7550 -9974 -7151 10490 4563 2906 9195 6516 -3531 -2582 -17137 -11148 SO 20190112T130053.0Z 6951.542280 518 1 32.01 2 89.17 121.65 125.19 56.28 0.00 1 0.00 1 0 15 6.422e-02 6.408e-02 5.804e-02 5.698e-02 2.820398e+03 3.285998e+03 2.064083e+02 -6.000000e+00 3.190790e+03 271.98 -2.00 20.00 -2.00 505.23 0.00e+00 4.593552e-03 1.484258e-03 1.880657e-04 -6.000000e+00 1.714998e-03 271.98 -2.00 20.00 -2.00 499.93 0.00e+00 2.622295e+00 1.135307e+00 3.292472e-02 -6.000000e+00 1.240129e+00 223.28 -2.00 3.57 -2.00 501.58 0.00e+00 19.267 0.139 489.00 513.00 1 9.5940e+00 8.6427e-02 3.3550e-02 -6.0000e+00 9.4338e-02 1.2842e-01 2.2861e-02 1.9030e-03 -6.0000e+00 2.5205e-02 7.0376e-06 -2.7402e-03 4.3017e-03 5.9793e-05 -6.0000e+00 5.0062e-03 2.1045e-03 -4.1199e-05 12 8 8 10 0 0 0.61 15.00 3.42 0.00210 -0.01690 8 1 1 4 0 4000.000 21.58 15.00 18.26 -5756 1578 -8522 -909 -11728 1877 -6672 -403 8525 723 11078 5369 -4041 5923 1389 2560 5855 -11230 4785 -956 4615 -10168 13310 1621 11899 -3179 12342 -7905 6314 -7607 4297 -1924 2483 3 144 -3307 -779 -2905 -589 457 -3891 2246 -3341 11218 -8457 -1314 -2731 3668 -7650 930 12495 1244 -424 2813 3935 9242 1140 1701 4013 7411 1944 -818 1195 -11082 -1602 1595 7499 -8304 -115 -12384 -2111 6327 9098 3471 2885 -4226 4050 4502 11522 2403 6097 4591 -10225 7449 3138 -6281 -5583 14165 -6961 9386 -3106 15929 2697 10340 -12467 10047 -5986 6982 -935 -4238 -2213 4084 2082 3503 -7101 7870 2603 -13774 5794 -3559 -1000 -1957 8144 -3184 8201 2533 -2069 -741 267 -2266 1648 -163 -279 -4424 3054 -8988 6266 -2976 -1460 -1855 8151 5815 -9719 2924 -13386 -1127 -4555 9845 1958 4125 3074 7521 -1149 -8878 2548 4874 6538 1201 -1362 -10440 -5873 1507 -9237 -956 -14162 2023 -7976 -461 8958 810 10985 5538 -4502 5876 1421 2579 5744 -13254 4987 -1078 4924 -12492 12996 1774 11880 -3705 12329 -9575 6565 -8688 4195 -1980 2474 3 159 -3852 -876 -3280 -641 487 -4305 2357 -3750 11080 -10262 -1500 -3158 3938 -9024 989 11503 1235 -419 2673 3776 8768 1207 1818 4193 7434 2044 -888 1280 -13382 -1755 1667 7239 -9171 -116 -13866 -2096 5754 8108 3306 2808 -4414 3817 4107 9671 2187 5336 4106 -10616 6511 2881 -6385 -5636 11733 -7024 8052 -3013 12973 2556 9244 -13819 8768 -5978 5987 -841 -3824 -1916 3328 1769 3066 -7158 6893 2361 -14348 4898 -3299 -924 -1865 7159 -3168 7353 2406 -2070 -737 262 -2241 1539 -152 -257 -4274 2782 -9220 5547 -2881 -1384 -1772 7082 5071 -9618 2522 -13379 -1006 -4321 8311 1805 3764 2852 6680 -1113 -9336 2406 4488 5825 1091 -1228 -10153 SO 20190112T130448.0Z 6951.545000 522 1 32.01 2 88.57 122.33 124.61 57.19 0.00 1 0.00 1 0 8 4.688e-02 4.571e-02 4.157e-02 4.101e-02 1.139006e+03 2.230742e+03 1.914205e+02 -6.000000e+00 2.329325e+03 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