File name: Pandora103s1_Downsview_20190114_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T023939.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190114_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190114 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190114T125558.0Z 6953.538866 511 1 32.01 2 89.79 120.44 127.90 26.90 0.00 1 0.00 1 0 22 1.022e-01 9.558e-02 1.011e-01 9.833e-02 -3.183469e+03 5.078373e+03 2.499590e+02 -6.000000e+00 5.076216e+03 271.86 -2.00 20.00 -2.00 505.13 0.00e+00 7.114796e-03 2.551998e-03 3.397810e-04 -6.000000e+00 2.727054e-03 271.86 -2.00 20.00 -2.00 499.98 0.00e+00 2.782874e-01 1.955732e+00 5.714500e-02 -6.000000e+00 1.970534e+00 223.36 -2.00 3.57 -2.00 501.59 0.00e+00 20.449 0.167 489.00 513.00 1 1.0139e+01 1.4903e-01 3.7925e-02 -6.0000e+00 1.4995e-01 2.0861e-01 3.9797e-02 2.1728e-03 -6.0000e+00 3.9967e-02 4.0023e-06 2.4577e-03 7.5308e-03 1.0172e-04 -6.0000e+00 7.9697e-03 2.5824e-02 -2.9778e-05 12 8 8 10 0 0 -1.69 15.00 6.54 0.02582 0.04287 8 1 1 4 0 4000.000 21.69 15.00 18.46 3782 17084 176 288 -1736 -13311 -7319 7171 -4321 1786 -1317 7569 22989 16490 -17569 -8689 9670 4124 -1121 3073 11933 -3846 8657 -17716 13946 144 262 17273 1455 -5710 -4027 -566 31037 -4278 3726 5969 2320 3432 -16649 -3677 -9236 21534 -6158 19985 -12585 18737 -2679 858 -6659 1563 4939 -4431 3149 352 -8424 37815 4687 2914 -2135 -6485 -2803 8889 -6027 1968 11590 -7481 2521 -5620 4204 -16365 24221 -2078 12139 -1646 2389 517 -3851 1331 -8999 9705 7456 -4139 -9580 -8483 -14779 10518 -6255 6344 4801 -5572 -914 6614 230 6538 -8985 9792 3787 10863 -9319 7542 7646 -17044 3130 -9753 -1683 2890 -3901 -4239 1057 -12087 24156 18685 14934 9662 7245 -4915 10362 5569 11124 14144 11599 -12801 5181 -15393 -7682 -10007 -1843 2510 -12986 7704 6259 9739 3899 26254 1602 11092 -8308 4713 5821 -3533 -6207 2041 -4322 2943 3063 -3274 2087 -3165 -7 -5913 3603 14568 184 312 -1964 -17129 -9057 7767 -5200 1983 -1471 7646 19635 14725 -21578 -9783 9199 4238 -1247 3307 11699 -4387 8730 -23172 13560 161 291 16118 1537 -6157 -4163 -567 23394 -4739 3959 6218 2463 3550 -20643 -3988 -10623 18615 -7070 18107 -15840 17495 -3060 933 -7667 1621 4789 -4577 2980 345 -9307 27778 4853 3088 -2369 -7453 -3109 8883 -6986 2106 11183 -8518 2553 -6068 4084 -19030 18744 -2078 10683 -1680 2371 517 -3908 1258 -9334 8364 6588 -4127 -10061 -8821 -16474 9211 -6418 5727 4384 -5636 -888 6097 232 6285 -10002 9026 3657 9542 -9625 6421 6406 -18234 2824 -10303 -1657 2667 -3750 -3998 939 -12389 17897 14962 12701 8794 6802 -5207 9478 5296 9841 11903 9859 -13594 4626 -17003 -7911 -10519 -1790 2324 -13945 6807 5555 8152 3371 17940 1372 8792 -8151 4143 5102 -3402 -6109 1847 -4173 2664 2774 -3115 1829 -2803 -6 -5226 SO 20190114T125948.0Z 6953.541528 515 1 32.01 2 89.20 121.10 127.59 27.99 0.00 1 0.00 1 0 15 6.150e-02 5.896e-02 6.609e-02 6.470e-02 2.799526e+03 3.744142e+03 7.416846e+01 -6.000000e+00 3.053335e+03 271.86 -2.00 20.00 -2.00 505.18 0.00e+00 5.081016e-03 1.692014e-03 2.988015e-04 -6.000000e+00 1.641362e-03 271.86 -2.00 20.00 -2.00 499.86 0.00e+00 2.036923e+00 1.301945e+00 8.179717e-02 -6.000000e+00 1.186492e+00 223.36 -2.00 3.57 -2.00 501.52 0.00e+00 19.330 0.141 489.00 513.00 1 9.7539e+00 9.9242e-02 3.4579e-02 -6.0000e+00 9.0275e-02 1.5111e-01 2.6305e-02 2.1519e-03 -6.0000e+00 2.4084e-02 6.1731e-06 -2.7626e-03 4.8921e-03 6.5702e-05 -6.0000e+00 4.7947e-03 -1.1889e-02 1.4166e-04 12 8 8 10 0 0 -3.84 15.00 4.85 -0.01189 -0.03105 8 1 1 4 0 4000.000 21.69 15.00 18.47 -2650 13112 2416 -1979 6247 628 9537 -5111 611 -2293 6353 -2941 1472 -4961 -1360 -7212 5216 -9341 -5220 -4081 -3148 1456 -9826 1455 -1179 11872 2064 10403 -3175 8041 2658 8509 10927 -78 945 -5387 -253 -7458 1020 -1159 4623 2175 -4595 -7364 10656 -111 4101 -1007 5881 -3757 10176 -4159 6393 -562 -8813 -820 3853 3781 -1015 -6659 -2865 6351 -10294 -3278 2994 14371 2570 2731 -3493 -3555 649 13061 7245 -1746 -4286 -410 -4389 -2155 -5763 7150 19391 -9020 2091 -1300 -9098 2004 7125 -4714 3631 525 -4474 -856 1297 1718 -7055 725 -3510 -3455 43 -4226 8027 9051 1152 2340 4086 5609 -1283 1349 16626 -5373 6540 8756 -9500 1039 3221 3141 -3591 -577 992 -1483 -8781 -1060 -2981 1878 -5129 4272 -2395 -4387 7338 -3160 -221 10227 -2516 2842 8203 -6151 4477 -12608 8574 10313 33 -3284 1079 5905 -84 5530 -11127 2208 -6345 12071 -2655 11353 2393 -2136 6421 693 9867 -6182 700 -2666 6636 -3310 1563 -5500 -1437 -8037 5184 -10904 -6040 -4764 -3631 1602 -12042 1599 -1341 11976 2283 10559 -3615 7859 2631 7921 10053 -83 1038 -6401 -282 -8781 1092 -1252 4708 2286 -5228 -8731 10759 -126 4437 -1131 6075 -4175 9557 -4344 5899 -553 -9625 -862 3990 3968 -1115 -7665 -3164 6450 -12369 -3676 3138 13265 2602 2712 -3644 -3652 628 11159 6595 -1756 -4488 -413 -4484 -2096 -5727 6224 14956 -9232 1929 -1238 -9433 1882 6358 -4687 3303 490 -4398 -823 1249 1672 -7410 692 -3417 -3271 38 -3802 6287 7037 991 2079 3693 4999 -1201 1205 12591 -5060 5609 7509 -9897 990 3023 2959 -3636 -571 961 -1445 -9005 -990 -2802 1699 -5030 3826 -2290 -4269 6337 -3035 -206 8437 -2293 2424 6572 -5711 3854 -13084 7318 8744 31 -3189 1007 5288 -80 4961 -11504 1939 -5865 9246 SO 20190114T130334.0Z 6953.544144 519 1 32.01 2 88.62 121.76 127.26 29.05 0.00 1 0.00 1 0 29 5.168e-02 5.084e-02 4.858e-02 4.769e-02 2.338063e+03 2.764017e+03 2.883112e+02 -6.000000e+00 2.566599e+03 271.86 -2.00 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