File name: Pandora103s1_Downsview_20190127_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T023918.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190127_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190127T124635.0Z 6966.532350 239 1 32.01 2 89.77 116.24 57.32 211.52 0.00 1 0.00 1 0 36 5.377e-02 5.287e-02 4.848e-02 4.755e-02 1.433793e+03 2.610245e+03 5.662047e+01 -6.000000e+00 2.669745e+03 271.77 -2.00 20.00 -2.00 505.20 0.00e+00 1.978836e-03 1.224174e-03 1.092682e-04 -6.000000e+00 1.436028e-03 271.77 -2.00 20.00 -2.00 499.82 0.00e+00 4.013932e+00 9.418003e-01 2.666719e-02 -6.000000e+00 1.042400e+00 223.88 -2.00 3.57 -2.00 501.48 0.00e+00 20.425 0.166 489.00 513.00 1 9.1839e+00 7.1508e-02 3.6826e-02 -6.0000e+00 7.9215e-02 1.1965e-01 1.9070e-02 2.0755e-03 -6.0000e+00 2.1301e-02 8.4962e-06 1.2661e-02 3.5756e-03 2.9526e-05 -6.0000e+00 4.1987e-03 -1.4278e-02 3.7165e-06 12 8 8 10 0 0 1.66 15.00 2.83 -0.01428 0.07354 8 1 1 4 0 4000.000 21.58 15.00 18.28 900000 -3647 7805 -4252 5858 5648 6488 -1234 5347 3433 2978 1796 -2200 -4298 -6293 -3593 -4183 124 -3011 -1586 -2634 -1748 -6820 4797 656 8219 -1335 -1530 109 6066 -2522 8564 851 7099 4645 -1844 -1955 -7100 8311 2651 1984 -2806 617 -7606 7260 -58 12713 452 5658 -7873 1558 -2627 915 -7098 -8867 -4212 -344 -3399 726 -4093 -7421 5253 -2305 2009 -4486 4903 -545 13947 3682 2085 -8712 1313 -5418 10968 7364 7681 -2579 -4856 580 -3067 -1185 -2283 -3028 -9996 10050 -8605 -156 3445 5328 3839 3594 5258 4281 2916 3408 2287 -1862 -10663 2734 -7367 3566 -793 1082 6230 -7396 -1167 -11490 1068 -5398 -2333 665 5876 -3078 5388 -4577 6489 -3057 6573 -951 8481 4966 -723 -1715 9135 -1895 6055 11481 203 5388 -8189 -3133 -4401 3552 225 3990 -11540 6525 -3623 7929 -1315 -2026 -6152 559 3990 4865 8233 -2505 -3139 1583 -100 900000 -3766 7509 -4778 6085 5997 6971 -1439 5813 3728 3195 1926 -2409 -4735 -7029 -3930 -4679 137 -3535 -1845 -3083 -2030 -8309 5250 753 8741 -1551 -1762 119 5989 -2670 8201 903 7434 5117 -2151 -2245 -8442 8383 2802 2117 -3164 681 -9209 7674 -66 12587 495 5788 -8905 1550 -2649 882 -7509 -9897 -4647 -371 -3786 771 -4520 -8471 5338 -2522 2097 -4916 4799 -551 12089 3479 1961 -9008 1239 -5516 9686 6772 6907 -2489 -4700 528 -2881 -1099 -2157 -2883 -10252 8582 -8834 -147 3115 4717 3452 3260 4784 4002 2751 3141 2090 -1730 -10475 2291 -6658 2893 -685 956 5468 -7487 -1096 -11678 940 -5033 -2146 607 5185 -3005 4878 -4578 5860 -3052 5964 -914 7293 4343 -658 -1582 7697 -1783 5269 9479 186 4701 -8196 -2943 -4085 3004 194 3330 -11500 5608 -3488 6905 -1263 -1962 -6222 534 3705 4481 7249 -2377 -2898 1372 -89 SO 20190127T125038.0Z 6966.535162 243 1 32.01 2 89.12 116.94 57.71 212.58 0.00 1 0.00 1 0 15 3.593e-02 3.481e-02 3.340e-02 3.290e-02 3.330362e+03 1.924543e+03 2.208952e+01 -6.000000e+00 1.783800e+03 271.77 -2.00 20.00 -2.00 505.20 0.00e+00 9.116646e-04 8.596776e-04 5.355172e-05 -6.000000e+00 9.588745e-04 271.77 -2.00 20.00 -2.00 499.84 0.00e+00 2.354668e+00 6.544910e-01 7.402627e-02 -6.000000e+00 6.943450e-01 223.88 -2.00 3.57 -2.00 501.51 0.00e+00 19.153 0.137 489.00 513.00 1 9.1171e+00 4.9886e-02 3.3302e-02 -6.0000e+00 5.2813e-02 1.3532e-01 1.3165e-02 2.1626e-03 -6.0000e+00 1.4111e-02 1.2420e-05 3.3511e-03 2.4701e-03 1.3758e-05 -6.0000e+00 2.8013e-03 2.2655e-02 -1.5305e-04 12 8 8 10 0 0 4.15 15.00 2.82 0.02266 0.04590 8 1 1 4 0 4000.000 21.58 15.00 18.28 -5378 740 -3715 5612 -3035 3179 -4777 4761 -2469 9232 -4128 1706 -4787 1594 -1413 1220 -5501 1873 186 -2193 685 -1371 1590 500 -492 1058 427 1906 -1159 -3608 3109 -721 2334 -3488 75 839 3548 -554 1233 2890 -493 2105 9 192 -2908 6195 86 1768 -2885 2207 -3941 652 -3816 5326 1156 230 5 -503 -1954 9042 -1701 307 3311 84 1074 3806 -1722 3751 1706 -3873 -733 -2153 4073 1049 -222 -201 2293 -4733 986 -7148 259 -5086 2084 -1771 -1026 -1807 4992 964 -1925 3237 -6910 3597 -4549 5255 -4048 3318 -3225 1076 -165 -2451 -712 356 2430 2571 -4972 2777 4315 -2688 -641 -271 5514 -5556 8446 884 3240 -335 14671 -92 3300 -5495 2487 1148 9652 -3554 -23 -1270 138 -1548 394 -4825 -3788 3377 4171 543 -6055 -1742 -4461 1250 -2994 1811 -1089 -4144 2020 666 -7051 4716 -1601 -423 3185 3764 -5480 720 -3910 5628 -3394 3407 -5656 5201 -2892 9511 -4748 1833 -5390 1657 -1499 1262 -6143 1999 209 -2554 774 -1579 1776 565 -566 1200 484 2119 -1297 -3945 3095 -746 2386 -3936 85 951 3858 -617 1329 3028 -533 2230 10 212 -3346 6538 95 1907 -3197 2270 -4150 636 -3815 4887 1138 237 6 -540 -2119 8728 -1816 324 3404 88 1116 3779 -1765 3589 1648 -3880 -701 -2091 3761 1014 -220 -198 2143 -4618 901 -7022 237 -4953 1901 -1684 -981 -1757 4541 908 -1855 2965 -7010 3340 -4667 4919 -4075 3037 -3069 954 -144 -2133 -602 303 2097 2331 -5004 2585 3889 -2534 -583 -247 4852 -5535 7434 844 3028 -325 12407 -91 3109 -5531 2270 1041 7988 -3384 -21 -1191 128 -1449 360 -4667 -3608 2928 3517 469 -5542 -1556 -4217 1139 -2876 1678 -1043 -4095 1891 636 -7267 4307 -1521 -384 2720 3186 SO 20190127T125445.0Z 6966.538021 247 1 32.01 2 88.46 117.66 58.12 213.66 0.00 1 0.00 1 0 22 2.430e-02 2.359e-02 2.510e-02 2.478e-02 1.791917e+03 1.378229e+03 8.552697e+01 -6.000000e+00 1.206284e+03 271.77 -2.00 20.00 -2.00 505.21 0.00e+00 1.181157e-03 6.436262e-04 6.187684e-05 -6.000000e+00 6.485770e-04 271.77 -2.00 20.00 -2.00 499.86 0.00e+00 2.583480e+00 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