File name: Pandora103s1_Downsview_20190130_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T023934.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190130_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190130 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190130T124330.0Z 6969.530208 386 1 32.01 2 89.78 115.07 63.71 169.58 0.00 1 0.00 1 0 22 5.224e-02 5.095e-02 4.891e-02 4.846e-02 -2.262777e+02 2.515485e+03 7.853976e+01 -6.000000e+00 2.592653e+03 271.77 -2.00 20.00 -2.00 505.31 0.00e+00 5.960271e-03 1.267343e-03 2.993616e-04 -6.000000e+00 1.395795e-03 271.77 -2.00 20.00 -2.00 500.37 0.00e+00 2.706161e+00 9.449326e-01 4.639847e-02 -6.000000e+00 1.015193e+00 224.00 -2.00 3.57 -2.00 501.97 0.00e+00 20.438 0.166 489.00 513.00 1 9.2401e+00 7.1731e-02 3.7629e-02 -6.0000e+00 7.7105e-02 8.9084e-02 1.9069e-02 2.0576e-03 -6.0000e+00 2.0804e-02 8.3740e-06 7.6037e-03 3.6932e-03 7.6593e-05 -6.0000e+00 4.0813e-03 3.0292e-02 -4.5571e-04 12 8 8 10 0 0 63.15 15.00 5.28 0.03029 0.08303 8 1 1 4 0 4000.000 21.69 15.00 18.45 900000 -2879 -8223 2994 -3701 853 -4298 8412 -1834 9767 -9875 -4951 621 -4149 -8157 8430 -1218 -1012 3150 -1166 -1988 8488 2043 -4527 4529 -1516 -2737 -3933 3582 -2917 12499 661 1420 2241 8113 -2228 4027 -4243 1844 -7293 6575 416 4306 7904 1581 3331 -1541 -2103 -2198 -876 -5657 3601 -3142 602 -10661 3867 809 8879 1683 -2475 1337 8031 -5732 2060 2573 -3957 2878 -4357 -3219 1578 4867 -6732 8046 -2451 6267 9259 674 4375 4702 5086 3716 -7671 18359 -1284 -63 -3803 -3340 -1508 3742 -3052 1462 -6042 1498 -3297 4962 1259 -1136 8076 -1372 2113 1339 3073 -7442 6584 -4027 7805 -4793 -661 430 8331 3622 -9540 3694 1890 402 -2387 5048 -125 5092 -1909 3879 -4756 -806 -6740 8534 -3331 -5636 -6177 4653 1903 -557 -6994 -1790 -2208 4390 -8065 2690 4812 -253 6671 -5268 5482 -6927 1559 -291 -981 558 8377 -10816 7605 900000 -2714 -8467 2890 -3920 880 -4767 8341 -2007 9393 -11245 -5303 620 -4265 -8633 7590 -1216 -1032 3185 -1249 -2136 8231 2109 -5000 4633 -1654 -3015 -4364 3614 -2993 10701 636 1379 2251 8032 -2461 4127 -4645 1879 -8045 6356 432 4369 7869 1700 3544 -1714 -2322 -2392 -920 -6021 3400 -3114 577 -11759 3856 855 8753 1777 -2701 1404 7964 -6538 2176 2682 -4319 2880 -4603 -3329 1531 4496 -6964 7270 -2489 5934 8465 653 3990 4232 4538 3362 -7827 14577 -1234 -60 -3809 -3323 -1464 3436 -2994 1379 -6228 1474 -3448 4760 1235 -1125 7128 -1288 1862 1168 2652 -7299 5870 -4074 6972 -4741 -615 391 7093 3310 -10151 3534 1871 407 -2498 4945 -129 4939 -1944 3677 -4833 -784 -7048 7777 -3409 -5912 -6502 4397 1860 -557 -7277 -1733 -2113 3901 -8191 2533 4532 -253 6299 -5603 5244 -7514 1569 -299 -1011 554 7435 -11234 6574 SO 20190130T124727.0Z 6969.532951 390 1 32.01 2 89.14 115.75 63.59 170.59 0.00 1 0.00 1 0 15 1.190e-02 1.194e-02 1.005e-02 9.992e-03 1.211710e+03 5.113983e+02 9.440517e+01 -6.000000e+00 5.909971e+02 271.77 -2.00 20.00 -2.00 505.42 0.00e+00 8.077557e-03 2.627139e-04 4.199797e-04 -6.000000e+00 3.176899e-04 271.77 -2.00 20.00 -2.00 501.04 0.00e+00 2.017978e+00 1.881335e-01 6.566491e-02 -6.000000e+00 2.301214e-01 224.00 -2.00 3.57 -2.00 502.54 0.00e+00 19.195 0.138 489.00 513.00 1 7.7977e+00 1.4282e-02 3.4883e-02 -6.0000e+00 1.7502e-02 9.0774e-03 3.7480e-03 1.9397e-03 -6.0000e+00 4.6782e-03 4.3082e-05 7.1635e-04 7.6624e-04 1.0439e-04 -6.0000e+00 9.2815e-04 4.4184e-02 -3.0237e-04 12 8 8 10 0 0 91.75 15.00 0.87 0.04418 0.04915 8 1 1 4 0 4000.000 21.69 15.00 18.46 -165 -2158 -2193 -1044 -245 10 -305 764 -1751 1535 -257 -279 -881 -1501 -2280 -406 -670 -147 1058 21 1375 962 1101 1802 1440 103 1237 517 632 -1260 -1219 -1830 967 -1773 -453 116 289 1079 -218 -645 852 -207 1432 319 508 1329 2220 1782 309 -382 -356 -1510 -1599 -2327 -2350 124 913 594 469 446 419 1020 480 609 791 525 468 -488 -131 195 -1075 -465 187 -1361 2557 -1119 344 341 234 -1859 664 261 407 -526 98 -434 399 -448 -1776 928 -784 828 -480 3197 -57 1023 404 -870 -660 -1811 -2076 -112 -259 1117 407 427 499 -720 -1432 -1336 -88 -615 397 -365 1792 800 2813 1892 2190 -2112 -30 -349 -403 550 773 -763 -301 -1038 42 460 1045 212 -539 -962 -1201 -98 -2235 -1457 -1374 2546 -1007 1598 -509 1893 1218 1552 99 -633 -2699 -2028 -135 -1824 -1921 -947 -227 9 -295 742 -1740 1458 -243 -260 -815 -1373 -2081 -364 -607 -135 994 21 1306 917 1049 1715 1393 102 1210 508 609 -1184 -1109 -1675 876 -1715 -453 117 288 1050 -213 -627 821 -204 1417 325 525 1378 2283 1823 317 -387 -349 -1458 -1521 -2237 -2325 125 941 622 492 466 438 1070 510 647 835 547 479 -497 -132 193 -1057 -455 183 -1374 2528 -1143 339 329 223 -1803 629 250 392 -510 95 -428 390 -439 -1751 891 -770 813 -491 3218 -59 1034 405 -861 -634 -1711 -1932 -103 -243 1079 407 425 488 -697 -1383 -1304 -87 -629 412 -388 1886 855 2977 2031 2328 -2298 -31 -363 -417 572 813 -817 -322 -1119 44 491 1111 223 -559 -987 -1225 -100 -2393 -1581 -1506 2720 -1117 1728 -564 2066 1344 1701 108 -672 -2839 -2109 SO 20190130T125120.0Z 6969.535648 394 1 32.01 2 88.51 116.43 63.50 171.59 0.00 1 0.00 1 0 22 1.029e-02 1.012e-02 7.544e-03 7.512e-03 1.010914e+03 3.838421e+02 8.315246e+01 -6.000000e+00 5.109871e+02 271.77 -2.00 20.00 -2.00 505.39 0.00e+00 7.516377e-03 1.970401e-04 3.894356e-04 -6.000000e+00 2.747510e-04 271.77 -2.00 20.00 -2.00 500.88 0.00e+00 2.079486e+00 1.422840e-01 5.957157e-02 -6.000000e+00 1.990389e-01 224.00 -2.00 3.57 -2.00 502.40 0.00e+00 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