File name: Pandora103s1_Downsview_20190202_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T023951.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190202_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190202T124017.0Z 6972.527975 464 1 32.01 2 89.76 113.85 78.69 136.47 0.00 1 0.00 1 0 29 1.929e-01 1.580e-01 1.726e-01 1.594e-01 2.844614e+03 9.631476e+03 9.190819e+02 -6.000000e+00 9.580227e+03 271.77 -2.00 20.00 -2.00 505.34 0.00e+00 2.455908e-03 4.165996e-03 3.457489e-05 -6.000000e+00 5.146097e-03 271.77 -2.00 20.00 -2.00 499.84 0.00e+00 4.428294e+00 3.181731e+00 5.242964e-02 -6.000000e+00 3.719558e+00 224.12 -2.00 3.57 -2.00 501.55 0.00e+00 20.416 0.166 489.00 513.00 1 1.0370e+01 2.4324e-01 3.6796e-02 -6.0000e+00 2.8309e-01 9.2553e-02 6.2744e-02 2.0207e-03 -6.0000e+00 7.5342e-02 2.4056e-06 2.5426e-02 1.2038e-02 7.4397e-05 -6.0000e+00 1.5042e-02 -6.4008e-02 6.0533e-04 12 8 8 10 0 0 1.36 15.00 7.49 -0.06401 0.11236 8 1 1 4 0 4000.000 21.69 15.00 18.44 1569 -17609 -4679 -3447 10048 6810 5450 507 -16120 20043 10830 35167 -7462 23120 -16419 2620 15768 3788 -15111 -2755 -21814 -2144 -9149 14047 13709 17854 -11919 32857 -16293 2703 21749 -9291 11101 -7214 12943 28365 -5402 -2377 6663 -2897 26876 -21418 34150 -1533 -6008 1620 -19631 8670 411 23692 24670 -1605 15202 -8811 36435 16576 14555 29874 -18265 8375 3603 -5432 319 9538 -8988 6779 -652 2491 -11576 -20284 13870 21741 1852 9965 -3944 6619 -16299 -15146 4144 32191 13243 10878 34610 -27818 -805 -5291 11021 -4482 -3327 31438 -5483 48376 11389 5232 1558 35052 -10034 -5793 37177 44499 4790 -9068 -2151 18206 -8050 17287 -4113 37186 -7480 10929 -19117 20562 -9751 -9227 -755 7402 14393 21392 14784 -7975 -20533 -19174 6958 -7611 52765 -4816 20312 -16654 -4114 -24967 27588 -26063 15016 2895 16084 12192 30490 13943 -12340 17813 -10547 -13963 -13726 -12556 -4616 25919 9404 32583 6753 90602 1546 -21718 -5288 -3930 10268 7316 5975 579 -21188 18327 10685 27039 -8508 19577 -20419 2762 15125 4188 -20104 -3247 -30876 -2514 -11544 14296 13958 17402 -15291 26484 -20151 2753 18618 -11017 11361 -9026 13239 24640 -6398 -2694 6878 -3292 23198 -29702 28192 -1795 -7337 1817 -26587 8775 436 19446 19560 -1619 13286 -10072 27878 15579 13943 24528 -23645 8410 3812 -6273 347 9345 -10293 6545 -668 2440 -12719 -24026 11912 17534 1837 9179 -4062 5988 -18046 -16452 3730 22297 11059 9296 23777 -35101 -785 -5362 9493 -4462 -3278 22412 -5672 30411 10111 4825 1456 23204 -9918 -5350 22345 24975 4010 -9054 -2096 14751 -8268 13656 -3907 23792 -7458 9328 -22112 16473 -10503 -9912 -753 6891 12522 17138 12385 -8157 -23359 -21662 6209 -7830 30575 -4830 15939 -18677 -4108 -29960 19577 -30478 11746 2558 12895 10406 22155 12009 -13788 14941 -11655 -16072 -15837 -14320 -4809 19588 8067 22142 5928 36786 SO 20190202T124427.0Z 6972.530868 468 1 32.01 2 89.08 114.58 78.19 137.29 0.00 1 0.00 1 0 25 8.836e-02 8.280e-02 9.035e-02 8.767e-02 6.233669e+03 5.451550e+03 2.962205e+02 -6.000000e+00 4.386518e+03 271.77 -2.00 20.00 -2.00 505.17 0.00e+00 1.128434e-03 2.281287e-03 7.342339e-05 -6.000000e+00 2.364402e-03 271.77 -2.00 20.00 -2.00 499.70 0.00e+00 1.409928e+00 1.769498e+00 7.384335e-02 -6.000000e+00 1.723501e+00 224.12 -2.00 3.57 -2.00 501.37 0.00e+00 19.060 0.135 489.00 513.00 1 1.0196e+01 1.3439e-01 3.3107e-02 -6.0000e+00 1.3078e-01 1.6639e-01 3.5974e-02 2.2715e-03 -6.0000e+00 3.5482e-02 4.5151e-06 6.3830e-03 6.5010e-03 4.6932e-05 -6.0000e+00 6.9071e-03 9.1075e-02 -1.1462e-03 12 8 8 10 0 0 12.09 15.00 3.12 0.09107 0.13535 8 1 1 4 0 4000.000 21.69 15.00 18.46 900000 -10789 6707 -4459 -4640 8237 5073 -5509 8656 -5043 -6489 -652 14409 16105 -3493 -2960 -6109 15762 -1925 -4609 8505 -1943 -3550 -1662 2575 -6209 6470 20 6206 3982 -9100 -4391 2864 1468 72 -8707 4451 2343 22590 -6540 327 -14430 21462 4370 3905 2459 1244 -3595 2921 16755 -4086 -10699 7598 3516 2875 -7955 -6926 12387 2562 6889 -9912 4700 -4165 2883 -10594 6386 -5079 5389 -4906 -1224 -1890 -4888 20731 4941 21839 -7385 9655 -15343 -37 22128 11590 -2655 10770 -2362 -401 -16154 10981 -11094 -7035 8252 -9952 11340 -987 16805 -1896 6241 -12754 1052 -474 12584 -4411 4565 -8774 17946 -11261 -1689 4224 1389 -662 17145 1160 -10432 -11759 13511 -2790 10876 15368 -794 13357 -4348 7031 -5073 14178 -2214 4115 -4740 10463 -1926 11216 -700 -8746 -7141 -3131 -6132 10017 -4916 -4765 -7059 -4593 10639 -6519 6475 -3270 1154 1563 8099 -1526 141 -9265 13811 900000 -11940 6435 -4967 -5350 8532 5531 -6771 9314 -6143 -7853 -734 13839 14929 -3861 -3241 -6931 14748 -2208 -5564 9049 -2282 -4228 -1941 2901 -7660 7026 23 6636 4183 -10397 -4747 2912 1560 81 -10943 4879 2576 20127 -7610 354 -18042 19139 4646 4222 2714 1388 -4151 3114 15316 -4426 -11922 6916 3298 2761 -8820 -7852 11829 2692 6886 -11567 4774 -4641 3001 -12509 6306 -5487 5160 -5129 -1219 -1857 -4913 16374 4601 17582 -7925 8616 -16930 -34 16567 9565 -2530 9089 -2268 -382 -18138 9514 -11853 -7176 7225 -10392 9713 -971 14101 -1885 5581 -13320 933 -414 9458 -3826 3635 -8152 13520 -11827 -1647 3854 1278 -607 13171 1055 -10809 -12492 11324 -2743 9363 12739 -779 11469 -4367 6193 -4909 11163 -2041 3616 -4549 8658 -1795 9138 -639 -8665 -6851 -2815 -5595 7751 -4406 -4378 -6799 -4371 8843 -6458 5670 -3155 1073 1451 7043 -1438 127 -8862 10394 SO 20190202T124827.0Z 6972.533646 472 1 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