File name: Pandora103s1_Downsview_20190312_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T030218.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190312_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190312T114155.1Z 7010.487443 428 1 32.14 2 89.74 94.86 115.82 31.39 0.00 1 0.00 1 0 22 1.420e-01 1.316e-01 1.292e-01 1.237e-01 7.573714e+03 7.665095e+03 5.731597e+02 -6.000000e+00 7.106472e+03 273.66 -2.00 20.00 -2.00 505.26 0.00e+00 7.453221e-03 3.220761e-03 2.213356e-04 -6.000000e+00 3.802736e-03 273.66 -2.00 20.00 -2.00 500.02 0.00e+00 2.825267e-01 2.413671e+00 4.981475e-02 -6.000000e+00 2.735467e+00 225.63 -2.00 3.57 -2.00 501.66 0.00e+00 20.343 0.164 489.00 513.00 1 1.0327e+01 1.8377e-01 3.7171e-02 -6.0000e+00 2.0833e-01 1.7717e-01 4.7870e-02 2.3068e-03 -6.0000e+00 5.5349e-02 3.2106e-06 2.9874e-02 9.2108e-03 9.3223e-05 -6.0000e+00 1.1067e-02 -2.0563e-02 4.4189e-04 12 8 8 10 0 0 97.11 15.00 10.65 -0.02056 0.18665 8 1 1 4 0 4000.000 21.69 15.00 18.48 25410 -5286 41979 -14825 24301 -20008 -7741 -6563 590 -6636 19683 12616 2850 -5370 15192 -13929 -6139 3189 -271 23128 -6618 2194 -18875 19624 162 -7294 -9560 6687 -20684 2847 13576 18876 9432 -3675 2560 25738 15892 6157 -1352 -8211 6942 -21536 8444 10310 37910 -883 21687 -15294 -1167 12349 -4991 16335 -4856 -7551 12206 14572 -5428 6275 21020 -13784 -10260 17103 -2463 1335 1537 12029 -16798 13931 -11834 14243 18239 6806 -8971 15104 2969 17583 12447 -7124 -14302 -7939 16072 -4999 -11488 16120 3313 -5518 14744 -7877 44473 3807 32452 6253 19497 -8596 1056 -3582 5961 -2840 -10496 -5172 7248 26267 17555 -7130 -15569 14772 -123 4683 -10050 5328 -26322 15362 2400 3425 -5981 -219 -10108 28235 -9210 8555 9035 8658 12535 -1501 -12720 4064 -9250 5859 2730 -3860 22830 -9645 26871 -29871 11394 1577 8341 -9718 -944 -7587 9555 10415 -7347 -5663 11341 -9571 25631 2782 -10190 17422 20362 -5941 30787 -19126 21909 -27977 -9596 -7911 648 -7682 17378 11708 2870 -5834 13633 -16894 -7110 3424 -299 20320 -7738 2366 -25214 18180 180 -8690 -11390 6502 -25326 2774 12105 16647 9518 -4248 2745 21749 14591 6143 -1453 -9547 7085 -29404 8771 10597 29791 -996 19386 -19112 -1231 11097 -5209 13917 -5237 -8706 11941 14090 -6349 6516 18933 -17510 -12675 16226 -2799 1436 1615 11247 -20535 12444 -13316 12456 15473 6543 -10186 13505 2905 14586 10730 -7364 -15817 -8307 13373 -5102 -12610 13650 3160 -5675 12340 -8157 27967 3595 23861 5965 16085 -9040 984 -3385 5004 -2525 -9869 -4653 5969 18930 14211 -7324 -17096 11869 -113 4145 -10505 4898 -33322 13127 2330 3303 -6390 -223 -11288 21377 -9778 7483 7778 7568 10675 -1464 -13858 3756 -9665 5319 2539 -3722 16679 -9521 18546 -36104 9500 1465 7319 -10253 -918 -7865 8419 9121 -7627 -5732 9520 -9499 17658 2380 -10037 13489 SO 20190312T114606.0Z 7010.490347 432 1 32.01 2 88.99 95.58 115.43 32.37 0.00 1 0.00 1 0 8 6.901e-02 6.612e-02 6.325e-02 6.199e-02 -6.519537e+02 3.294007e+03 3.178298e+02 -6.000000e+00 3.452972e+03 273.66 -2.00 20.00 -2.00 505.24 0.00e+00 1.661258e-03 1.609576e-03 1.134766e-04 -6.000000e+00 1.850312e-03 273.66 -2.00 20.00 -2.00 499.91 0.00e+00 3.426286e+00 1.225727e+00 8.346288e-02 -6.000000e+00 1.335883e+00 225.63 -2.00 3.57 -2.00 501.57 0.00e+00 18.815 0.130 489.00 513.00 1 9.7058e+00 9.2946e-02 3.2565e-02 -6.0000e+00 1.0164e-01 1.1000e-01 2.4983e-02 2.0499e-03 -6.0000e+00 2.7179e-02 6.5846e-06 -2.5715e-04 4.6643e-03 3.4118e-05 -6.0000e+00 5.3817e-03 5.6127e-02 -4.1139e-04 12 8 8 10 0 0 -4.96 15.00 4.08 0.05613 0.05434 8 1 1 4 0 4000.000 21.69 15.00 18.49 -6371 48 3731 -208 1701 3278 81 -3648 4890 -3703 -6459 -4241 5373 -4597 3114 3965 -7215 -4625 6571 14996 13183 3025 5461 -5203 767 5738 3314 6872 -7351 537 -10228 -5184 -3215 3089 -12931 3460 -2423 1456 -302 -4296 8834 6080 12111 2544 3474 2143 -3935 1073 455 -2233 2963 -10669 -729 -6788 -9060 4038 105 331 2721 3035 -4995 -2318 -3746 520 8075 107 -10692 5059 -4398 5030 5065 1953 -11482 3765 -2398 22410 -1355 9104 -4944 -1509 1436 21352 11953 7521 6781 -4377 -4355 4800 -3320 6265 10064 -977 9927 2007 14337 -5271 958 -2272 7127 2398 -2320 5763 -11435 2404 -4141 -13013 -3149 -5990 2453 1085 -7762 -2169 13213 9290 -7545 12548 7207 1134 -4391 13474 -11038 -6861 -9617 -1139 -55 5894 -6574 -2628 1003 1212 -9914 -1498 13486 -2117 6755 9071 -3050 -12438 2730 -313 -552 809 3916 -9469 -3194 8719 1956 7961 10022 4352 -6501 46 3594 -217 1798 3473 90 -4292 5310 -4321 -7584 -4810 5471 -5066 3148 3967 -8119 -5189 6841 14691 13122 3321 5847 -6180 867 6202 3650 7278 -8787 569 -11605 -5580 -3438 3225 -16499 3821 -2798 1592 -331 -4829 8710 6187 11745 2740 3754 2357 -4575 1172 491 -2423 2953 -11732 -712 -7004 -9787 3996 112 353 2832 3121 -5519 -2508 -4131 549 7875 111 -12035 4799 -4525 4649 4590 1820 -12282 3520 -2420 17757 -1320 7792 -4787 -1404 1298 16056 9901 6510 5972 -4339 -4320 4340 -3236 5567 8640 -944 8813 1951 12283 -5380 907 -2165 6016 2060 -2050 4732 -11380 2184 -4139 -14137 -3047 -5824 2157 969 -7695 -2079 11110 8233 -7927 10880 6613 1107 -4483 11349 -11594 -6812 -9717 -1070 -51 5229 -6584 -2528 926 1123 -10243 -1399 10647 -1914 5542 7338 -2858 -13092 2513 -300 -532 770 3634 -10090 -3220 7813 1837 6825 8157 3705 SO 20190312T115010.0Z 7010.493171 436 1 32.01 2 88.26 96.29 115.04 33.32 0.00 1 0.00 1 0 15 3.395e-02 3.321e-02 3.385e-02 3.344e-02 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