File name: Pandora103s1_Downsview_20190402_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T032626.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190402_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190402 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190402T110407.0Z 7031.461192 386 1 32.01 2 89.74 83.44 81.95 114.99 0.00 1 0.00 1 0 15 7.586e-02 7.235e-02 7.220e-02 7.026e-02 1.480932e+03 4.015854e+03 1.473026e+02 -6.000000e+00 3.831518e+03 275.89 -2.00 20.00 -2.00 505.17 0.00e+00 4.342026e-03 1.855448e-03 2.306778e-04 -6.000000e+00 2.046697e-03 275.89 -2.00 20.00 -2.00 499.74 0.00e+00 3.042129e+00 1.421188e+00 3.591378e-02 -6.000000e+00 1.475449e+00 227.13 -2.00 3.57 -2.00 501.39 0.00e+00 20.288 0.163 489.00 513.00 1 9.5991e+00 1.0851e-01 3.6907e-02 -6.0000e+00 1.1220e-01 1.5585e-01 2.8996e-02 2.0589e-03 -6.0000e+00 3.0216e-02 5.8461e-06 -3.5408e-04 5.4022e-03 6.3499e-05 -6.0000e+00 5.9260e-03 4.8548e-02 -4.8669e-04 12 8 8 10 0 0 -4.83 15.00 5.74 0.04855 0.04609 8 1 1 4 0 4000.000 21.69 15.00 18.47 900000 -2847 -3484 -6068 5229 -395 -1647 14425 -4289 -2412 12037 -1998 -5471 -1234 12658 2137 6483 11627 1198 10357 1698 -122 -5177 -2880 -7600 7643 -9662 -604 -469 5479 -1671 -147 -1337 322 4529 -2050 2641 -7706 3484 -2648 7779 -11153 160 -12112 3457 -784 10561 -2303 2853 531 12082 -6786 1704 -7295 -7227 13088 -1142 15286 -8019 2790 -524 2721 -5681 6922 -7515 20269 -4985 16811 -6570 786 -6787 3816 4096 6270 -2182 7692 11734 -4952 -3082 -5658 -2693 -11201 11252 -7589 4513 4688 -2542 -9448 65 -8800 9450 -5846 4546 42 -2677 -2810 11975 1921 -2204 4559 -5436 3142 -5103 12489 7489 9462 -4068 1198 -4778 10057 -4954 5944 3806 6704 11338 -14345 -12609 -2140 -7407 6026 12487 2356 -2574 13234 -13494 2645 14723 -8911 -3060 -2756 183 -4328 19373 -5090 4335 -3732 12924 8855 -2274 -7810 11384 4291 -3032 6305 16610 -10599 2513 3506 -6993 -1880 900000 -2919 -3698 -6892 5500 -447 -1925 14650 -5240 -2862 12137 -2271 -6341 -1347 11907 2215 6477 11255 1324 10714 1908 -139 -6190 -3368 -9377 8191 -12209 -696 -532 5626 -1764 -152 -1409 345 4874 -2400 2924 -9269 3709 -2950 7799 -13517 176 -15195 3781 -900 10848 -2648 3069 572 11278 -7346 1660 -7700 -7768 12016 -1241 14373 -9456 2937 -565 2857 -6515 7021 -8716 17672 -5431 14534 -7043 773 -7034 3545 3816 5782 -2219 7121 10217 -4925 -2962 -5532 -2548 -11589 9410 -7614 4052 4243 -2468 -9753 61 -8927 8041 -5821 4185 42 -2676 -2761 10004 1726 -1999 3761 -4828 2565 -4607 9900 6467 8045 -3876 1061 -4398 8011 -4655 5136 3420 5945 9686 -15765 -13701 -2113 -7664 5374 10262 2099 -2373 10533 -14114 2368 11727 -8923 -2877 -2590 168 -4069 14130 -4627 3554 -3319 10044 7336 -2124 -7776 9468 3819 -2903 5549 13289 -11017 2264 3029 -6465 -1629 SO 20190402T110819.0Z 7031.464109 390 1 32.01 2 88.99 84.17 81.27 115.74 0.00 1 0.00 1 0 8 3.190e-02 3.166e-02 3.488e-02 3.442e-02 1.437541e+03 1.925032e+03 1.918253e+02 -6.000000e+00 1.610539e+03 275.89 -2.00 20.00 -2.00 505.20 0.00e+00 2.566879e-03 9.056399e-04 1.136683e-04 -6.000000e+00 8.599381e-04 275.89 -2.00 20.00 -2.00 499.89 0.00e+00 2.438950e+00 6.860789e-01 1.912139e-02 -6.000000e+00 6.178699e-01 227.13 -2.00 3.57 -2.00 501.54 0.00e+00 18.765 0.129 489.00 513.00 1 9.1495e+00 5.2339e-02 3.2002e-02 -6.0000e+00 4.7037e-02 1.3238e-01 1.3897e-02 1.7675e-03 -6.0000e+00 1.2576e-02 1.2216e-05 -1.7466e-04 2.6103e-03 3.6242e-05 -6.0000e+00 2.4871e-03 2.2362e-02 -2.1542e-04 12 8 8 10 0 0 11.37 15.00 1.25 0.02236 0.02115 8 1 1 4 0 4000.000 21.69 15.00 18.49 1442 3106 1081 -4866 -3111 -1015 621 -1540 -2330 3416 -1673 -1965 2568 850 2454 3994 -5680 2473 -2985 1620 -933 2238 -2336 2490 637 5191 4036 -95 -1353 1437 -4931 -1028 -2498 -1120 3779 -4040 1790 -195 -2622 -1069 -1472 5241 -267 3824 -695 600 -713 5999 3170 -1702 716 -10153 -737 5777 19 2209 -1013 4388 -3667 -464 -2702 8 66 3401 944 4963 -1231 6574 -247 -4379 -6688 -3396 1029 3626 2439 -1015 -2338 -1319 -682 501 3308 -4845 -3862 -872 4567 -131 6465 -2873 2732 3516 -1406 -66 5378 1069 -3746 7696 -1306 2810 -2625 984 631 -2401 -1987 1760 -4488 7372 -2983 -1625 2125 -474 -7328 154 1070 416 -631 -2299 -3985 6380 -317 6536 919 261 210 -3253 1817 -2256 1581 -2311 3618 -1879 -523 -210 2552 2266 359 -2480 1502 -3271 -1323 3803 -2570 -1148 -1483 3999 1905 5023 948 -1812 -3872 -3712 1371 2928 1072 -5334 -3457 -1125 692 -1779 -2720 3727 -1878 -2180 2688 888 2493 3986 -6274 2576 -3390 1797 -1059 2459 -2679 2726 716 5607 4388 -106 -1518 1502 -5278 -1055 -2631 -1206 4061 -4762 1969 -215 -2920 -1156 -1594 5343 -291 4047 -779 668 -801 6237 3330 -1836 729 -11109 -719 5275 19 2224 -1084 4509 -4071 -495 -2928 8 71 3509 991 4929 -1271 6177 -245 -4460 -6832 -3349 979 3410 2360 -1015 -2312 -1257 -637 459 2947 -4714 -3742 -822 4122 -125 5791 -2805 2512 3205 -1347 -63 4987 1047 -3814 6878 -1250 2518 -2408 847 535 -2107 -1781 1592 -4469 6548 -2879 -1514 1873 -430 -7234 145 1010 400 -617 -2289 -4059 5908 -311 5892 859 242 192 -3100 1668 -2153 1454 -2203 3236 -1780 -489 -192 2218 1946 310 -2224 1334 -3115 -1251 3457 -2498 -1101 -1432 3687 1799 4589 884 -1681 -3549 -3360 SO 20190402T111226.0Z 7031.466968 394 1 32.01 2 88.25 84.88 80.61 116.48 0.00 1 0.00 1 0 15 2.528e-02 2.507e-02 2.156e-02 2.132e-02 3.872011e+03 1.271127e+03 2.589929e+02 -6.000000e+00 1.276078e+03 275.89 -2.00 20.00 -2.00 505.22 0.00e+00 2.096414e-03 5.614035e-04 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