File name: Pandora103s1_Downsview_20190406_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T032619.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190406_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190406 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190406T105702.0Z 7035.456273 388 1 32.01 2 89.74 81.32 100.16 71.77 0.00 1 0.00 1 0 15 1.051e-01 9.817e-02 1.016e-01 9.894e-02 1.610040e+04 6.931937e+03 1.547683e+03 -6.000000e+00 5.316880e+03 276.35 -2.00 20.00 -2.00 505.40 0.00e+00 -1.319660e-05 2.563365e-03 3.054787e-05 -6.000000e+00 2.835205e-03 276.35 -2.00 20.00 -2.00 500.27 0.00e+00 6.464519e-01 1.923495e+00 1.289581e-02 -6.000000e+00 2.032979e+00 227.44 -2.00 3.57 -2.00 501.90 0.00e+00 20.278 0.162 489.00 513.00 1 1.0152e+01 1.4538e-01 3.6456e-02 -6.0000e+00 1.5484e-01 1.0068e-01 3.8199e-02 2.3968e-03 -6.0000e+00 4.1292e-02 4.1238e-06 8.7916e-03 7.0385e-03 1.0942e-04 -6.0000e+00 8.1989e-03 4.1077e-02 -1.6838e-04 12 8 8 10 0 0 3.01 15.00 9.31 0.04108 0.10206 8 1 1 4 0 4000.000 21.58 15.00 18.32 12400 -8605 2406 -10319 5392 1629 532 2754 6481 13398 10158 -237 -7788 816 -7991 -2529 11232 1915 -11116 3467 -17153 1179 -11190 4211 -7101 -5880 625 1649 2440 -5701 6751 998 1636 5892 10089 9726 7843 1529 7862 -5799 344 -4299 10188 -3166 20264 -9721 1298 2415 24574 -4661 -9351 4020 -1344 -784 -10068 -1608 936 -5179 -2105 11095 -3965 -1587 -1955 8579 948 7321 1200 5611 -18231 720 -8340 -10161 -4827 19371 5818 7218 -5078 7169 5069 7645 25465 -11845 15127 884 11209 -3679 -126 6509 6396 15436 7814 -2053 28694 -1314 16070 279 7099 14435 -426 -13347 -5433 5120 11072 27322 -12163 -6970 -7215 3186 -10983 7153 663 636 -18980 -10408 -1948 6382 -12985 13521 12127 -3704 5156 1972 9381 -10134 10000 -2956 12949 -10353 24922 -20439 9286 -14703 12657 -15611 15621 5546 -11181 -18221 2799 -2117 39104 4676 1449 7327 6357 -2218 17798 -3553 -8934 15251 10029 -8737 2288 -11516 5272 1687 569 2903 6559 12453 9600 -245 -8516 810 -8599 -2600 10290 1986 -13465 3665 -22092 1273 -13606 4436 -8400 -6856 681 1763 2499 -6056 6284 992 1663 6035 10189 9803 7933 1621 7732 -6459 363 -4773 9953 -3565 18357 -11758 1398 2534 20438 -4992 -10117 3727 -1299 -768 -11210 -1708 987 -5810 -2280 10504 -4356 -1718 -2131 8418 989 7041 1202 5329 -21577 697 -8757 -10953 -5010 16232 5596 6726 -5182 6376 4563 6675 18815 -12671 12542 853 9962 -3799 -125 6011 5861 12950 7116 -2095 21971 -1316 13045 252 5782 10681 -357 -12463 -4725 4159 9035 20378 -13752 -7520 -7696 3008 -11819 6558 659 635 -22894 -11510 -1978 6034 -15168 12409 11195 -3896 4836 1856 8177 -10816 8839 -2964 11160 -11106 18988 -24245 8111 -15773 10346 -16741 12502 5042 -12231 -21550 2743 -2211 27664 4643 1491 7117 6213 -2329 15070 -3603 -9421 12814 SO 20190406T110117.0Z 7035.459225 392 1 32.01 2 88.98 82.05 99.45 72.50 0.00 1 0.00 1 0 36 2.133e-02 2.095e-02 1.123e-02 1.115e-02 5.945200e+03 6.369407e+02 4.099945e+02 -6.000000e+00 1.078843e+03 276.35 -2.00 20.00 -2.00 505.38 0.00e+00 3.048035e-03 2.971003e-04 1.302267e-04 -6.000000e+00 5.754206e-04 276.35 -2.00 20.00 -2.00 501.16 0.00e+00 1.544770e+00 2.080997e-01 5.280784e-02 -6.000000e+00 4.127857e-01 227.44 -2.00 3.57 -2.00 502.61 0.00e+00 18.745 0.128 489.00 513.00 1 8.0241e+00 1.5861e-02 3.2337e-02 -6.0000e+00 3.1435e-02 -1.4913e-02 4.0947e-03 2.0915e-03 -6.0000e+00 8.3910e-03 3.9814e-05 4.3139e-03 8.4579e-04 7.2828e-05 -6.0000e+00 1.6631e-03 -4.9651e-03 4.3528e-05 12 8 8 10 0 0 20.52 15.00 8.96 -0.00497 0.02496 8 1 1 4 0 4000.000 21.58 15.00 18.32 -4878 -4204 -3600 -3254 -1398 -324 834 -423 235 2084 -587 -1494 -1935 -1619 -3275 -1930 -3505 -1171 4171 3287 -427 177 480 3645 1980 3995 16 286 916 -1169 -2799 -770 -701 1521 1010 2058 1266 324 2594 -1956 1099 -1965 965 838 2311 2128 4900 1932 618 -367 -979 -5693 -2931 -3630 -350 1069 2806 2365 1412 1920 1449 2106 1503 2288 -73 402 117 1003 -1617 118 -789 -2177 -324 1297 -209 1225 -444 -2819 -969 -1459 -2204 -1763 -836 -2510 -1484 -2220 48 -2735 1112 -1547 2556 -272 1755 4941 4060 1711 1333 -983 -2956 -3178 -3692 -744 -1760 755 1280 -5 -1097 -299 -1756 -596 -3177 1113 1811 1919 2023 2882 3041 5623 2454 834 -949 -280 -131 1225 1708 879 291 1312 -380 14 491 -2211 -1630 -2730 -2810 -3041 -110 -750 681 865 3292 467 1900 618 -632 278 -1330 -2801 -2964 -2727 -3943 -3445 -3053 -2880 -1249 -293 764 -398 220 1888 -537 -1364 -1749 -1437 -2937 -1714 -3209 -1079 3778 3049 -410 170 459 3399 1901 3777 16 279 868 -1081 -2568 -696 -648 1444 1008 2046 1252 320 2476 -1938 1061 -1981 959 849 2343 2177 4856 1949 623 -366 -948 -5620 -2774 -3490 -338 1062 2820 2413 1451 1955 1485 2169 1571 2377 -77 416 119 1001 -1644 116 -774 -2177 -323 1296 -215 1238 -445 -2830 -948 -1430 -2187 -1764 -834 -2565 -1527 -2326 50 -2871 1119 -1601 2559 -286 1853 5079 4133 1740 1327 -974 -2918 -3074 -3564 -710 -1771 785 1369 -5 -1088 -288 -1703 -580 -3251 1114 1827 1953 2067 2939 3143 5729 2567 872 -990 -285 -133 1242 1745 908 303 1354 -398 15 512 -2315 -1669 -2806 -2888 -3206 -116 -814 739 952 3560 522 2112 701 -728 315 -1504 -3117 -3232 -2974 SO 20190406T110523.4Z 7035.462076 396 1 30.73 2 88.25 82.76 98.75 73.22 0.00 1 0.00 1 0 22 1.374e-02 1.340e-02 1.336e-03 1.326e-03 9.631864e+03 8.136905e+01 6.650011e+02 -6.000000e+00 6.953420e+02 276.35 -2.00 20.00 -2.00 505.47 0.00e+00 2.839452e-03 3.527479e-05 1.432549e-04 -6.000000e+00 3.709001e-04 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