File name: Pandora103s1_Downsview_20190421_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T032715.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190421_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190421 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190421T103144.0Z 7050.438704 168 1 32.01 2 89.76 73.74 76.89 231.60 0.00 1 0.00 1 0 15 1.719e-01 1.405e-01 1.410e-01 1.308e-01 1.771387e+04 9.674281e+03 1.594084e+03 -6.000000e+00 8.761365e+03 278.06 -2.00 20.00 -2.00 505.21 0.00e+00 1.516511e-03 3.441582e-03 3.511100e-05 -6.000000e+00 4.657476e-03 278.06 -2.00 20.00 -2.00 499.70 0.00e+00 -1.221706e+00 2.647213e+00 3.188164e-02 -6.000000e+00 3.325997e+00 228.69 -2.00 3.57 -2.00 501.35 0.00e+00 20.252 0.162 489.00 513.00 1 1.0545e+01 2.0119e-01 3.6536e-02 -6.0000e+00 2.5349e-01 2.1692e-01 5.3301e-02 2.6594e-03 -6.0000e+00 6.7507e-02 3.0783e-06 -1.3373e-02 9.3242e-03 1.1419e-04 -6.0000e+00 1.3413e-02 -3.0777e-02 3.2188e-04 12 8 8 10 0 0 -5.02 15.00 10.02 -0.03078 -0.12354 8 1 1 4 0 4000.000 21.58 15.00 18.38 4625 -5973 -3834 4311 1184 24167 -19569 6975 -2778 -7631 -20160 23925 13449 6022 -10214 23827 -5627 8448 -1667 5949 11467 16621 3958 -6242 -6356 -1241 4588 -7046 -3800 -3843 23489 -10582 36090 9307 4173 8805 6355 -13572 2176 -19603 3911 -9888 -5973 2491 -8919 4514 -1726 18437 4815 21250 -10517 26116 790 8534 -1122 11115 -7440 8622 -1931 -1638 -1006 1601 -5071 -10173 10442 11548 -4529 6754 16162 -14360 -2426 -932 -12747 15436 15282 -6152 70191 4832 -2068 -14093 35084 -13342 21553 -8205 12462 -4380 24691 -15010 9956 -10147 25891 -11363 216 -4627 14522 24889 9128 34168 -18314 31015 -16642 27924 -27219 52076 20158 26776 8786 -17456 -7332 5606 2882 18269 -7455 5216 -12969 20561 10302 -18628 9746 -7373 20393 1233 6076 2622 12089 -27296 56696 -9711 47916 -30872 1332 -164 2269 4123 26603 14063 -17648 30097 22162 525 23082 2833 -10516 -7477 949 19664 -10488 -9622 -3121 12548 4517 -6391 -4090 4410 1296 21684 -27254 7669 -3385 -9707 -28430 21634 13281 6271 -12229 20369 -6388 8484 -1897 6489 11958 16430 4409 -7655 -7820 -1465 5110 -8732 -4530 -4449 19936 -12195 26662 9072 4468 9339 6907 -17573 2386 -26132 4113 -11872 -6969 2707 -10960 4922 -2003 17483 5126 18989 -12422 20928 784 7755 -1126 10287 -8540 8669 -2162 -1818 -1101 1708 -5816 -12300 10339 11196 -5030 6592 14216 -16779 -2482 -929 -14305 13351 13473 -6746 36585 4573 -2045 -15469 23827 -14429 16804 -8554 10752 -4522 19431 -17236 8898 -10864 19514 -12316 213 -4848 12479 18582 7566 21345 -18353 19013 -15778 17191 -29139 27527 15463 20130 7921 -20037 -7471 4981 2657 14798 -7789 4817 -14199 16211 8991 -21931 8899 -7913 16397 1156 5264 2314 9839 -32716 30345 -9827 27746 -37818 1201 -148 1938 3409 17672 10556 -18394 20322 16268 480 17238 2589 -10975 -7595 886 15262 -10759 -9580 -2836 9631 SO 20190421T103609.0Z 7050.441771 172 1 32.01 2 88.99 74.50 77.51 232.44 0.00 1 0.00 1 0 15 9.041e-02 8.268e-02 8.487e-02 8.259e-02 6.588632e+03 5.166910e+03 5.262097e+02 -6.000000e+00 4.605187e+03 278.06 -2.00 20.00 -2.00 505.18 0.00e+00 4.506284e-03 2.163682e-03 2.305716e-04 -6.000000e+00 2.451354e-03 278.06 -2.00 20.00 -2.00 499.91 0.00e+00 1.717805e+00 1.646442e+00 4.469812e-02 -6.000000e+00 1.757993e+00 228.69 -2.00 3.57 -2.00 501.52 0.00e+00 18.725 0.128 489.00 513.00 1 1.0052e+01 1.2489e-01 3.2471e-02 -6.0000e+00 1.3379e-01 1.4543e-01 3.3494e-02 1.9927e-03 -6.0000e+00 3.5980e-02 5.0018e-06 -1.5528e-03 6.1591e-03 7.8706e-05 -6.0000e+00 7.0625e-03 3.3135e-02 -3.2513e-04 12 8 8 10 0 0 -6.20 15.00 3.76 0.03314 0.02236 8 1 1 4 0 4000.000 21.69 15.00 18.38 900000 -9396 2957 7922 -1650 -8228 4503 3182 -30 -8740 19241 -7759 -3682 1482 10769 4970 2080 9506 -2825 7299 -12366 20745 -7399 10126 -6719 14729 1947 5241 8049 14528 -4825 2986 -9482 -2701 764 -6983 5986 3741 -5765 -1160 10451 -10733 -1089 -2910 4099 -1970 5013 3444 -1435 -4475 -414 1981 9990 -9234 -4528 -7724 353 168 -6112 2119 -2547 -2236 -509 11112 -7099 -5739 -3062 7085 -10469 2530 9822 34423 -9503 -1179 12634 4887 -12629 7188 897 -1290 -1066 8831 4952 5405 16606 -4208 5384 -11488 -1898 4777 8334 -8345 10445 -8127 10047 -877 2936 1986 -3583 -17029 6612 -11161 3791 -2885 7786 40 -2081 -2635 -12792 -1015 -9477 1283 -8738 2306 7867 2496 27079 5542 1504 19915 -6509 -7293 10224 6217 6634 6936 -12423 4640 3294 4753 12626 -8725 -1335 -3384 31822 -15794 10531 -8209 12079 -805 432 -1385 16755 -10204 10690 -2953 5098 -2880 -11498 4172 900000 -10095 2900 7727 -1825 -9876 4878 3546 -35 -10849 17808 -9178 -4125 1550 10153 4934 2134 9243 -3192 7652 -15670 19012 -8894 10273 -8087 14508 2164 5618 8281 13469 -5174 2945 -10659 -2937 841 -8465 6334 3978 -6630 -1259 10102 -12820 -1200 -3308 4418 -2269 5396 3721 -1599 -5040 -435 1962 8952 -9904 -4734 -8669 378 183 -7080 2249 -2812 -2472 -558 10876 -8247 -6479 -3297 6784 -11749 2469 8756 24056 -10218 -1184 11279 4713 -14118 6446 841 -1226 -1007 7622 4462 4851 13492 -4227 4932 -12307 -1836 4305 7262 -8631 9204 -8695 8917 -842 2645 1752 -3244 -17102 5172 -10373 3125 -2659 6770 38 -1992 -2485 -13059 -925 -9555 1190 -9059 2170 7042 2357 20320 5183 1464 15972 -6599 -7286 8474 5376 5794 6058 -13091 4145 2962 4220 10417 -8674 -1205 -3074 20406 -16130 8564 -8180 9994 -764 408 -1333 13565 -10774 9234 -2902 4562 -2701 -11357 3495 SO 20190421T104027.0Z 7050.444757 176 1 32.01 2 88.24 75.24 78.12 233.26 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