File name: Pandora103s1_Downsview_20190424_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T032750.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190424_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190424 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190424T102701.0Z 7053.435428 165 1 32.01 2 89.76 72.31 67.74 192.98 0.00 1 0.00 1 0 22 2.011e-01 1.739e-01 1.787e-01 1.644e-01 -2.473344e+03 9.558635e+03 3.575982e+02 -6.000000e+00 1.025853e+04 278.40 -2.00 20.00 -2.00 505.25 0.00e+00 1.201661e-02 4.464954e-03 8.114686e-04 -6.000000e+00 5.451018e-03 278.40 -2.00 20.00 -2.00 499.84 0.00e+00 5.005414e+00 3.399063e+00 1.400404e-01 -6.000000e+00 3.890805e+00 228.96 -2.00 3.57 -2.00 501.50 0.00e+00 20.248 0.162 489.00 513.00 1 1.0200e+01 2.6252e-01 4.2448e-02 -6.0000e+00 2.9655e-01 1.1591e-01 6.7148e-02 2.3828e-03 -6.0000e+00 7.9001e-02 2.4144e-06 7.3240e-03 1.2142e-02 2.1460e-04 -6.0000e+00 1.5686e-02 -9.9818e-03 1.7623e-04 12 8 8 10 0 0 9.76 15.00 1.45 -0.00998 0.04082 8 1 1 4 0 4000.000 21.79 15.00 18.56 42720 596 45985 -3459 5241 988 32635 -24038 27773 -16254 15885 9143 6645 7017 -17714 -250 -364 19231 10118 -6508 10566 8571 -3858 -18182 -666 -20287 8415 24258 -25327 10847 -17412 22972 -25986 25025 11212 17712 12490 -3830 -2880 28636 18097 -9579 -14303 -12904 17958 15138 42878 4110 -4977 19589 43590 -24912 18172 -3936 26988 2295 10350 20110 9102 34762 -3459 -6093 8987 -18212 18011 1412 8729 509 -2284 -574 -12763 -3202 -36352 -5910 14616 31909 -15787 11944 4726 19811 4912 6290 -3050 63203 -5986 -28053 -8908 5029 1509 -12040 18613 32232 -9861 -15751 -2566 -7302 49986 3817 60425 -16278 -5847 28942 12580 -5861 8530 9388 36824 32657 17483 12665 17264 -5730 -27620 -2993 10052 -386 -10117 20797 5095 32191 -12549 57280 -3854 4851 2033 -20282 -17764 12016 19610 19039 -9392 -9804 -456 9702 23516 -4487 -9632 1449 41354 6125 22293 -1758 14202 -9316 -6827 -26869 22159 3922 27869 3617 28557 608 31839 -3987 5675 1134 28192 -35823 24960 -21708 15247 9221 6734 6972 -22120 -265 -390 17509 10291 -7770 10630 8793 -4459 -24349 -764 -28219 8864 21753 -35230 10183 -21035 19005 -35198 21808 11461 16933 12341 -4363 -3218 23628 16692 -11701 -18640 -16907 17759 15426 33351 4557 -5919 17934 30752 -32970 15784 -4287 22691 2528 10758 19098 9558 28416 -4080 -7432 9504 -24851 17134 1540 8692 540 -2454 -594 -14623 -3355 -52710 -6479 13227 24053 -18206 10376 4365 15756 4507 5713 -3009 33292 -6088 -35128 -9201 4500 1387 -12592 14662 22863 -10730 -18332 -2620 -7740 30308 3476 31178 -16793 -5380 19251 10002 -5699 7212 7690 22749 20620 12761 9916 13327 -5666 -34604 -3018 9033 -385 -11095 16853 4705 22601 -13321 31145 -3765 4437 1920 -23773 -20392 10353 15784 15502 -9900 -10125 -422 8022 16984 -4312 -9975 1368 26969 5597 17401 -1721 12021 -9929 -7110 -33389 16694 3383 18811 3098 SO 20190424T103127.0Z 7053.438507 169 1 32.01 2 89.00 73.08 67.92 194.04 0.00 1 0.00 1 0 15 9.166e-02 8.664e-02 9.074e-02 8.859e-02 2.234974e+03 5.039076e+03 7.299071e+01 -6.000000e+00 4.675908e+03 278.40 -2.00 20.00 -2.00 505.23 0.00e+00 -2.926339e-04 2.316545e-03 5.978298e-05 -6.000000e+00 2.485828e-03 278.40 -2.00 20.00 -2.00 499.95 0.00e+00 2.066979e+00 1.735029e+00 3.611139e-02 -6.000000e+00 1.776419e+00 228.96 -2.00 3.57 -2.00 501.61 0.00e+00 18.735 0.128 489.00 513.00 1 1.0171e+01 1.3201e-01 3.1974e-02 -6.0000e+00 1.3534e-01 1.2478e-01 3.5204e-02 1.8566e-03 -6.0000e+00 3.6144e-02 4.6606e-06 1.8598e-03 6.8099e-03 1.7666e-05 -6.0000e+00 7.1487e-03 1.6656e-02 -1.3232e-04 12 8 8 10 0 0 15.96 15.00 2.27 0.01666 0.02956 8 1 1 4 0 4000.000 21.79 15.00 18.57 -1861 -7688 -5653 6035 7696 2581 10498 1190 2971 -16537 10443 6554 2232 -766 -7657 -3939 -2499 -4897 11380 6838 283 -1244 -3002 -16343 11179 -1992 -3073 -1444 -669 10104 9299 -2521 7433 10314 -1990 -9569 -6143 5167 7378 -1741 -3471 10700 14898 1767 7461 -1359 -2479 687 16663 8520 3749 -8619 -4789 2107 -7427 8596 1354 -6767 -1150 686 1114 -5846 -1741 -6834 10314 4702 6743 2145 -6632 -3965 4226 765 6164 -3241 -1397 10290 -18086 -3556 1038 -10013 -17004 8525 -2644 35768 4341 3974 -6067 7875 6264 -2061 -6411 1633 -1769 8684 27344 -10055 10836 -8067 13510 5275 -15938 -3604 4165 -2710 1043 -6676 9068 -7177 3763 -19331 4401 -11877 9681 9859 2254 7962 -382 17846 1964 10920 15355 8410 20217 14400 3532 -1141 -1684 12494 -14221 -9082 -5054 10982 -15501 -8011 -7111 -4392 10433 1174 -1363 -1121 9045 2778 5113 -8061 3443 -15400 11594 3747 22261 -8907 -1812 -8010 -5965 5933 7649 2744 10571 1330 3270 -21718 10362 6674 2336 -811 -8577 -4255 -2690 -5535 11375 7272 320 -1428 -3499 -21680 11439 -2318 -3593 -1653 -745 9695 8713 -2648 7199 10107 -2292 -11988 -7340 5446 7503 -1907 -3851 10394 14032 1910 7716 -1536 -2816 745 15238 8232 3660 -9178 -4812 1982 -7872 8114 1408 -7678 -1231 715 1151 -6500 -1870 -7700 9771 4621 6363 2082 -6938 -3979 3853 722 5572 -3262 -1403 9193 -20720 -3449 952 -10166 -18494 7325 -2545 23883 3976 3693 -6220 7034 5664 -2021 -6578 1569 -1793 8006 20747 -10715 9235 -8028 10618 4377 -16041 -3261 3615 -2644 1015 -6993 8018 -7260 3364 -21683 3996 -12833 8602 8818 2175 7283 -382 15035 1914 9576 12660 7276 15455 11761 3232 -1090 -1616 10419 -15267 -9324 -4978 9057 -16167 -7673 -6699 -4091 8684 1091 -1314 -1091 8019 2620 4743 -8551 3278 -17519 9959 3359 16234 -8718 SO 20190424T103545.0Z 7053.441493 173 1 32.01 2 88.25 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