File name: Pandora103s1_Downsview_20190517_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T035352.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190517_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190517 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190517T095716.0Z 7076.414769 201 1 32.01 2 89.77 63.00 96.07 261.89 0.00 1 0.00 1 0 15 5.665e-02 5.606e-02 5.403e-02 5.318e-02 8.483805e+03 3.509071e+03 4.875942e+02 -6.000000e+00 2.920350e+03 281.02 -2.00 20.00 -2.00 505.30 0.00e+00 4.176037e-04 1.415364e-03 5.391446e-05 -6.000000e+00 1.547208e-03 281.02 -2.00 20.00 -2.00 500.09 0.00e+00 2.441490e+00 1.059279e+00 7.205958e-02 -6.000000e+00 1.103031e+00 231.01 -2.00 3.57 -2.00 501.74 0.00e+00 20.166 0.160 489.00 513.00 1 9.3878e+00 8.0690e-02 3.6567e-02 -6.0000e+00 8.4015e-02 1.0442e-01 2.1236e-02 2.4970e-03 -6.0000e+00 2.2584e-02 8.0036e-06 1.1172e-03 3.9168e-03 5.5044e-05 -6.0000e+00 4.4264e-03 2.7570e-03 -1.3645e-04 12 8 8 10 0 0 -1.83 15.00 5.89 0.00276 0.01051 8 1 1 4 0 4000.000 21.88 15.00 18.74 900000 -16070 99 -3930 4853 1134 3063 -5412 -4145 7454 861 10882 2847 -5038 5665 11669 -2441 -4478 3365 -5525 -3517 3072 3778 2127 1932 -6798 -3882 -5672 -3079 -1613 3204 161 -4270 -1348 4172 -7859 -28 -1386 -1795 3219 8488 -1249 7652 -428 11062 8270 12373 0 4785 767 -2471 -1144 -11382 9128 -7675 2432 -856 2348 -6899 5938 2774 193 -4205 1957 -4511 1940 -3263 -2242 683 -87 472 8727 -1623 2986 3202 -6751 17562 7798 -5128 1438 -1267 -1123 7823 2062 2246 -1423 5645 -1948 2579 4389 5786 10601 2289 -3710 611 -6398 -7625 -1579 11093 1273 7778 5536 -2085 3073 4940 1432 641 -466 -2681 1691 -9204 -292 6928 5126 5895 -13331 1718 1152 5134 -12972 2628 417 -6829 -7364 10625 -8360 -8470 1585 1868 -3008 6730 1149 3942 -4820 197 1816 -3474 8185 2722 -902 593 -3858 -9419 1337 2425 4699 -3294 8732 1845 -3397 900000 -17669 96 -4134 4833 1193 3234 -6312 -4795 7626 922 10435 2914 -5469 5479 10630 -2574 -4929 3555 -6509 -4062 3327 4059 2323 2129 -8191 -4524 -6700 -3490 -1727 3157 163 -4568 -1454 4463 -9613 -31 -1549 -1986 3343 8337 -1354 7687 -470 11008 8501 12183 0 4925 803 -2582 -1140 -12254 8018 -8129 2431 -910 2449 -7862 5920 2837 203 -4654 2040 -4976 1978 -3425 -2290 672 -85 450 7660 -1589 2837 3090 -7175 14384 6831 -5020 1310 -1182 -1056 6788 1900 2094 -1394 5169 -1911 2403 4004 5216 9218 2201 -3807 589 -6396 -7474 -1414 8559 1056 5969 4386 -1842 2733 4530 1377 615 -443 -2553 1544 -9519 -282 6284 4753 5428 -14809 1666 1140 4897 -14530 2474 392 -6768 -7378 9054 -8580 -8709 1477 1724 -2922 5953 1050 3428 -4524 175 1611 -3346 7193 2553 -889 582 -3971 -10299 1324 2381 4497 -3354 7690 1691 -3248 SO 20190517T100132.0Z 7076.417732 205 1 32.01 2 89.08 63.73 96.81 262.58 0.00 1 0.00 1 0 15 3.061e-02 3.068e-02 2.629e-02 2.612e-02 7.650835e+03 1.680092e+03 5.005560e+02 -6.000000e+00 1.578001e+03 281.02 -2.00 20.00 -2.00 505.33 0.00e+00 3.241578e-03 7.017965e-04 1.877568e-04 -6.000000e+00 8.359938e-04 281.02 -2.00 20.00 -2.00 500.38 0.00e+00 2.483089e+00 5.123846e-01 6.472131e-02 -6.000000e+00 5.958882e-01 231.01 -2.00 3.57 -2.00 501.98 0.00e+00 18.855 0.131 489.00 513.00 1 8.7986e+00 3.9052e-02 3.2902e-02 -6.0000e+00 4.5389e-02 6.3472e-02 1.0230e-02 2.2426e-03 -6.0000e+00 1.2198e-02 1.6669e-05 9.4790e-04 1.9309e-03 7.1247e-05 -6.0000e+00 2.3916e-03 9.4570e-03 -1.6301e-04 12 8 8 10 0 0 -13.10 15.00 1.23 0.00946 0.01603 8 1 1 4 0 4000.000 21.88 15.00 18.75 900000 -4620 47 1117 3010 -270 5572 165 1333 -4047 1492 -7399 2815 -5261 471 5019 1875 -1630 -405 1059 3923 2353 1633 1165 4812 -158 2602 50 211 -6468 -3518 -1708 -2939 -2244 -2023 2251 -1204 2703 -2672 521 -1284 1392 373 82 3579 6802 1428 -2206 -1865 4040 -2266 -4215 -1131 -2318 207 -7943 1918 -1572 5133 2105 -1077 5256 4066 3729 2543 55 -450 1624 -3045 -1493 -1045 -1773 -1581 2711 -5973 805 -3867 -1237 1273 922 4323 2869 -1456 1412 -2573 1016 -3595 3588 -6162 -1543 2542 4567 -898 67 -4165 31 943 4040 862 -4534 1974 -4507 3870 -1865 401 6758 903 -2061 1863 -1595 -1556 -1980 1004 -267 -4277 1017 -2777 808 1910 3867 2389 3378 -1557 6758 306 -699 -1668 3991 -675 4414 2269 -347 -92 -1697 -2645 -6555 -2706 -3352 219 -2268 -399 1078 3203 -2522 6244 -2488 3569 432 1875 -2428 900000 -4369 44 1079 2945 -278 5540 176 1408 -4454 1525 -8135 2765 -5494 460 4685 1819 -1673 -425 1120 4028 2453 1714 1230 4948 -172 2743 54 223 -7002 -3567 -1697 -2995 -2357 -2222 2412 -1319 2807 -2887 539 -1349 1437 393 88 3769 6993 1544 -2441 -2025 4061 -2343 -4301 -1097 -2270 202 -8775 1985 -1705 5214 2186 -1148 5304 4181 3848 2639 58 -464 1612 -3132 -1490 -1020 -1740 -1562 2605 -6352 801 -3932 -1194 1183 854 3863 2621 -1396 1320 -2531 976 -3615 3345 -6263 -1494 2372 4229 -897 67 -4265 30 868 3500 751 -4060 1632 -4000 3268 -1756 386 6183 865 -1993 1705 -1515 -1509 -1968 981 -267 -4451 1008 -2886 822 1925 3766 2312 3169 -1509 6091 298 -688 -1662 3767 -663 4146 2178 -335 -86 -1606 -2513 -6547 -2685 -3418 218 -2348 -409 1094 3202 -2680 6111 -2641 3515 426 1774 -2376 SO 20190517T100542.0Z 7076.420625 209 1 32.00 2 88.40 64.44 97.54 263.25 0.00 1 0.00 1 0 15 2.079e-02 2.066e-02 1.866e-02 1.853e-02 8.026036e+03 1.202292e+03 5.923389e+02 -6.000000e+00 1.071821e+03 281.02 -2.00 20.00 -2.00 505.31 0.00e+00 2.884743e-03 4.948034e-04 1.649348e-04 -6.000000e+00 5.678502e-04 281.02 -2.00 20.00 -2.00 500.24 0.00e+00 1.837877e+00 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