File name: Pandora103s1_Downsview_20190523_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T035329.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190523_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190523 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190523T095143.0Z 7082.410914 144 1 32.01 2 89.79 61.13 67.07 191.28 0.00 1 0.00 1 0 22 2.326e-01 1.905e-01 2.185e-01 2.006e-01 -1.301001e+04 1.035166e+04 9.610362e+02 -6.000000e+00 1.202503e+04 281.65 -2.00 20.00 -2.00 505.33 0.00e+00 5.034813e-03 5.341505e-03 1.379879e-04 -6.000000e+00 6.350484e-03 281.65 -2.00 20.00 -2.00 500.43 0.00e+00 6.923451e+00 3.835802e+00 1.466807e-01 -6.000000e+00 4.484049e+00 231.40 -2.00 3.57 -2.00 502.04 0.00e+00 20.170 0.160 489.00 513.00 1 1.0370e+01 2.9233e-01 3.8215e-02 -6.0000e+00 3.4240e-01 2.4154e-02 7.4898e-02 3.7561e-03 -6.0000e+00 9.0636e-02 1.9970e-06 1.0384e-02 1.4129e-02 1.7220e-04 -6.0000e+00 1.8108e-02 2.1258e-02 3.4415e-04 12 8 8 10 0 0 3.79 15.00 14.15 0.02126 0.09328 8 1 1 4 0 4000.000 21.88 15.00 18.78 4157 -19948 -3884 -4530 2741 1109 -11219 -28182 43968 -19528 28491 -23940 -20081 3669 39184 6595 -1510 24798 41952 -7565 -19141 21630 2009 38081 1233 49467 3543 3539 -14502 28345 -22630 50030 16699 3978 2000 44363 28048 10808 22783 -7615 -646 -4134 7598 -14564 47961 -3540 30186 -12322 10816 -5388 37730 53201 -11703 -2230 -19241 40482 -7905 30211 23359 -6510 -7766 -6350 9693 -4024 3369 6578 -21326 39088 -10180 23444 -4398 62563 208 464 -6496 38278 -1337 -23887 387 -1105 30334 11002 4751 -18355 30470 -334 2151 -6572 16704 7161 -4607 6115 42594 29322 49063 -23089 17729 4212 38310 -24585 17049 -19130 4326 -13997 9257 -14164 -10976 4733 -354 34761 18998 32324 -25664 -6653 20623 50587 -4579 18218 -20921 51383 -2012 3054 -8846 36946 10904 47758 35176 49787 2871 -1528 20104 -2547 -15233 -12769 -15556 38154 -7562 -3753 33860 -12297 -2059 -23255 -9608 -8467 19892 -16780 14110 -11154 13602 -4788 3778 -23665 -4128 -4982 2866 1204 -13883 -41048 31686 -25270 23028 -31473 -25037 3612 27548 6398 -1621 21416 31205 -9000 -25430 19494 2193 29803 1376 34814 3843 3754 -17473 22068 -28706 32324 15455 4330 2231 32587 23734 10628 19797 -8856 -711 -4760 7944 -19065 34752 -4164 25394 -15305 10517 -5908 26633 31880 -13041 -2344 -24674 30116 -9392 24834 20349 -7523 -9140 -7402 9668 -4525 3464 6422 -26763 27254 -11129 18285 -4469 33959 207 466 -6913 25887 -1289 -28319 363 -1056 21711 9463 4328 -20984 21953 -322 2022 -6733 13801 6508 -4758 5862 29545 23363 32791 -30914 15732 4095 26042 -29922 13968 -22492 4159 -15993 8209 -15219 -11181 4111 -327 23600 15454 24002 -34075 -7476 17971 32991 -4963 15526 -25447 31274 -2032 2965 -9800 26614 10054 31114 25772 31869 2899 -1606 16900 -2598 -17143 -13848 -17553 26677 -8389 -4066 25753 -14475 -2189 -30567 -11246 -9899 17655 -20569 12364 -12081 11636 -4988 SO 20190523T095610.0Z 7082.414005 148 1 32.01 2 89.08 61.90 67.22 192.36 0.00 1 0.00 1 0 43 1.017e-01 9.708e-02 1.002e-01 9.758e-02 9.093391e+03 6.373976e+03 1.554166e+03 -6.000000e+00 5.255410e+03 281.65 -2.00 20.00 -2.00 505.28 0.00e+00 3.744442e-03 2.574203e-03 1.991065e-04 -6.000000e+00 2.779769e-03 281.65 -2.00 20.00 -2.00 500.14 0.00e+00 2.530782e+00 1.934515e+00 3.215799e-02 -6.000000e+00 1.971782e+00 231.40 -2.00 3.57 -2.00 501.75 0.00e+00 18.838 0.130 489.00 513.00 1 1.0136e+01 1.4742e-01 3.2557e-02 -6.0000e+00 1.5039e-01 8.8549e-02 3.8966e-02 2.2421e-03 -6.0000e+00 4.0096e-02 4.2763e-06 -2.0002e-02 7.1743e-03 1.4729e-04 -6.0000e+00 7.9348e-03 -3.5429e-04 5.3219e-05 12 8 8 10 0 0 -0.12 15.00 4.96 -0.00035 -0.13910 8 1 1 4 0 4000.000 21.88 15.00 18.78 9733 -10840 -3296 -1844 -626 1774 522 18067 -1630 -4372 2739 10201 3505 6100 9539 5988 -13099 -2745 4776 7551 -9157 -151 -1458 9171 -5462 7064 -227 754 2802 -8248 674 -5508 3291 8352 2222 -11937 -2880 -2597 13630 -4647 5145 -14990 21004 -6446 15729 4146 -2808 5705 2361 -1100 -3460 30850 522 14727 -7872 17701 2389 7040 -8472 9620 2738 5126 -296 -7090 -5465 8323 -15256 970 -24879 -5710 -11876 -9294 4449 -4908 21881 2294 7799 -3245 12792 -7966 -35 -2148 13050 -15695 4140 7796 5523 -5113 2462 -5493 14932 -5206 -3545 12565 10451 19167 15126 6435 -8213 4676 3022 -600 -30225 -5960 3636 5158 -10063 20079 -21586 -752 -9062 159 13101 8620 2914 16961 9956 -5749 -4653 7503 12067 -529 19839 -4879 31812 -1794 -8176 4527 -736 -11650 12818 -5178 17354 -1401 9206 17895 -4565 -6103 -2707 9119 -3995 3911 -7452 6583 7546 -1176 -4602 -5546 -8883 14078 8492 -11241 -3205 -1825 -639 1826 555 16550 -1834 -5066 2930 9949 3595 6016 8941 5741 -15060 -2880 4757 7572 -11016 -167 -1622 9209 -6324 7319 -254 833 3024 -9748 700 -5852 3198 7825 2288 -14777 -3324 -2952 13044 -5237 5212 -18394 18364 -7433 14850 4439 -3242 6051 2556 -1212 -3822 23700 520 12530 -8287 14938 2431 7061 -10015 9524 2875 5237 -321 -8249 -6264 8305 -18813 1001 -32391 -6113 -13290 -9966 4161 -5061 17661 2274 7328 -3311 10888 -8159 -33 -2056 10860 -17336 3782 6956 5094 -5224 2323 -5541 12301 -5214 -3537 10967 9400 15563 12382 5550 -7910 3876 2484 -502 -33882 -5452 3198 4682 -10707 15817 -24946 -698 -9147 149 11117 7727 2780 14162 8909 -6051 -4923 7074 10719 -520 15638 -4803 22134 -1750 -8504 4174 -715 -12493 10899 -5243 13830 -1308 7689 13674 -4382 -6125 -2684 8150 -4110 3763 -8030 6225 7103 -1206 -4860 -5815 -9347 11545 SO 20190523T100022.0Z 7082.416921 152 1 32.01 2 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