File name: Pandora103s1_Downsview_20190612_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T041954.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190612_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190612T094227.0Z 7102.404479 260 1 32.01 2 89.78 57.28 118.53 295.29 0.00 1 0.00 1 0 15 3.067e-02 3.024e-02 2.817e-02 2.801e-02 5.144431e+03 1.724224e+03 3.295135e+02 -6.000000e+00 1.597986e+03 283.73 -2.00 20.00 -2.00 505.36 0.00e+00 4.444418e-03 7.549113e-04 2.552203e-04 -6.000000e+00 8.429490e-04 283.73 -2.00 20.00 -2.00 500.50 0.00e+00 3.137169e+00 5.420388e-01 5.777552e-02 -6.000000e+00 5.957551e-01 232.69 -2.00 3.57 -2.00 502.09 0.00e+00 20.085 0.158 489.00 513.00 1 8.6302e+00 4.1324e-02 3.6589e-02 -6.0000e+00 4.5453e-02 4.5556e-02 1.0786e-02 2.2247e-03 -6.0000e+00 1.2141e-02 1.5653e-05 7.7021e-04 2.1105e-03 6.8342e-05 -6.0000e+00 2.3924e-03 1.5229e-02 -1.7962e-04 12 8 8 10 0 0 98.41 15.00 4.01 0.01523 0.02057 8 1 1 4 0 4000.000 21.98 15.00 18.89 -6729 -6373 6102 -766 319 2450 -314 3958 -926 -2835 1201 -5693 1031 -803 1960 -420 -966 5083 -5819 1786 307 3937 649 8004 -1475 1629 -1787 -1129 3692 3484 -1880 1500 -4123 -1715 -3669 3330 4471 346 -1049 462 1717 2009 549 2 -2018 -1433 5785 1533 -2412 -1735 -1905 -678 -275 -6619 -1386 -4153 1554 -124 773 1651 2805 622 -693 3740 -1798 -30 -3763 7735 -3002 2065 788 -1185 -3030 -626 3459 4720 -4086 5645 3755 559 3695 -3548 -3942 2887 5104 -4557 -1018 -5961 2251 -1600 1443 562 3737 -3347 408 -1377 2408 2561 2992 -10002 -863 -1264 2709 -4410 3188 -1332 -384 -2954 -1234 146 69 2103 800 4999 2693 1883 1970 2197 -686 1112 -5532 3440 1064 864 824 -1412 -2025 -3133 -538 627 4547 -1340 3997 -405 -2155 -1501 1924 1035 2493 -2209 1464 1933 -187 -1369 2797 -2241 -1601 -3695 -1398 190 -6282 -5990 5252 -737 314 2406 -324 3980 -979 -3019 1205 -6027 1009 -786 1849 -405 -945 4793 -6310 1837 320 3958 674 7757 -1583 1710 -1935 -1211 3718 3368 -1847 1423 -4190 -1768 -4038 3482 4570 362 -1101 472 1734 2040 573 2 -2229 -1587 5966 1629 -2622 -1836 -1956 -666 -264 -6751 -1379 -4421 1614 -132 819 1723 2883 658 -747 3865 -1950 -32 -4010 7250 -3092 1995 757 -1158 -3041 -622 3360 4524 -4167 5100 3412 520 3331 -3461 -3880 2664 4661 -4619 -997 -6091 2108 -1551 1362 542 3580 -3479 404 -1355 2230 2302 2607 -9637 -747 -1107 2349 -4304 3006 -1320 -372 -2877 -1163 137 66 2019 790 4798 2659 1881 1987 2236 -716 1123 -5849 3271 1023 841 814 -1429 -2068 -3236 -540 625 4372 -1337 3705 -388 -2084 -1460 1865 1035 2488 -2339 1508 1986 -197 -1472 2898 -2431 -1697 -3877 -1394 185 SO 20190612T094648.0Z 7102.407500 264 1 32.01 2 89.11 58.02 119.22 296.18 0.00 1 0.00 1 0 15 1.411e-02 1.354e-02 2.048e-03 2.024e-03 1.102493e+04 1.280232e+02 7.282556e+02 -6.000000e+00 7.350232e+02 283.73 -2.00 20.00 -2.00 505.49 0.00e+00 9.984156e-03 5.482500e-05 5.289786e-04 -6.000000e+00 3.876846e-04 283.73 -2.00 20.00 -2.00 501.34 0.00e+00 1.570450e+00 3.771745e-02 1.142624e-01 -6.000000e+00 2.739683e-01 232.69 -2.00 3.57 -2.00 502.78 0.00e+00 18.857 0.131 489.00 513.00 1 5.9465e+00 2.8723e-03 3.5853e-02 -6.0000e+00 2.0903e-02 -6.1062e-02 7.3796e-04 2.7640e-03 -6.0000e+00 5.5820e-03 2.8134e-04 2.6733e-04 1.4998e-04 1.5929e-04 -6.0000e+00 1.1005e-03 1.4861e-02 -1.6158e-04 12 8 8 10 0 0 83.02 15.00 4.20 0.01486 0.01672 8 1 1 4 0 4000.000 21.98 15.00 18.90 -5041 -4519 -2786 -1342 27 562 834 1510 2070 1073 603 -203 -1029 -1168 -1793 -1508 -1583 -629 407 885 821 551 999 1004 1477 1513 1527 1289 635 -925 -2013 -2271 -1661 -280 809 1884 1068 243 391 -58 -2 197 707 1341 2049 2296 1764 1732 849 251 -871 -1669 -2778 -2013 -1483 -297 711 1164 991 970 956 830 1242 1517 1583 598 242 -371 -321 -1253 -1700 -1399 -1074 -343 -138 269 -646 -1359 -1797 -1544 -1896 -1616 -967 -1253 -770 -482 -504 -170 -304 83 -97 587 1078 1867 1640 1445 1306 80 -1020 -2268 -2994 -2885 -1791 -898 487 537 12 -1422 -891 -905 -161 359 884 1698 2041 2409 2040 2279 2034 1168 687 195 -185 824 707 553 1050 599 607 1018 526 -22 -987 -1713 -1877 -1652 -1194 -43 393 440 515 3 624 618 867 102 -76 -1169 -2314 -2867 -4056 -3668 -2308 -1152 23 501 761 1392 1903 984 543 -182 -917 -1026 -1569 -1315 -1396 -561 372 822 762 512 928 939 1398 1452 1470 1243 608 -861 -1828 -2066 -1528 -265 797 1730 980 222 383 -57 -2 182 665 1282 1988 2255 1748 1705 834 244 -832 -1563 -2590 -1867 -1412 -293 719 1192 1021 997 984 866 1307 1600 1664 626 250 -380 -326 -1269 -1702 -1395 -1078 -348 -142 276 -655 -1354 -1779 -1517 -1867 -1599 -956 -1246 -772 -487 -509 -170 -301 81 -96 587 1105 1933 1679 1440 1266 76 -960 -2111 -2754 -2663 -1687 -886 496 554 12 -1464 -903 -929 -169 386 896 1732 2093 2479 2141 2436 2192 1253 726 203 -191 852 746 590 1123 647 655 1101 574 -24 -1048 -1820 -1992 -1774 -1316 -48 440 501 594 3 726 723 1015 120 -88 -1333 -2602 -3230 SO 20190612T095055.6Z 7102.410366 268 1 33.23 2 88.48 58.73 119.87 297.03 0.00 1 0.00 1 0 22 1.013e-02 9.917e-03 7.553e-04 7.502e-04 1.082976e+04 4.707806e+01 7.354827e+02 -6.000000e+00 5.278877e+02 283.73 -2.00 20.00 -2.00 505.44 0.00e+00 6.898433e-03 2.042981e-05 3.710814e-04 -6.000000e+00 2.784818e-04 283.73 -2.00 20.00 -2.00 501.13 0.00e+00 1.538864e+00 1.410579e-02 9.338691e-02 -6.000000e+00 1.968610e-01 232.69 -2.00 3.57 -2.00 502.61 0.00e+00 17.284 0.101 489.00 513.00 1 4.7856e+00 1.0731e-03 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