File name: Pandora103s1_Downsview_20190619_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T041951.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190619_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190619 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190619T094233.0Z 7109.404549 134 1 32.01 2 89.78 56.85 76.28 218.00 0.00 1 0.00 1 0 22 1.757e-01 8.815e-02 9.236e-02 8.129e-02 8.062735e+03 5.595346e+03 1.641118e+02 -6.000000e+00 9.212836e+03 284.41 -2.00 20.00 -2.00 505.43 0.00e+00 1.967967e-03 2.230645e-03 6.380989e-05 -6.000000e+00 4.838698e-03 284.41 -2.00 20.00 -2.00 500.06 0.00e+00 5.028616e+00 1.626414e+00 1.201029e-01 -6.000000e+00 3.431108e+00 232.91 -2.00 3.57 -2.00 501.75 0.00e+00 20.069 0.157 489.00 513.00 1 9.6114e+00 1.2404e-01 3.6895e-02 -6.0000e+00 2.6139e-01 4.4032e-02 3.1972e-02 2.8215e-03 -6.0000e+00 6.9773e-02 5.1567e-06 -2.3970e-03 6.0347e-03 1.5730e-05 -6.0000e+00 1.3715e-02 6.3041e-03 -7.5610e-05 12 8 8 10 0 0 13.25 15.00 7.33 0.00630 -0.01032 8 1 1 4 0 4000.000 22.09 15.00 19.03 -5413 -41 -7247 -6518 10674 2980 -19080 -4440 913 813 -13294 4373 -9800 4996 3721 4084 -218 1245 2782 12828 11099 -7327 10752 -8517 -5339 -7009 -7097 5081 7302 5022 13002 -5327 737 8667 -3873 -3499 9439 6515 8637 -2444 14219 3752 1418 -2767 -13576 6975 1412 6445 -8673 9355 -14365 4595 -1931 -6526 59 5409 -6622 13595 4304 2233 816 16023 8374 8977 -8532 -8615 17909 11272 1463 4797 8294 3260 17250 2317 3625 5608 -2116 3507 -2461 -4958 1246 -9483 182918 900000 3693 -1722 1763 -2381 13046 -7525 6291 -10525 3132 -5890 8750 -4031 3087 7784 -1439 2246 11321 12217 2306 15933 -6256 29358 -12731 4889 4104 16653 756 -8655 -2261 4494 -7812 -2056 18744 6584 5450 -4235 -5890 -12663 5609 -11201 -867 -11671 14684 -7974 -7564 390 7563 -10608 7009 -14685 1855 15782 -3733 -3308 6490 -1714 -10806 8099 7943 9072 696 -12619 -13014 14273 5960 -374 -5274 -38 -7451 -6953 9972 3059 -24824 -5104 1002 886 -16293 4458 -11326 4918 3666 4003 -224 1291 2944 12627 11121 -8777 10807 -10330 -6331 -8507 -8596 5448 7565 5111 11773 -5726 755 8515 -4505 -4142 9758 6817 8739 -2716 13383 3927 1536 -3158 -17441 7393 1577 6769 -10379 9209 -17230 4429 -1937 -6800 59 5331 -7563 12944 4481 2352 866 14727 8341 8885 -9951 -9901 15568 10252 1447 4527 7420 3046 14169 2227 3498 5315 -2112 3221 -2355 -4818 1136 -9647 29804 900000 3370 -1677 1661 -2322 10864 -7605 5565 -11059 2942 -6099 7736 -3913 2712 6336 -1247 1834 8320 8951 1916 12237 -6254 21103 -13629 4330 3593 12912 697 -8912 -2215 4156 -8161 -2035 15327 6151 5168 -4352 -6028 -13545 4943 -11689 -831 -12469 12183 -8255 -7762 372 6759 -11096 6048 -15498 1660 12488 -3681 -3328 6017 -1747 -12175 7637 7551 8593 718 -14784 -15108 12381 5451 -360 SO 20190619T094650.0Z 7109.407523 138 1 32.01 2 89.13 57.59 76.74 218.87 0.00 1 0.00 1 0 36 6.061e-02 5.818e-02 5.441e-02 5.382e-02 8.261384e+02 3.002467e+03 8.632239e+01 -6.000000e+00 3.166184e+03 284.41 -2.00 20.00 -2.00 505.33 0.00e+00 4.964944e-03 1.445316e-03 2.753814e-04 -6.000000e+00 1.669193e-03 284.41 -2.00 20.00 -2.00 500.34 0.00e+00 4.921181e+00 1.059450e+00 4.751311e-02 -6.000000e+00 1.180728e+00 232.91 -2.00 3.57 -2.00 501.95 0.00e+00 18.877 0.131 489.00 513.00 1 9.3358e+00 8.0739e-02 3.3075e-02 -6.0000e+00 9.0025e-02 3.0710e-02 2.1353e-02 1.8889e-03 -6.0000e+00 2.4188e-02 7.9962e-06 -6.8597e-03 4.1093e-03 7.3940e-05 -6.0000e+00 4.7364e-03 2.5947e-02 -2.8017e-04 12 8 8 10 0 0 2.97 15.00 5.85 0.02595 -0.02163 8 1 1 4 0 4000.000 22.09 15.00 19.04 900000 -1618 -1265 -4209 -998 -1133 7242 4675 183 634 -2579 -3628 6201 -3197 -8644 -6809 -796 -326 2853 -2715 1442 -8 -1618 -1422 -5874 6545 -7713 7427 -1037 9634 -8650 7758 -2907 24359 3019 3728 1014 -3009 1492 1284 -473 -1243 10012 -1227 -1303 437 5417 3551 17008 -5424 4200 -184 5394 -12299 534 -10906 3945 7418 3568 -926 -4893 -760 7442 -3766 -3025 3562 -3967 6216 -12039 3636 -6560 7748 -7092 857 3533 7540 -8084 9486 -1588 1529 -2197 2691 -4230 2735 3464 1082 8468 -6350 -5107 -6429 -2061 -5480 8045 7314 7704 -332 2867 3758 -622 -3451 -7791 -2778 10738 -7811 -1857 -10313 12611 5330 943 -8155 -8884 -1744 -169 6369 824 11454 4802 8277 -1972 15192 4363 1332 0 -6641 2948 3160 3272 -748 12750 1529 -140 855 -5687 -7356 -3592 -3551 -5246 -7389 -1599 -222 9623 -5398 2618 3399 -1826 1829 -679 3302 -3997 -1874 900000 -1482 -1183 -4224 -1011 -1175 7070 4778 197 677 -2786 -3890 5972 -3317 -9325 -7174 -793 -329 2873 -2976 1527 -8 -1760 -1545 -6712 6707 -9089 7534 -1134 9199 -9426 7078 -2965 19530 3122 3960 1104 -3351 1569 1337 -497 -1324 9678 -1343 -1448 483 5728 3791 15698 -6122 4201 -185 5016 -13422 520 -12321 3998 7424 3725 -1003 -5470 -817 7447 -4213 -3350 3656 -4293 5966 -13616 3490 -6812 6918 -7340 829 3383 7011 -8618 8279 -1513 1402 -2077 2437 -4128 2494 3149 1018 7439 -6415 -5065 -6430 -1977 -5471 7183 6729 7090 -326 2685 3419 -574 -3178 -7291 -2456 8445 -7620 -1784 -10907 10529 4681 847 -7957 -8881 -1667 -163 5866 811 10227 4602 7730 -2036 13097 4104 1271 0 -6775 2787 3003 3110 -742 11052 1481 -139 833 -5767 -7455 -3469 -3422 -5259 -7796 -1622 -225 8952 -5825 2619 3402 -1939 1879 -709 3227 -4054 -1825 SO 20190619T095102.1Z 7109.410441 142 1 32.15 2 88.49 58.31 77.21 219.71 0.00 1 0.00 1 0 15 5.230e-02 5.225e-02 4.430e-02 4.384e-02 5.790375e+03 2.766429e+03 3.698961e+02 -6.000000e+00 2.732651e+03 284.41 -2.00 20.00 -2.00 505.30 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