File name: Pandora103s1_Downsview_20190623_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T042004.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20181123.txt Level 1 file used: Pandora103s1_Downsview_20190623_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190623T094323.0Z 7113.405127 134 1 32.01 2 89.78 56.84 56.51 173.83 0.00 1 0.00 1 0 22 3.404e-02 3.333e-02 3.293e-02 3.271e-02 4.011819e+03 1.967710e+03 1.626190e+02 -6.000000e+00 1.781143e+03 284.78 -2.00 20.00 -2.00 505.27 0.00e+00 1.997371e-03 8.782885e-04 1.264697e-04 -6.000000e+00 9.384987e-04 284.78 -2.00 20.00 -2.00 500.31 0.00e+00 2.022810e+00 6.372920e-01 6.112351e-02 -6.000000e+00 6.633244e-01 232.93 -2.00 3.57 -2.00 501.91 0.00e+00 20.059 0.157 489.00 513.00 1 8.9117e+00 4.8610e-02 3.6157e-02 -6.0000e+00 5.0579e-02 9.7130e-02 1.2873e-02 2.2311e-03 -6.0000e+00 1.3592e-02 1.3359e-05 5.1953e-03 2.4741e-03 3.5493e-05 -6.0000e+00 2.6602e-03 -1.2708e-02 -6.6432e-05 12 8 8 10 0 0 0.68 15.00 3.79 -0.01271 0.02333 8 1 1 4 0 4000.000 22.19 15.00 19.08 900000 -5113 -397 573 619 11032 -427 3516 4314 2613 -4386 2984 1131 -6421 -918 -5160 1591 3575 -3843 5400 995 -555 -126 8034 -1979 2464 -87 1755 -10 1166 -5619 -141 6672 -4418 -2850 -975 328 -1237 150 -4348 620 -3506 1910 -2303 4131 267 5639 1639 2837 -305 2748 -1495 170 -1583 -987 -2527 -3363 995 487 1536 -2472 472 -1652 2554 -3081 1320 -3342 823 691 157 127 -2202 845 2347 -2117 770 -6360 -1557 -1384 -4876 6094 -4160 -1406 -4601 6994 5850 -2456 1719 1602 -2876 -1353 -3306 1281 164 1202 -2574 -4651 -1193 556 1888 -8095 5759 1780 -295 652 -1778 -240 1883 -1296 -3701 -6612 3218 956 1531 5381 1998 3843 2820 1007 -292 7203 -412 -7807 4291 3932 7723 420 2355 318 1503 3034 -2972 -1945 -3658 2567 -773 -3713 -1337 9795 -2011 1842 -2480 852 -2754 -677 -758 -855 2276 338 987 900000 -4942 -380 567 629 10313 -457 3670 4471 2718 -4787 2996 1138 -6842 -919 -5380 1570 3550 -4243 5546 1064 -602 -136 8031 -2200 2632 -95 1872 -11 1170 -5844 -139 6264 -4815 -3193 -1084 355 -1338 158 -4729 642 -3807 1991 -2535 4327 292 5824 1735 2923 -317 2674 -1470 161 -1532 -978 -2646 -3647 1045 513 1587 -2647 495 -1779 2637 -3335 1346 -3493 813 677 152 121 -2153 810 2252 -2155 759 -6544 -1492 -1310 -4746 5336 -4068 -1345 -4559 6275 5362 -2440 1633 1515 -2842 -1322 -3340 1265 165 1178 -2556 -4604 -1110 495 1619 -7559 4756 1582 -281 638 -1781 -233 1753 -1225 -3608 -6770 3050 940 1511 5128 1974 3764 2812 1016 -293 6586 -397 -8027 3968 3687 6976 408 2238 307 1442 2858 -2901 -1842 -3482 2286 -722 -3681 -1321 8790 -2049 1818 -2558 856 -2884 -696 -776 -859 2147 316 914 SO 20190623T094753.0Z 7113.408252 138 1 32.01 2 89.10 57.61 56.42 175.12 0.00 1 0.00 1 0 15 1.862e-02 1.846e-02 1.673e-02 1.665e-02 9.291567e+03 1.088482e+03 5.889991e+02 -6.000000e+00 9.740380e+02 284.78 -2.00 20.00 -2.00 505.39 0.00e+00 1.088951e-03 4.511694e-04 5.135999e-05 -6.000000e+00 5.129362e-04 284.78 -2.00 20.00 -2.00 500.57 0.00e+00 2.342246e+00 3.202874e-01 7.042981e-02 -6.000000e+00 3.613679e-01 232.93 -2.00 3.57 -2.00 502.16 0.00e+00 18.796 0.129 489.00 513.00 1 8.3697e+00 2.4455e-02 3.2540e-02 -6.0000e+00 2.7584e-02 3.1472e-02 6.3404e-03 2.3809e-03 -6.0000e+00 7.3600e-03 2.6851e-05 5.7865e-04 1.2328e-03 6.5897e-05 -6.0000e+00 1.4524e-03 5.0839e-03 -6.9742e-05 12 8 8 10 0 0 66.27 14.99 1.29 0.00508 0.00910 8 1 1 4 0 4000.000 22.19 14.99 19.09 -3510 -240 187 -905 -950 -973 -970 -1536 94 2028 -1347 1254 -1804 -1053 -3146 1756 1054 1372 2028 319 2154 243 933 73 50 1001 1515 1752 22 -1008 -1096 -3072 2123 -1566 266 204 1908 -1245 626 -761 -2896 1195 510 2699 999 -1780 259 3029 -581 -959 115 -3518 -1007 -3043 -1602 1058 1872 2466 334 1936 1420 1609 313 2393 -652 2650 -178 1897 3885 -2307 -2176 10 3817 -4448 167 -3114 2939 -1452 503 -2174 23 -3494 -2448 -2454 -496 -2073 749 -2153 1139 1475 1300 1795 769 -193 -378 2957 -679 997 -410 -2220 -2083 -1698 -245 -1 -1532 1971 -1013 527 646 124 -1655 1596 -1509 1312 2583 413 804 2634 624 -1295 4090 -2690 3684 -104 2570 -506 2480 -3257 -2666 -40 3504 -2498 1402 -34 2201 -1711 1763 1318 -2203 20 -1422 -1969 -377 -848 -311 1374 -2483 3013 -1776 -792 -3133 -210 168 -860 -931 -972 -993 -1606 97 2037 -1372 1232 -1802 -1027 -3103 1652 1008 1342 2042 333 2213 254 971 77 53 1057 1587 1825 23 -1017 -1070 -3054 2038 -1619 283 220 2005 -1329 648 -789 -3058 1221 531 2785 1062 -1956 278 3131 -613 -994 114 -3502 -959 -2953 -1574 1056 1908 2530 349 1980 1454 1656 329 2463 -687 2665 -180 1853 3692 -2294 -2126 10 3555 -4558 167 -3202 2785 -1398 469 -2068 22 -3396 -2373 -2390 -481 -2069 729 -2146 1092 1405 1244 1732 765 -195 -375 2749 -634 888 -362 -1950 -1805 -1485 -219 -1 -1543 1942 -1018 512 617 119 -1653 1572 -1546 1316 2562 420 824 2694 652 -1357 3985 -2735 3471 -103 2502 -508 2426 -3368 -2726 -40 3396 -2508 1329 -32 2050 -1682 1730 1325 -2321 21 -1527 -2135 -406 -922 -337 1460 -2697 3020 -1818 -799 SO 20190623T095207.0Z 7113.411192 142 1 32.01 2 88.45 58.34 56.35 176.33 0.00 1 0.00 1 0 22 1.003e-02 9.767e-03 3.447e-03 3.424e-03 1.242308e+04 2.248517e+02 8.096402e+02 -6.000000e+00 5.249309e+02 284.78 -2.00 20.00 -2.00 505.48 0.00e+00 1.999977e-03 9.333010e-05 1.131591e-04 -6.000000e+00 2.765998e-04 284.78 -2.00 20.00 -2.00 501.07 0.00e+00 1.631453e+00 6.454137e-02 8.990764e-02 -6.000000e+00 1.954124e-01 232.93 -2.00 3.57 -2.00 502.59 0.00e+00 17.187 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