File name: Pandora103s1_Downsview_20190627_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T042059.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190627_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190627T094445.0Z 7117.406076 246 1 32.01 2 89.78 57.00 55.99 119.45 0.00 1 0.00 1 0 22 2.260e-02 2.253e-02 1.984e-02 1.973e-02 1.243073e+04 1.345602e+03 7.779855e+02 -6.000000e+00 1.183806e+03 285.14 -2.00 20.00 -2.00 505.44 0.00e+00 3.733130e-03 5.346292e-04 1.858593e-04 -6.000000e+00 6.219325e-04 285.14 -2.00 20.00 -2.00 500.72 0.00e+00 2.672107e+00 3.780921e-01 9.804679e-02 -6.000000e+00 4.343331e-01 232.95 -2.00 3.57 -2.00 502.28 0.00e+00 20.048 0.157 489.00 513.00 1 8.2661e+00 2.8930e-02 3.6891e-02 -6.0000e+00 3.3216e-02 2.3427e-02 7.3474e-03 2.9425e-03 -6.0000e+00 8.7672e-03 2.3389e-05 2.0336e-03 1.4373e-03 8.6786e-05 -6.0000e+00 1.7547e-03 1.3623e-02 -9.4339e-05 12 8 8 10 0 0 -8.51 15.00 3.18 0.01362 0.02773 8 1 1 4 0 4000.000 22.09 15.00 19.08 -4150 -98 -1247 -3040 -3818 2918 753 2072 1147 -1775 -679 -699 -2035 -2420 73 -2738 1767 849 4782 -3028 -37 -901 707 1618 -901 69 -476 412 -2116 1684 -3544 1401 1166 2488 930 4061 -1852 -864 1805 436 -2104 1650 -2170 1665 2813 1988 1047 463 2675 562 746 -2536 -572 -1127 1745 1829 2484 -1462 2877 -1789 2801 -1886 2918 263 -312 -2007 1407 -1870 2628 -219 263 -1138 -664 -401 -888 542 -3071 -443 -3023 1205 -3156 -1465 -3004 177 -1521 2626 -1354 2411 -37 1561 2736 706 -1543 607 1808 -770 -205 -424 503 -2830 -1644 -3962 3588 108 5617 -4321 3270 -2964 3215 -3594 1606 -1419 666 765 3240 1466 3164 4033 -590 -2892 350 -1473 -2621 440 -2960 5188 3473 465 428 2206 -2750 2530 -3581 -1699 624 -2220 1871 1360 -1612 1100 2047 2198 -543 -3469 1339 2037 2857 -2806 -3397 -5382 -3740 -88 -1183 -3025 -3904 2861 767 2087 1153 -1799 -673 -684 -1983 -2344 69 -2687 1700 853 4719 -3218 -38 -939 728 1668 -959 73 -502 423 -2134 1583 -3501 1340 1163 2566 988 4137 -1969 -899 1811 444 -2212 1697 -2351 1765 2971 2113 1110 487 2697 560 719 -2477 -548 -1117 1753 1890 2583 -1578 2959 -1919 2897 -2055 3039 280 -328 -2102 1403 -1907 2528 -213 255 -1127 -664 -407 -903 530 -3033 -421 -2922 1116 -3071 -1410 -2948 171 -1511 2505 -1332 2264 -36 1474 2589 697 -1565 589 1674 -705 -181 -367 422 -2417 -1403 -3590 3208 105 5249 -4410 3047 -2889 2971 -3629 1572 -1444 667 768 3181 1486 3219 4087 -616 -3021 345 -1457 -2645 437 -3054 4966 3384 465 430 2180 -2785 2388 -3565 -1658 605 -2283 1885 1393 -1727 1162 2155 2325 -592 -3897 1431 2129 2885 -2922 -3541 -5801 SO 20190627T094859.0Z 7117.409016 250 1 32.01 2 89.14 57.73 55.33 120.41 0.00 1 0.00 1 0 22 1.094e-02 1.073e-02 2.231e-03 2.210e-03 2.129556e+04 1.555703e+02 1.383463e+03 -6.000000e+00 5.731750e+02 285.14 -2.00 20.00 -2.00 505.54 0.00e+00 3.839353e-03 6.007704e-05 2.150843e-04 -6.000000e+00 3.011291e-04 285.14 -2.00 20.00 -2.00 501.26 0.00e+00 1.922463e+00 4.152797e-02 1.374855e-01 -6.000000e+00 2.103089e-01 232.95 -2.00 3.57 -2.00 502.71 0.00e+00 18.875 0.131 489.00 513.00 1 6.0629e+00 3.1684e-03 3.4641e-02 -6.0000e+00 1.6084e-02 -6.2045e-02 8.0214e-04 3.8547e-03 -6.0000e+00 4.2452e-03 2.6062e-04 1.1536e-03 1.5022e-04 1.4544e-04 -6.0000e+00 8.4965e-04 3.6965e-03 -3.6117e-05 12 8 8 10 0 0 87.26 14.99 3.01 0.00370 0.01170 8 1 1 4 0 4000.000 22.19 14.99 19.08 -3372 -2336 -1016 -241 677 906 889 1384 731 293 -553 -555 -1105 -1499 -794 -911 -220 493 651 721 1070 535 643 938 1296 905 934 235 -1168 -1952 -1244 -1627 -163 1132 1087 704 93 -342 -388 -659 -152 1214 1008 1173 1507 1539 1033 1006 241 -577 -1915 -2085 -2063 -1266 -54 467 396 589 564 1032 771 1387 1076 1018 771 111 -149 -640 -1196 -1515 -1108 -829 -72 -240 -228 -706 -921 -1373 -1306 -1354 -597 -771 -430 -486 130 -464 -150 -679 -19 439 942 1485 1839 1557 1083 491 120 -848 -2410 -2503 -2289 -1822 -68 565 422 196 -840 -1216 -843 -459 -17 -16 823 843 1951 1812 2125 1212 796 -47 -152 -451 327 663 684 959 749 651 321 259 -234 -532 -646 -1378 -1112 -469 161 856 499 823 176 679 607 1174 718 480 -1332 -2322 -2003 -1632 -2880 -2048 -922 -208 591 809 810 1262 665 263 -495 -491 -968 -1307 -688 -800 -197 454 613 680 1007 507 613 903 1255 880 907 227 -1096 -1784 -1129 -1507 -155 1121 1098 707 93 -339 -382 -651 -151 1212 1027 1215 1573 1607 1074 1033 245 -573 -1871 -2003 -1982 -1244 -54 488 421 626 597 1087 822 1487 1079 1019 821 117 -155 -664 -1233 -1543 -1124 -847 -75 -235 -224 -681 -934 -1379 -1301 -1345 -593 -774 -434 -464 125 -451 -144 -649 -18 412 894 1437 1780 1463 1049 457 108 -757 -2150 -2206 -2042 -1694 -63 549 422 198 -842 -1206 -840 -467 -18 -17 850 869 1994 1894 2288 1338 874 -51 -159 -464 336 693 720 1014 799 692 345 280 -248 -554 -674 -1455 -1195 -519 180 962 537 900 196 760 682 1312 803 533 -1473 -2544 -2182 -1798 SO 20190627T095313.8Z 7117.411965 254 1 33.61 2 88.49 58.45 54.67 121.39 0.00 1 0.00 1 0 22 8.425e-03 8.189e-03 1.127e-03 1.120e-03 2.002842e+04 7.906451e+01 1.318017e+03 -6.000000e+00 4.413446e+02 285.14 -2.00 20.00 -2.00 505.48 0.00e+00 3.300317e-03 3.050770e-05 1.926207e-04 -6.000000e+00 2.318726e-04 285.14 -2.00 20.00 -2.00 501.07 0.00e+00 1.748461e+00 2.114651e-02 1.232299e-01 -6.000000e+00 1.619619e-01 232.95 -2.00 3.57 -2.00 502.56 0.00e+00 17.277 0.100 489.00 513.00 1 5.4721e+00 1.6153e-03 3.0274e-02 -6.0000e+00 1.2386e-02 -5.3132e-02 4.0995e-04 3.4629e-03 -6.0000e+00 3.2696e-03 6.0091e-04 9.1049e-04 7.6902e-05 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