File name: Pandora103s1_Downsview_20190628_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T041932.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190628_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190628T094510.0Z 7118.406366 260 1 32.01 2 89.78 57.06 59.89 106.41 0.00 1 0.00 1 0 15 1.841e-02 1.826e-02 1.703e-02 1.694e-02 1.151076e+04 1.138185e+03 7.980430e+02 -6.000000e+00 9.642003e+02 285.24 -2.00 20.00 -2.00 505.46 0.00e+00 4.155631e-03 4.597040e-04 2.224177e-04 -6.000000e+00 5.065233e-04 285.24 -2.00 20.00 -2.00 500.84 0.00e+00 2.588422e+00 3.243175e-01 7.825395e-02 -6.000000e+00 3.538800e-01 232.96 -2.00 3.57 -2.00 502.38 0.00e+00 20.046 0.157 489.00 513.00 1 8.1101e+00 2.4798e-02 3.6713e-02 -6.0000e+00 2.7059e-02 1.3065e-02 6.3222e-03 2.6978e-03 -6.0000e+00 7.1516e-03 2.7408e-05 -1.7480e-03 1.2434e-03 9.4691e-05 -6.0000e+00 1.4292e-03 2.0824e-01 -1.3432e-03 12 8 8 10 0 0 -2.46 14.99 3.32 0.20824 0.19612 8 1 1 4 0 4000.000 22.19 14.99 19.12 -3811 -2078 208 -1605 40 -868 -365 -592 -957 2817 831 510 353 -1985 -2235 -1566 -2659 1072 -217 -1378 932 -1149 -631 1112 977 2300 1755 -2748 1630 -695 -1596 -1159 1862 -65 1773 175 466 676 894 1567 464 596 1445 1567 2496 1403 2075 -684 -1301 913 -2365 -4727 -1008 42 909 252 2182 19 937 4125 848 1263 -666 1564 -1558 -799 3211 339 -984 -901 -1353 260 563 -1973 -1411 -480 -1856 -1248 1192 -1863 -2120 86 -437 -2437 3702 -48 960 -1219 -366 -1320 170 1021 3969 1812 1007 692 466 -1997 3315 -3935 -3034 368 -2641 742 794 877 979 -1562 2268 1959 2858 -620 -1293 1787 -1595 2132 -724 480 475 -2708 -177 -3819 3278 -2495 1086 3207 2338 1331 1321 1120 2162 -57 -3630 -1074 -2027 -2026 -1419 1592 2972 2216 -3174 -1116 -1673 3768 -1577 2091 -1483 -2045 -1337 -1139 -3362 -1864 191 -1548 39 -868 -369 -603 -968 2692 799 486 331 -1886 -2127 -1494 -2622 1055 -222 -1419 939 -1182 -647 1134 1006 2335 1787 -2881 1573 -661 -1527 -1119 1812 -68 1846 183 480 686 895 1559 471 613 1495 1645 2622 1489 2166 -723 -1358 905 -2344 -4698 -964 41 911 262 2265 20 980 4167 890 1331 -717 1640 -1660 -829 3150 338 -983 -884 -1329 253 554 -2029 -1446 -478 -1820 -1199 1110 -1780 -2045 81 -419 -2411 3500 -47 928 -1192 -352 -1284 165 1006 3846 1763 955 637 417 -1783 2752 -3441 -2644 320 -2500 717 782 858 942 -1514 2122 1878 2776 -630 -1334 1795 -1658 2163 -771 509 497 -2867 -179 -3918 3153 -2579 1091 3168 2337 1338 1332 1137 2134 -56 -3671 -1056 -2031 -2092 -1491 1644 3075 2341 -3552 -1232 -1868 4001 -1760 2226 -1595 -2152 -1382 -1187 SO 20190628T094923.2Z 7118.409297 264 1 10.44 2 89.14 57.79 59.17 107.24 0.00 1 0.00 1 0 29 1.081e-02 1.062e-02 2.644e-03 2.630e-03 2.051982e+04 1.823771e+02 1.345043e+03 -6.000000e+00 5.662963e+02 285.24 -2.00 20.00 -2.00 505.48 0.00e+00 5.952768e-03 7.181428e-05 3.272540e-04 -6.000000e+00 2.974847e-04 285.24 -2.00 20.00 -2.00 501.14 0.00e+00 1.784112e+00 4.956842e-02 1.339725e-01 -6.000000e+00 2.077533e-01 232.96 -2.00 3.57 -2.00 502.62 0.00e+00 18.878 0.131 489.00 513.00 1 5.6036e+00 3.7836e-03 3.5066e-02 -6.0000e+00 1.5888e-02 -6.5063e-02 9.6107e-04 3.6780e-03 -6.0000e+00 4.1943e-03 4.0500e-04 1.0607e-03 1.8078e-04 1.6601e-04 -6.0000e+00 8.3933e-04 -3.5989e-03 -4.2974e-06 12 9 9 12 1 1 999.00 15.01 3.00 -0.00360 0.00376 2 2 1 4 0 3423.890 22.19 15.01 19.13 -3345 -2378 -1143 59 189 1233 1330 1564 987 296 -333 -294 -1447 -1214 -1336 -671 -135 277 608 880 416 436 634 898 993 929 1392 263 -1280 -1713 -1478 -1613 26 593 1551 1396 68 194 -614 -184 -132 574 886 1322 1764 1289 724 1001 31 -1187 -1599 -1893 -1671 -1232 -514 619 1176 810 728 990 748 594 684 1479 637 180 -359 -388 -967 -1135 -1486 -737 -325 -186 -275 -360 -1158 -1571 -1903 -1246 -857 -635 -448 -223 493 57 -775 -203 -163 143 466 1365 1453 1148 1423 915 -77 -831 -2249 -2260 -2373 -1324 -855 164 949 162 -898 -1030 -815 -579 -111 187 976 1486 1249 1925 1912 1454 785 -334 -379 -96 527 1006 908 1080 480 924 501 142 -524 -219 -1295 -1240 -804 -429 28 422 660 687 520 -83 886 1072 864 94 -1146 -1989 -1646 -1587 -2960 -2041 -1017 53 176 1165 1280 1509 949 282 -314 -274 -1344 -1115 -1229 -620 -127 269 571 825 392 412 602 862 963 903 1346 253 -1203 -1647 -1417 -1491 24 589 1558 1392 67 192 -607 -182 -132 581 866 1312 1765 1298 727 990 31 -1206 -1583 -1847 -1628 -1231 -507 625 1202 833 746 1013 775 624 722 1544 662 184 -364 -391 -968 -1121 -1471 -732 -326 -191 -282 -362 -1144 -1537 -1855 -1202 -828 -617 -438 -221 493 57 -780 -200 -159 140 461 1375 1474 1135 1340 870 -71 -762 -2056 -2035 -2163 -1247 -816 165 930 161 -887 -1055 -800 -583 -113 193 1002 1520 1285 2006 2057 1523 821 -362 -399 -99 540 1048 955 1144 514 984 514 147 -559 -228 -1363 -1308 -821 -451 30 454 723 767 563 -91 966 1166 939 102 -1229 -2203 -1811 -1695 SO 20190628T095341.3Z 7118.412283 268 1 16.57 2 88.48 58.52 58.44 108.09 0.00 1 0.00 1 0 22 8.531e-03 8.383e-03 1.163e-03 1.158e-03 1.880313e+04 7.958979e+01 1.229590e+03 -6.000000e+00 4.470851e+02 285.24 -2.00 20.00 -2.00 505.46 0.00e+00 5.135471e-03 3.148976e-05 2.879758e-04 -6.000000e+00 2.348490e-04 285.24 -2.00 20.00 -2.00 501.07 0.00e+00 1.610274e+00 2.173423e-02 1.237011e-01 -6.000000e+00 1.639144e-01 232.96 -2.00 3.57 -2.00 502.57 0.00e+00 17.257 0.100 489.00 513.00 1 4.9833e+00 1.6576e-03 3.0656e-02 -6.0000e+00 1.2537e-02 -5.1339e-02 4.2264e-04 3.3493e-03 -6.0000e+00 3.3074e-03 9.6895e-04 5.0892e-04 8.0494e-05 1.4780e-04 -6.0000e+00 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