File name: Pandora103s1_Downsview_20190629_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T042001.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190629_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190629T094538.0Z 7119.406690 276 1 32.01 2 89.78 57.14 65.24 94.23 0.00 1 0.00 1 0 15 7.151e-02 6.881e-02 6.385e-02 6.250e-02 4.214935e+03 3.886929e+03 2.942871e+02 -6.000000e+00 3.749506e+03 285.33 -2.00 20.00 -2.00 505.28 0.00e+00 1.651227e-03 1.681307e-03 2.462428e-05 -6.000000e+00 1.969185e-03 285.33 -2.00 20.00 -2.00 500.02 0.00e+00 3.910242e+00 1.236661e+00 2.797225e-02 -6.000000e+00 1.376026e+00 232.96 -2.00 3.57 -2.00 501.67 0.00e+00 20.040 0.157 489.00 513.00 1 9.4054e+00 9.4557e-02 3.5749e-02 -6.0000e+00 1.0522e-01 9.2912e-02 2.4643e-02 2.0722e-03 -6.0000e+00 2.7801e-02 7.0924e-06 -1.8297e-03 4.6558e-03 2.7770e-05 -6.0000e+00 5.5572e-03 -8.0621e-03 -3.0035e-05 12 8 8 10 0 0 0.04 15.00 4.56 -0.00806 -0.02075 8 1 1 4 0 4000.000 22.29 15.00 19.23 -360 2088 -5266 2363 -9830 15866 -7584 1810 -10946 12964 -8392 -918 -8321 -6063 3003 6019 2981 1168 -6759 492 8678 -1021 3826 8394 14024 -4415 5808 -5782 -1431 6395 -3745 -9452 1954 -4238 11767 -2650 7415 -5546 -7036 4418 10123 -1151 8346 2681 2071 4810 -5069 442 1780 4942 -6195 14719 -7663 -1419 -758 -43 -5401 3662 -4153 5653 -6589 4693 -937 -5310 2319 -204 5897 7189 13248 952 4068 2468 -1330 -9713 1300 -13230 8119 -3711 4620 693 8273 4693 -2504 -3712 9076 4769 9957 10672 -236 4021 10984 -3358 6432 8261 -2946 -6169 -7171 5937 2844 2070 -14506 13525 3627 9246 -3979 -2003 -28 5477 -11137 5113 -13827 -8252 7124 -4031 4721 1332 -1433 -1072 -67 -5291 3882 13506 -3827 -7312 9657 -6073 14796 2366 -7141 25075 1089 -1121 1491 -11922 6701 -7851 -2821 2083 -2466 4120 -6861 3747 -3530 -91 1726 12381 2944 -11886 -8366 7919 -345 2005 -5665 2446 -11681 15009 -9183 2013 -13691 12609 -9897 -995 -9515 -6692 3024 5918 3077 1268 -8148 554 9014 -1165 4161 8788 14002 -5256 6236 -6872 -1571 6230 -3983 -10724 2043 -4935 12033 -3095 7718 -6457 -8192 4569 9934 -1273 8512 2927 2292 5180 -5940 483 1882 4911 -6617 12512 -8016 -1419 -783 -45 -6130 3809 -4622 5674 -7467 4798 -1012 -5956 2381 -210 5610 6672 11442 908 3735 2314 -1309 -10554 1276 -14655 7095 -3573 4067 631 7045 4169 -2388 -3613 7905 4342 8587 9081 -223 3638 9358 -3352 5924 7416 -2879 -6071 -6934 4913 2362 1697 -13981 10173 3144 7952 -3945 -1926 -26 4700 -11181 4458 -14782 -8484 6377 -4042 4355 1278 -1428 -1066 -65 -5297 3488 10871 -3657 -7333 8240 -6037 12022 2156 -7151 18463 996 -1023 1309 -11814 5571 -7732 -2717 1940 -2432 3849 -7154 3539 -3606 -90 1683 10754 2725 -12311 -8250 6719 SO 20190629T095001.0Z 7119.409734 280 1 32.01 2 89.11 57.89 64.46 94.99 0.00 1 0.00 1 0 22 5.063e-02 4.849e-02 4.600e-02 4.534e-02 5.853285e+03 2.908810e+03 2.158638e+02 -6.000000e+00 2.654076e+03 285.33 -2.00 20.00 -2.00 505.32 0.00e+00 1.247988e-03 1.221859e-03 1.190026e-04 -6.000000e+00 1.393974e-03 285.33 -2.00 20.00 -2.00 500.21 0.00e+00 3.279115e+00 8.871644e-01 7.831813e-02 -6.000000e+00 9.737314e-01 232.96 -2.00 3.57 -2.00 501.84 0.00e+00 18.813 0.130 489.00 513.00 1 9.2963e+00 6.7872e-02 3.2717e-02 -6.0000e+00 7.4464e-02 6.9110e-02 1.7554e-02 2.2497e-03 -6.0000e+00 1.9668e-02 9.8939e-06 2.0035e-03 3.3775e-03 3.3065e-05 -6.0000e+00 3.9328e-03 1.6892e-02 -1.6198e-04 12 8 8 10 0 0 -6.61 15.00 4.73 0.01689 0.03079 8 1 1 4 0 4000.000 22.29 15.00 19.25 197 -5582 7613 3416 1249 -5750 3331 2224 297 -6814 9536 -4612 1340 -7424 -3633 -161 2587 2633 -493 3972 3964 2647 -573 -3320 -2246 671 -5636 -1942 2357 2605 -3697 1808 389 -3698 -3579 486 -3300 3542 9532 7763 -5075 2062 1935 2848 1567 -2705 -912 620 -2018 8073 3052 10437 -2111 -7136 -1766 -4715 395 -1884 6188 289 823 -2927 6456 112 -3040 -2506 6153 -2666 11955 9877 -2879 -2287 -3518 3079 -5256 5167 -3931 -2272 -7780 6092 10862 1781 -5613 3265 -1945 3578 -6299 -6067 6320 -300 -1204 -1258 5230 -7180 840 -3301 4645 -9143 125 5173 11756 -2507 5906 -716 -1782 -6411 2312 1127 12987 3639 -1769 2680 467 6305 4259 2406 -7009 8226 -7410 2219 2636 5028 -1025 -3694 -6218 -9205 -1196 -4176 -6962 1679 -917 1536 9257 3049 10999 3002 -7033 7133 7615 1710 8731 -8797 19 -3870 5641 -542 -2914 1477 -1332 -4831 183 -5665 7100 3422 1302 -6565 3539 2396 323 -7781 9177 -5026 1354 -8085 -3809 -165 2638 2778 -548 4224 4217 2851 -637 -3822 -2571 743 -6612 -2162 2411 2565 -3860 1814 411 -4251 -4176 539 -3734 3698 9265 7649 -5696 2182 2075 3067 1718 -3081 -1007 663 -2169 7604 2918 9090 -2070 -7531 -1841 -5209 420 -2045 6159 303 863 -3204 6445 118 -3253 -2612 5790 -2706 10367 8583 -2825 -2251 -3554 2968 -5489 4758 -3848 -2158 -7738 5285 9078 1636 -5556 3003 -1904 3324 -6410 -6121 5637 -286 -1172 -1250 4920 -7497 790 -3145 3978 -8719 106 4125 8871 -2245 5138 -694 -1758 -6535 2121 1026 10562 3304 -1724 2533 455 5815 4014 2331 -7532 7615 -7858 2101 2433 4472 -975 -3653 -6308 -9627 -1156 -4133 -7112 1579 -867 1386 7673 2667 9017 2745 -7250 6490 6994 1678 8031 -9654 19 -4090 5421 -545 -2908 1373 -1262 -4795 SO 20190629T095414.0Z 7119.412662 284 1 32.01 2 88.46 58.62 63.72 95.72 0.00 1 0.00 1 0 22 1.587e-02 1.579e-02 1.454e-02 1.445e-02 1.670173e+04 1.038919e+03 1.081626e+03 -6.000000e+00 8.323247e+02 285.33 -2.00 20.00 -2.00 505.43 0.00e+00 3.390348e-03 3.910791e-04 1.985819e-04 -6.000000e+00 4.371309e-04 285.33 -2.00 20.00 -2.00 500.59 0.00e+00 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