File name: Pandora103s1_Downsview_20190703_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T041935.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190703_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190703T094743.0Z 7123.408137 332 1 32.01 2 89.78 57.54 96.50 51.75 0.00 1 0.00 1 0 29 1.138e-01 1.073e-01 1.107e-01 1.073e-01 6.288352e+03 6.897775e+03 2.493447e+02 -6.000000e+00 5.975076e+03 285.69 -2.00 20.00 -2.00 505.22 0.00e+00 2.784642e-03 2.919800e-03 2.200576e-04 -6.000000e+00 3.136792e-03 285.69 -2.00 20.00 -2.00 500.14 0.00e+00 -7.839863e-01 2.127920e+00 6.574980e-02 -6.000000e+00 2.189735e+00 232.98 -2.00 3.57 -2.00 501.76 0.00e+00 20.032 0.157 489.00 513.00 1 1.0284e+01 1.6252e-01 3.6381e-02 -6.0000e+00 1.6746e-01 1.8464e-01 4.3008e-02 2.2558e-03 -6.0000e+00 4.4257e-02 4.0551e-06 -5.0956e-03 8.2048e-03 5.3256e-05 -6.0000e+00 8.8442e-03 7.4889e-02 -5.5049e-04 12 8 8 10 0 0 0.69 15.00 11.10 0.07489 0.03954 8 1 1 4 0 4000.000 22.19 15.00 19.13 2472 -16888 14364 2538 -2661 -3960 12145 16312 8473 -8737 16414 -16095 -4466 12130 -3941 -12438 2822 22426 2256 15058 -3983 10154 -2623 -4546 -2201 1687 6237 -1591 12386 4737 17244 273 -13729 12928 -16362 12451 -2483 13006 3067 -9540 -18487 5734 15445 -3381 -3203 -7856 16991 -15976 5147 -4501 -4280 13917 -13485 -10325 1233 1483 10746 4202 -8277 7858 -6979 25375 10532 19488 -12263 8059 -9989 14571 -730 17425 -5147 19507 -591 -10028 -1226 12120 11630 -19007 -3772 3952 10057 1679 13767 2242 5785 1993 21842 -946 -18365 -17 784 -14351 4755 -10304 4319 -75 10840 -8742 -3595 1895 17129 10767 6658 9934 -4162 15085 12001 7997 -14723 5123 -11286 46009 -5683 -7489 -5604 5140 -6165 10081 -4233 7507 -10184 -4369 4012 464 -18677 -8231 -4921 499 11426 4013 -4016 14778 13285 -12824 21472 20747 7615 -1445 -6515 -10752 4681 10303 18544 -1572 4468 1350 4771 -12266 15426 -9885 2334 -19670 12870 2643 -2971 -4565 12201 15835 8814 -10518 15219 -20170 -4904 11175 -4212 -14472 2877 19486 2450 14495 -4594 10194 -2975 -5279 -2517 1855 6528 -1779 11686 4598 14602 274 -16202 12350 -21376 12253 -2776 12343 3160 -11023 -23364 5796 14388 -3832 -3659 -9404 15851 -20191 5211 -4864 -4456 11850 -14798 -11133 1236 1536 10386 4346 -9596 7743 -7956 21342 10250 17356 -14679 7772 -11250 12801 -736 14467 -5266 15827 -589 -11152 -1264 10823 10144 -21889 -3719 3601 8687 1587 11616 2131 5393 1937 17483 -937 -21419 -17 766 -16552 4643 -11581 4113 -73 9181 -8694 -3318 1622 12622 8609 5788 8801 -4317 12902 10384 7038 -16007 4666 -12287 29261 -6003 -8086 -5940 4933 -6675 9374 -4461 6914 -10884 -4320 3644 442 -21488 -8540 -4944 472 9706 3675 -3918 11699 10492 -12884 15477 15397 6579 -1378 -6593 -11443 4300 8973 14981 -1546 4133 1272 4233 -12403 11697 -9586 SO 20190703T095158.0Z 7123.411088 336 1 32.01 2 89.13 58.27 95.92 52.50 0.00 1 0.00 1 0 15 1.018e-01 9.815e-02 1.012e-01 9.875e-02 3.594301e+03 6.024215e+03 3.077587e+02 -6.000000e+00 5.340990e+03 285.69 -2.00 20.00 -2.00 505.34 0.00e+00 2.106978e-03 2.636982e-03 1.492980e-04 -6.000000e+00 2.806443e-03 285.69 -2.00 20.00 -2.00 500.24 0.00e+00 3.563511e+00 1.922922e+00 2.196641e-02 -6.000000e+00 1.965473e+00 232.98 -2.00 3.57 -2.00 501.88 0.00e+00 18.847 0.130 489.00 513.00 1 1.0056e+01 1.4624e-01 3.2372e-02 -6.0000e+00 1.5020e-01 6.1037e-02 3.8579e-02 1.8094e-03 -6.0000e+00 3.9876e-02 4.4275e-06 -1.3227e-03 7.3860e-03 4.5268e-05 -6.0000e+00 7.9342e-03 5.0826e-02 -6.5198e-04 12 8 8 10 0 0 12.67 14.99 11.11 0.05083 0.04165 8 1 1 4 0 4000.000 22.19 14.99 19.15 -2761 8372 -12855 4240 -7646 9038 1801 7263 -6799 21880 -2249 9114 -8345 -14363 -1051 5335 4772 -3342 -6948 -9561 9453 -6844 -470 -444 -12648 -6429 24258 -1988 8377 3418 1596 -3241 -5301 14069 -299 -6545 14900 15195 28211 -4591 -1283 8525 8256 -9973 10905 10857 -10170 9461 -12309 18686 -2532 -7257 10440 -10519 -17960 8878 16461 13555 -5762 10477 -10330 -1919 13 -1125 -15518 5382 5353 6823 -1092 -310 7268 -8477 15711 -1080 9458 -6523 2129 13101 10981 10707 8703 -8386 3266 -100 14880 -370 -2613 4871 2373 -2022 15801 -2920 -267 -1503 -1392 6896 -6738 23542 -14782 8574 3673 6917 -4412 -2302 9247 5932 -10826 -14173 8986 -1898 1743 301 19085 -5262 -967 2081 4013 -4309 8311 -19244 -4493 -3879 14964 -11884 13016 9461 29326 -963 5947 -4983 -10042 -17966 -8474 18876 -7546 -778 10277 -504 -15171 4441 9803 453 12475 3576 13739 1223 3374 10350 -21094 3781 -2619 7288 -14312 4161 -8606 8835 1929 7447 -7963 19074 -2435 8745 -9323 -16761 -1072 5134 4690 -3663 -8138 -11578 9501 -8054 -520 -493 -15966 -7637 21329 -2237 8272 3383 1578 -3380 -5775 13313 -337 -7818 14219 14264 23038 -5103 -1383 8444 8293 -12120 10937 10924 -12434 9419 -14875 16276 -2613 -7624 9118 -11348 -21612 8540 15031 12796 -6514 10039 -12112 -2089 14 -1216 -19065 5296 5161 6400 -1094 -302 6513 -8878 13161 -1083 8656 -6877 2005 10871 9214 8962 7456 -8556 2984 -95 12390 -359 -2586 4458 2216 -1971 13034 -2937 -267 -1520 -1380 6171 -6715 17024 -15073 6813 3042 5649 -4182 -2247 8262 5432 -11448 -15153 7604 -1807 1637 292 15640 -5500 -973 2042 3905 -4568 7716 -22894 -4548 -3836 12301 -12849 11145 8380 21494 -942 5432 -5097 -10699 -20178 -8539 14457 -7447 -735 8999 -498 -17503 4288 9025 458 11312 3556 12414 1238 3267 9067 -24514 3461 SO 20190703T095609.0Z 7123.413993 340 1 32.01 2 88.49 58.99 95.35 53.23 0.00 1 0.00 1 0 15 8.188e-02 7.954e-02 7.438e-02 7.291e-02 6.629919e+03 4.697556e+03 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