File name: Pandora103s1_Downsview_20190706_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T041953.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190706_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190706T094935.0Z 7126.409433 332 1 32.01 2 89.78 57.95 121.57 17.42 0.00 1 0.00 1 0 22 9.104e-02 8.899e-02 9.238e-02 8.977e-02 6.629380e+03 5.957945e+03 2.792908e+02 -6.000000e+00 4.784329e+03 285.97 -2.00 20.00 -2.00 505.23 0.00e+00 -4.155403e-04 2.423925e-03 6.636613e-05 -6.000000e+00 2.510484e-03 285.97 -2.00 20.00 -2.00 500.04 0.00e+00 2.730422e+00 1.790564e+00 7.537994e-02 -6.000000e+00 1.748046e+00 233.00 -2.00 3.57 -2.00 501.67 0.00e+00 20.022 0.156 489.00 513.00 1 9.8899e+00 1.3705e-01 3.6147e-02 -6.0000e+00 1.3374e-01 1.1327e-01 3.5526e-02 2.4191e-03 -6.0000e+00 3.5270e-02 4.8748e-06 -8.8433e-03 6.6216e-03 2.6395e-05 -6.0000e+00 7.0662e-03 2.6333e-02 -1.4083e-04 12 8 8 10 0 0 -7.86 15.00 6.29 0.02633 -0.03501 8 1 1 4 0 4000.000 22.29 15.00 19.35 8648 8530 8233 -1116 -16477 -14013 2182 11196 7088 3598 -12033 3632 2549 16565 -480 6315 1820 1829 7952 -3892 -2402 5867 -11665 3328 11221 -8939 11808 6117 -10194 -273 6011 -8213 11935 -2521 14181 -3072 -5270 -6746 2093 1545 13708 4359 7260 1874 -12456 2140 9636 -1950 1011 6745 -20907 14923 4680 10535 -13649 -175 -10144 13256 -1447 44 -3305 7469 -13018 6809 7156 9223 -6992 -1401 9859 -11813 7571 5574 13856 -5788 5539 642 8633 1088 7816 -10798 6103 -8156 20274 2220 20197 -5405 -3536 -10364 -14533 6006 -8582 -7292 -6329 -1712 -575 5472 13762 -16917 17835 -11310 15091 3197 -6245 8310 -1474 3895 16593 13512 -11036 3170 4769 -2875 704 -2819 6993 -5702 -7132 -2164 13296 -8132 20070 -3373 3523 671 4768 -8185 -9936 63 2526 7951 7077 12957 16298 4733 5052 -5902 -130 15085 -2169 13093 -8810 11922 -3037 7941 1230 -9482 -443 6259 -10539 -11818 7617 7673 7721 -1190 -20854 -17668 2402 11408 7499 3872 -14831 3804 2652 14828 -503 6221 1904 1973 8351 -4624 -2808 6328 -14883 3684 11591 -11196 12037 6539 -12385 -287 5851 -9229 11287 -2871 14214 -3636 -6264 -8019 2248 1652 13009 4561 7454 2051 -15804 2358 9782 -2179 1078 6614 -25829 12658 4317 9253 -15712 -183 -11941 12493 -1561 46 -3595 7368 -15691 6755 6998 8664 -7527 -1409 8800 -12762 6705 5053 11725 -6029 5231 627 7578 1006 6699 -11019 5310 -8227 15598 2049 15923 -5496 -3525 -10979 -15948 5400 -8927 -7612 -6650 -1710 -553 4823 10875 -17465 12851 -10568 10897 2647 -5926 7243 -1453 3635 13469 11047 -11297 2859 4315 -2836 676 -2809 6333 -5864 -7530 -2195 11507 -8489 15610 -3221 3129 620 4265 -8285 -10242 59 2288 6876 6112 10304 12360 3981 4237 -5637 -121 12300 -2116 11170 -9338 10387 -3079 7273 1202 -10195 -427 5476 -10629 -12083 SO 20190706T095353.0Z 7126.412419 336 1 32.01 2 89.12 58.69 121.35 18.56 0.00 1 0.00 1 0 29 5.992e-02 5.854e-02 5.203e-02 5.140e-02 1.479879e+04 3.592392e+03 8.735813e+02 -6.000000e+00 3.149848e+03 285.97 -2.00 20.00 -2.00 505.36 0.00e+00 1.431817e-03 1.382495e-03 6.953695e-05 -6.000000e+00 1.653061e-03 285.97 -2.00 20.00 -2.00 500.38 0.00e+00 1.289814e+00 9.930963e-01 1.011298e-01 -6.000000e+00 1.153173e+00 233.00 -2.00 3.57 -2.00 501.99 0.00e+00 18.814 0.130 489.00 513.00 1 9.5508e+00 7.6002e-02 3.3180e-02 -6.0000e+00 8.8200e-02 7.6940e-02 1.9418e-02 2.9258e-03 -6.0000e+00 2.3304e-02 8.7113e-06 5.9089e-03 3.6479e-03 6.8360e-05 -6.0000e+00 4.6584e-03 -3.7822e-02 1.3759e-04 12 8 8 10 0 0 -9.72 15.00 7.68 -0.03782 0.00316 8 1 1 4 0 4000.000 22.40 15.00 19.36 -11283 -6440 -9959 732 -879 8651 -1596 5833 1912 5019 -6449 -3554 307 -1626 2311 -2787 -3225 3149 -6601 -7366 1185 -7235 8467 625 4105 5715 5361 -1809 -1642 -5933 -989 119 4116 9347 6229 5007 417 -5573 5 102 7659 4781 145 6745 -2392 8442 -4757 4615 -2162 7246 371 -2635 -3457 6107 -4764 6831 -4592 10706 -2617 13025 -3646 -875 1617 -2603 5572 -1491 952 -12464 -3869 -8680 1015 -2998 12389 -7231 2323 1431 10113 -6263 3293 4897 1593 8618 -2899 -10518 313 12667 -2375 7035 6416 4299 1649 6724 -3188 13 7376 2454 -6994 -7046 -14750 10063 -6025 13797 -135 2267 4231 -1800 1404 -597 -1333 -3586 -7312 3607 5458 2497 7409 -11205 219 -6625 7981 -5921 441 -3391 13392 1041 4067 -1558 9381 8534 2791 9774 96 7104 -6037 -908 -1317 782 -1271 -709 -8502 7546 -7621 2400 -927 -5757 -4239 9188 -7509 335 -5057 103 -11519 -6488 -10843 739 -918 8430 -1745 5940 1998 4991 -7088 -3743 306 -1636 2238 -2867 -3417 3249 -7626 -8555 1267 -8391 8443 679 4324 5900 5530 -1962 -1701 -6208 -987 119 4139 9335 6484 5206 447 -6245 6 107 7497 4870 156 6920 -2696 8531 -5395 4702 -2300 6799 361 -2587 -3428 5680 -5132 6757 -5131 10284 -2841 12101 -4014 -944 1702 -2836 5514 -1548 950 -14045 -3950 -9143 973 -3022 10929 -7850 2287 1385 8763 -6284 2988 4366 1479 7520 -2848 -11318 307 11012 -2373 6348 5791 3973 1586 6278 -3272 13 6357 2132 -6443 -6366 -14078 7464 -5313 10483 -125 2165 4026 -1803 1337 -570 -1290 -3621 -7766 3461 5144 2416 6844 -12615 226 -7311 7517 -6227 424 -3323 11228 997 3789 -1537 8315 7580 2633 8587 90 6122 -5888 -842 -1250 750 -1262 -708 -9325 7159 -8434 2423 -969 -6300 -4547 8501 -7959 321 -5100 100 SO 20190706T095808.0Z 7126.415370 340 1 32.01 2 88.46 59.42 121.13 19.68 0.00 1 0.00 1 0 22 4.070e-02 4.057e-02 3.711e-02 3.655e-02 1.427169e+04 2.652209e+03 9.025820e+02 -6.000000e+00 2.138399e+03 285.97 -2.00 20.00 -2.00 505.29 0.00e+00 1.045570e-03 9.845834e-04 9.203447e-05 -6.000000e+00 1.122848e-03 285.97 -2.00 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