File name: Pandora103s1_Downsview_20190707_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T042021.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190707_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190707T095015.1Z 7127.409897 337 1 32.15 2 89.78 58.11 127.95 3.12 0.00 1 0.00 1 0 22 9.248e-02 9.080e-02 8.316e-02 8.146e-02 1.212754e+04 5.578255e+03 7.245549e+02 -6.000000e+00 4.861085e+03 286.06 -2.00 20.00 -2.00 505.36 0.00e+00 -5.158060e-04 2.194450e-03 2.026680e-04 -6.000000e+00 2.550881e-03 286.06 -2.00 20.00 -2.00 500.30 0.00e+00 2.186640e-01 1.578079e+00 9.550398e-02 -6.000000e+00 1.776511e+00 233.01 -2.00 3.57 -2.00 501.94 0.00e+00 20.020 0.156 489.00 513.00 1 9.9656e+00 1.2021e-01 3.6723e-02 -6.0000e+00 1.3591e-01 1.2407e-01 3.1088e-02 2.8355e-03 -6.0000e+00 3.5862e-02 5.4016e-06 4.6952e-03 5.9300e-03 6.6108e-05 -6.0000e+00 7.1807e-03 1.0226e-02 -7.3645e-05 12 8 8 10 0 0 0.87 15.00 3.77 0.01023 0.04279 8 1 1 4 0 4000.000 22.40 15.00 19.42 -21071 -1114 184 2340 -11506 7006 -9863 -307 -14260 18097 -13384 -6714 4582 6421 184 3321 -3274 7730 3113 1901 -10752 255 3507 -3937 -3254 -2875 3238 -9899 -88 2905 14647 2246 22975 -583 8782 5164 4615 9013 10473 373 2352 2017 15283 -15918 9596 -2710 -2657 12893 -1538 9247 1261 5923 4377 10505 -11166 -4903 2782 7573 -5260 18012 1672 7755 -13060 20130 2916 11138 -1643 -3697 10440 9062 -5387 5239 10893 -10206 16448 -7423 3453 -7434 841 -13988 -3205 4913 15447 -7659 15773 -3891 9530 1204 690 -1475 -5329 27193 3050 3512 3328 15754 -9635 16674 -7875 -2095 -11699 9774 10693 4166 -4158 -7032 -1039 -4166 6351 -10768 8514 17143 8876 -3303 7957 5270 4375 646 1812 5200 520 -13384 5371 -12783 3840 -10296 10409 5877 4440 -8555 -7812 -7960 1502 8199 -10656 2761 7441 -4394 -8494 6368 -22804 -628 -159 17756 2332 7898 -12081 11136 -9600 4321 -24217 -1092 186 2374 -13592 7078 -11898 -338 -17742 16149 -16034 -7427 4466 6092 185 3288 -3550 7800 3340 2059 -13174 281 3740 -4547 -3737 -3270 3455 -11736 -91 2825 12741 2241 19569 -650 9020 5418 4795 8848 10006 392 2438 2120 14292 -20375 9622 -3045 -2941 12080 -1618 8461 1208 5323 4005 9340 -12745 -5408 2873 7446 -5807 15834 1734 7628 -15709 17434 2932 10137 -1668 -3795 9204 7981 -5473 4857 9731 -11372 14075 -7799 3185 -7534 781 -15009 -3130 4468 12787 -8069 13420 -4007 8571 1165 669 -1465 -5573 21153 2987 3323 3038 12303 -9321 12252 -7190 -1795 -11210 7962 9202 4001 -4377 -7532 -1029 -4179 5787 -11793 7830 14566 8168 -3409 7373 5087 4335 663 1807 4895 498 -14445 4874 -13973 3570 -10991 9062 5310 4085 -8881 -7838 -7852 1343 6862 -10913 2559 6698 -4485 -9160 6004 -28676 -641 -162 15179 2299 7249 -13077 9409 -9877 3934 SO 20190707T095433.0Z 7127.412882 341 1 32.01 2 89.12 58.85 127.91 4.41 0.00 1 0.00 1 0 29 2.700e-02 2.642e-02 9.359e-03 9.248e-03 7.879175e+03 5.841093e+02 4.534188e+02 -6.000000e+00 1.419446e+03 286.06 -2.00 20.00 -2.00 505.61 0.00e+00 2.728259e-03 2.515170e-04 1.191910e-04 -6.000000e+00 7.447302e-04 286.06 -2.00 20.00 -2.00 501.43 0.00e+00 1.863681e+00 1.716126e-01 8.046425e-02 -6.000000e+00 5.183612e-01 233.01 -2.00 3.57 -2.00 502.88 0.00e+00 18.810 0.130 489.00 513.00 1 7.7317e+00 1.3112e-02 3.2859e-02 -6.0000e+00 3.9660e-02 -5.0609e-02 3.2880e-03 2.4311e-03 -6.0000e+00 1.0458e-02 5.1757e-05 2.1520e-03 6.9161e-04 5.7218e-05 -6.0000e+00 2.0955e-03 1.8759e-03 1.6389e-05 12 8 8 10 0 0 38.36 14.99 11.45 0.00188 0.01680 8 1 1 4 0 4000.000 22.40 14.99 19.43 -11007 -5593 -2310 -2712 53 765 627 204 390 -595 -1070 -2739 -4860 -3979 -3697 -2813 -1449 89 1958 1575 2097 1060 2797 2597 3060 2103 1690 -788 -2400 -4755 -2008 -1130 1461 2619 3408 1756 2098 1138 1684 -518 984 2581 2811 2372 6030 3670 3053 1478 415 -1193 -3172 -3712 -4464 -2397 -1023 3931 1224 1247 4283 4292 2674 3288 3346 3204 752 -364 -1932 -859 -1362 -4161 -3536 -1532 950 655 1449 -2473 -3203 -3073 -3671 -2647 -3384 -1725 -1096 -275 -107 -614 -1078 -554 -252 -1271 1954 3184 1404 1753 3234 1907 271 -2224 -4866 -4547 -3418 -2359 -280 1968 1753 832 -2276 -2293 -2485 171 321 1007 2967 3473 2713 5538 3603 2404 2750 1367 1366 -350 1871 855 1397 1686 1356 -1146 2714 856 -1562 -2327 -4578 -3460 -2792 -2501 223 613 1343 1946 -804 266 2048 3135 141 -294 -1634 -4107 -4674 -3514 -9375 -4685 -1964 -2392 46 684 572 188 354 -536 -959 -2466 -4404 -3547 -3292 -2517 -1314 82 1821 1472 1952 1000 2606 2456 2901 2011 1620 -761 -2258 -4442 -1829 -1040 1370 2550 3344 1733 2039 1105 1612 -508 961 2520 2786 2402 5941 3698 3063 1486 414 -1171 -3081 -3562 -4328 -2354 -1036 3912 1269 1293 4290 4299 2751 3397 3468 3312 785 -378 -2009 -877 -1380 -4274 -3618 -1557 959 677 1362 -2361 -3009 -2854 -3417 -2445 -3187 -1611 -1025 -259 -102 -591 -1039 -529 -240 -1229 1862 3075 1393 1704 3013 1752 246 -2026 -4453 -4103 -3095 -2198 -271 1951 1759 835 -2314 -2299 -2520 173 331 1049 3060 3583 2835 5713 3852 2604 2926 1448 1418 -366 1936 908 1481 1792 1447 -1252 2875 925 -1692 -2495 -4988 -3720 -3038 -2808 249 692 1533 2232 -953 315 2401 3652 169 -348 -1908 -4798 -5478 -4142 SO 20190707T095844.0Z 7127.415787 345 1 32.01 2 88.47 59.56 127.87 5.66 0.00 1 0.00 1 0 15 3.000e-02 2.990e-02 2.653e-02 2.633e-02 1.592029e+04 1.886817e+03 9.407797e+02 -6.000000e+00 1.577510e+03 286.06 -2.00 20.00 -2.00 505.40 0.00e+00 1.108757e-03 7.136114e-04 9.594073e-05 -6.000000e+00 8.277270e-04 286.06 -2.00 20.00 -2.00 500.54 0.00e+00 1.448842e+00 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