File name: Pandora103s1_Downsview_20190708_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T041908.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190708_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190708 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190708T095058.0Z 7128.410394 335 1 32.01 2 89.78 58.28 132.37 346.95 0.00 1 0.00 1 0 15 9.757e-02 9.363e-02 7.959e-02 7.748e-02 8.519107e+03 5.124038e+03 6.530993e+02 -6.000000e+00 5.132642e+03 286.15 -2.00 20.00 -2.00 505.16 0.00e+00 4.415232e-03 2.109770e-03 3.747833e-04 -6.000000e+00 2.697631e-03 286.15 -2.00 20.00 -2.00 500.13 0.00e+00 -7.073789e-01 1.546109e+00 6.964561e-02 -6.000000e+00 1.893762e+00 233.01 -2.00 3.57 -2.00 501.71 0.00e+00 20.013 0.156 489.00 513.00 1 9.9194e+00 1.1847e-01 3.7057e-02 -6.0000e+00 1.4459e-01 1.7945e-01 3.1160e-02 2.3282e-03 -6.0000e+00 3.8653e-02 5.6803e-06 2.6765e-03 5.8481e-03 1.2492e-04 -6.0000e+00 7.6184e-03 -7.7438e-02 6.8865e-04 12 8 8 10 0 0 22.18 14.99 6.60 -0.07744 -0.05887 8 1 1 4 0 4000.000 22.19 14.99 19.21 13048 4079 -6040 13458 5003 7263 4352 10831 -10504 -1224 -4389 636 -4262 7022 -14615 13823 -1923 -7600 12476 -2245 4897 10931 -3885 -3193 187 -6246 14415 4329 17799 -4735 7614 -16688 15418 -623 9128 -504 2728 186 -2521 2309 -4971 -9350 11116 -8245 -10120 13493 -10235 -1013 -3010 -425 -11371 15575 8595 16771 8086 20283 -20204 20459 -3722 2550 -1689 9178 2485 -1817 -9805 -4567 -7422 -2493 -9646 -3783 -3031 -6755 2784 -4261 7080 461 -681 14673 15492 -356 7601 -7398 10623 -10214 12980 16723 -9270 -5352 -372 228 -15092 -5138 -11005 15368 -12032 9503 -8714 21665 -8617 9729 -7015 5798 -17092 23604 -4646 17946 4810 6345 -7844 8351 -1962 -4142 9786 -2442 50 -9973 6653 -5494 8923 -15210 23265 -6356 6938 1677 10346 8792 14655 5619 12989 7932 -4836 5791 1929 17676 -2069 7090 6619 1585 3232 11550 -14075 9089 -9316 -3366 -5640 7569 -3187 2823 -8104 900000 11201 3957 -6742 12740 5229 7583 4723 11008 -12905 -1344 -4903 665 -4588 6705 -17205 12469 -2071 -8922 12200 -2518 5121 10757 -4426 -3647 208 -7334 13768 4445 15295 -4923 7041 -19891 14057 -690 9239 -551 2850 196 -2706 2371 -5532 -11014 10896 -9882 -12405 13093 -12329 -1099 -3247 -432 -12488 12970 7711 14364 7836 17914 -26640 18125 -4139 2667 -1858 9134 2635 -1992 -11404 -4947 -8150 -2585 -10536 -3848 -3070 -7168 2739 -4549 6706 454 -662 12171 12668 -340 6776 -7654 9276 -11071 11320 14024 -9922 -5468 -362 222 -17302 -5467 -12405 13101 -12977 8071 -8574 15506 -8066 7548 -6496 4932 -19158 18414 -4763 14552 4338 5571 -7999 7442 -1963 -4277 8875 -2493 50 -11130 6381 -5883 8138 -17124 17614 -6350 6165 1581 8956 7736 12120 5046 10910 6927 -4646 4924 1685 13208 -1907 6139 5829 1479 3002 9934 -15527 8039 -9863 -3356 -5692 6559 -2964 2419 -7717 900000 SO 20190708T095525.0Z 7128.413484 339 1 32.01 2 89.09 59.04 132.55 348.37 0.00 1 0.00 1 0 15 5.897e-02 5.805e-02 5.473e-02 5.391e-02 3.741125e+03 3.292788e+03 1.107935e+02 -6.000000e+00 3.101805e+03 286.15 -2.00 20.00 -2.00 505.30 0.00e+00 -7.701454e-04 1.459316e-03 8.598821e-05 -6.000000e+00 1.626972e-03 286.15 -2.00 20.00 -2.00 500.19 0.00e+00 3.518068e+00 1.048907e+00 1.017225e-01 -6.000000e+00 1.131570e+00 233.01 -2.00 3.57 -2.00 501.83 0.00e+00 18.746 0.128 489.00 513.00 1 9.4966e+00 8.0502e-02 3.2806e-02 -6.0000e+00 8.6588e-02 6.9895e-02 2.0768e-02 2.3261e-03 -6.0000e+00 2.2814e-02 8.2788e-06 -7.4251e-04 4.0349e-03 2.3840e-05 -6.0000e+00 4.5747e-03 -1.2933e-02 1.4715e-04 12 8 8 10 0 0 89.57 15.00 5.51 -0.01293 -0.01808 8 1 1 4 0 4000.000 22.29 15.00 19.22 -6719 -10521 6288 -6628 5355 -285 4944 -6548 3045 6140 -10546 593 -7918 6232 -4862 -871 3652 9568 -5331 -3390 -2387 4963 1477 -4912 2678 11116 2826 -2433 -3314 7340 5326 -7143 5554 -9748 7852 1409 5195 -3940 4151 863 10807 -2533 -506 8260 279 -4043 10058 -8336 68 1106 -1159 10448 6957 7516 3376 3966 -5778 12634 1960 4148 -7283 -2219 -3879 -1691 -2634 6661 3767 -1350 -3747 -5046 8944 4876 -6663 -2635 -3789 -1842 10552 -5135 -3638 -1879 3309 -756 83 -1 1372 2205 -2769 -9246 5169 7575 -7028 4255 2038 2824 -6400 -3651 -7724 -23 7611 6600 -5172 -3164 6154 999 -1725 9158 1511 4069 -9774 5642 -6818 -3849 1802 12576 3569 4660 1812 7311 -879 -3634 2383 9076 -2485 10059 3696 -3518 -3289 5994 10191 -4507 -8513 1794 12683 -5599 1 -4759 935 -271 -8127 -2361 649 4985 -3633 2319 2584 -2114 -7003 11488 -13450 1364 -6712 -11238 5956 -7343 5379 -310 5194 -7731 3246 6234 -12455 620 -8845 6002 -5210 -907 3725 9551 -6297 -3930 -2742 5305 1632 -5817 2957 11245 3086 -2754 -3628 6986 5151 -7900 5631 -12011 8289 1566 5475 -4475 4293 917 10451 -2814 -557 8442 310 -4660 9969 -9716 72 1112 -1150 9049 6206 6824 3321 3993 -6472 11809 2014 4146 -8174 -2383 -4233 -1795 -2776 6275 3587 -1337 -3744 -5013 7737 4426 -6868 -2659 -3865 -1800 8894 -4970 -3446 -1748 2956 -708 77 -1 1296 2071 -2722 -9640 4682 6717 -7255 4013 1980 2684 -6494 -3522 -7537 -21 6075 5247 -4656 -2886 5401 961 -1716 8082 1406 3621 -9949 5031 -6981 -3876 1732 10918 3387 4413 1781 6791 -869 -3622 2197 7738 -2390 8668 3389 -3460 -3223 5337 8751 -4472 -8611 1607 10103 -5291 1 -4663 888 -264 -8665 -2400 643 4766 -3807 2304 2555 -2154 -7263 9672 -14309 1272 SO 20190708T095939.0Z 7128.416424 343 1 32.01 2 88.43 59.77 132.71 349.72 0.00 1 0.00 1 0 15 3.222e-02 3.193e-02 2.663e-02 2.638e-02 6.444734e+03 1.703902e+03 3.912730e+02 -6.000000e+00 1.694595e+03 286.15 -2.00 20.00 -2.00 505.29 0.00e+00 2.042687e-03 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