File name: Pandora103s1_Downsview_20190712_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T044758.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190712_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190712 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190712T095358.0Z 7132.412477 286 1 32.01 2 89.78 59.03 125.25 282.00 0.00 1 0.00 1 0 22 8.648e-02 8.416e-02 7.170e-02 6.974e-02 5.409307e+03 4.477563e+03 2.120744e+02 -6.000000e+00 4.554032e+03 286.52 -2.00 20.00 -2.00 505.28 0.00e+00 5.817381e-04 1.875996e-03 3.803254e-05 -6.000000e+00 2.389290e-03 286.52 -2.00 20.00 -2.00 499.99 0.00e+00 4.380910e+00 1.373047e+00 5.518220e-02 -6.000000e+00 1.667195e+00 233.03 -2.00 3.57 -2.00 501.64 0.00e+00 20.004 0.156 489.00 513.00 1 9.4969e+00 1.0518e-01 3.5852e-02 -6.0000e+00 1.2749e-01 7.8982e-02 2.7137e-02 2.2290e-03 -6.0000e+00 3.3762e-02 6.3268e-06 3.5523e-03 5.1663e-03 2.0032e-05 -6.0000e+00 6.7346e-03 -1.5175e-02 -1.3489e-04 12 8 8 10 0 0 -1.15 15.00 7.72 -0.01517 0.00947 8 1 1 4 0 4000.000 22.09 15.00 19.05 -4569 3396 -585 -1593 -7004 10385 -13186 -3397 -12702 5057 4680 2410 -7341 23354 -6380 3493 5417 726 5253 2550 4487 -8007 -7220 5529 7357 4882 4248 7795 2755 -5617 10538 -3103 2091 -12830 -156 4104 9645 3096 -2549 -4551 4591 3277 -5410 7686 -6327 6121 3215 7628 -2833 11926 -709 17255 -9554 12139 -5127 2744 -16409 1852 3908 -5431 5410 3411 12266 445 -11697 -7271 5555 340 14871 -7522 15248 5763 8798 -21553 15392 770 8277 -6328 12934 -13361 6604 -5591 12261 -10406 -3786 8335 2706 -3808 6416 -578 2549 17686 -2789 -2724 6413 9469 -10290 -3869 -15063 18725 -6856 15405 -1659 3485 -15516 -263 -3515 5532 -3703 -905 8328 7457 16674 2188 5938 -7172 -6011 1112 -1465 846 -320 -14605 10630 15083 21484 4347 8772 -5177 -1791 4824 4214 601 -270 10031 -7867 1304 11169 4882 -6358 1011 -7928 14220 -5462 -1890 4836 -5932 -19032 6302 -6210 7548 -4561 3230 -603 -1716 -8105 10380 -16877 -3975 -16144 5307 4867 2530 -8327 19435 -7068 3543 5509 800 5683 2835 4895 -9856 -8818 6005 7897 5344 4660 8153 2908 -6178 9839 -3346 2215 -16470 -181 4518 9894 3338 -2861 -5176 4791 3497 -6348 8042 -7630 6524 3479 7775 -3131 11049 -717 14294 -10191 10694 -5555 2841 -20738 1958 4013 -6062 5453 3526 11629 470 -13697 -7979 5279 337 12585 -7756 12536 5230 7853 -26284 13141 741 7187 -6228 10472 -13912 5706 -5475 10120 -10818 -3739 7333 2503 -3728 5666 -547 2360 14410 -2801 -2698 5660 7897 -10095 -3469 -14689 12926 -6098 11367 -1519 3180 -17243 -249 -3368 4756 -3474 -840 7202 6589 13584 2058 5393 -7460 -6255 1081 -1439 796 -299 -15408 8824 12163 16319 3901 7543 -5069 -1702 4316 3727 538 -241 8047 -7574 1184 9457 4454 -6560 981 -8426 12262 -5746 -1929 4618 -6206 -21992 5528 -6080 6530 SO 20190712T095818.0Z 7132.415486 290 1 32.01 2 89.10 59.78 125.99 282.83 0.00 1 0.00 1 0 15 4.602e-02 4.570e-02 4.171e-02 4.113e-02 1.358653e+04 2.920946e+03 9.692905e+02 -6.000000e+00 2.423217e+03 286.52 -2.00 20.00 -2.00 505.29 0.00e+00 2.904034e-04 1.116770e-03 5.911398e-05 -6.000000e+00 1.270782e-03 286.52 -2.00 20.00 -2.00 500.16 0.00e+00 5.832448e-01 8.104570e-01 6.235066e-02 -6.000000e+00 8.835138e-01 233.03 -2.00 3.57 -2.00 501.78 0.00e+00 18.767 0.129 489.00 513.00 1 9.4009e+00 6.1933e-02 3.2443e-02 -6.0000e+00 6.7607e-02 1.2394e-01 1.6028e-02 2.4800e-03 -6.0000e+00 1.7830e-02 1.0939e-05 -4.5986e-04 2.9195e-03 8.9972e-05 -6.0000e+00 3.5725e-03 -1.0083e-02 7.1442e-05 12 8 8 10 0 0 -3.14 15.00 7.19 -0.01008 -0.01327 8 1 1 4 0 4000.000 22.19 15.00 19.06 -5485 6735 -1529 552 -8899 471 -697 4788 -4975 -1686 -2211 142 -1610 -4273 -5152 -2641 3190 3952 7100 -4407 167 2107 12356 -3394 4913 2225 2699 -2893 -1403 -6815 -858 7359 7860 1096 2738 -4138 3077 1671 -50 -626 -5847 -13 325 -279 -8164 7186 -2187 3067 681 10687 -5088 -1907 4127 3909 -5864 4105 -9941 2713 1339 1693 -1108 8672 -2049 -6432 1897 976 2256 2489 6864 2827 3291 1828 3193 -38 -388 -2923 6836 1332 7088 -2517 -357 -3997 2088 392 -5057 4364 -1771 -3731 696 6562 -1367 5034 -927 3044 -6212 8569 -2258 6346 -1490 -1099 4808 -5448 -8966 5150 2752 843 756 6277 970 -2341 -1982 -6203 6439 -4164 7739 -8260 6268 -1480 -4867 -2860 -3732 7535 3862 -3047 7556 -1452 651 -4004 5597 -3193 -3220 3838 509 4431 -2152 1941 -7009 1749 -4940 3724 -2396 3478 -7849 9365 4558 2458 261 -2879 -4179 -3931 -5474 6144 -1577 576 -10363 512 -780 5096 -5770 -1856 -2415 149 -1694 -4560 -5530 -2788 3252 4140 7385 -5126 186 2296 12179 -3925 5265 2434 2927 -3263 -1497 -7374 -872 6985 7686 1199 3004 -4802 3276 1779 -53 -668 -6593 -15 353 -308 -9799 7409 -2440 3198 712 9805 -5259 -1868 3793 3684 -6329 4147 -11674 2814 1396 1749 -1184 8479 -2225 -7254 1943 988 2216 2415 6299 2650 3064 1742 3048 -39 -391 -2952 6105 1236 6167 -2396 -335 -3920 1940 376 -5193 4100 -1757 -3737 663 5914 -1345 4743 -930 2866 -6149 7062 -1997 5043 -1253 -907 3785 -4922 -8921 4727 2642 821 722 5573 906 -2297 -1968 -6452 5924 -4234 7000 -8829 5936 -1522 -5102 -2869 -3670 6493 3455 -2954 6618 -1390 610 -3894 4964 -3088 -3042 3306 450 3753 -1968 1758 -7064 1635 -5006 3510 -2410 3323 -8400 8470 4300 2332 247 -2729 -3973 -3764 SO 20190712T100230.0Z 7132.418403 294 1 32.01 2 88.45 60.50 126.70 283.64 0.00 1 0.00 1 0 15 2.738e-02 2.712e-02 2.471e-02 2.439e-02 6.958339e+03 1.609444e+03 3.356767e+02 -6.000000e+00 1.441858e+03 286.52 -2.00 20.00 -2.00 505.27 0.00e+00 1.782172e-03 6.589845e-04 1.188804e-04 -6.000000e+00 7.562113e-04 286.52 -2.00 20.00 -2.00 500.03 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