File name: Pandora103s1_Downsview_20190713_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T042216.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190713_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190713 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190713T095446.0Z 7133.413032 267 1 32.01 2 89.78 59.24 118.78 270.21 0.00 1 0.00 1 0 15 5.186e-02 5.103e-02 5.070e-02 5.016e-02 7.037481e+03 3.259139e+03 7.560295e+02 -6.000000e+00 2.732861e+03 286.61 -2.00 20.00 -2.00 505.33 0.00e+00 4.759973e-03 1.354980e-03 2.419526e-04 -6.000000e+00 1.433028e-03 286.61 -2.00 20.00 -2.00 500.31 0.00e+00 2.369333e+00 9.831756e-01 3.617891e-02 -6.000000e+00 9.976902e-01 233.04 -2.00 3.57 -2.00 501.91 0.00e+00 20.002 0.156 489.00 513.00 1 9.2466e+00 7.5104e-02 3.6162e-02 -6.0000e+00 7.6327e-02 9.1502e-02 1.9532e-02 2.0256e-03 -6.0000e+00 2.0162e-02 8.9214e-06 -1.2619e-03 3.7157e-03 9.0134e-05 -6.0000e+00 4.0318e-03 -3.4170e-02 1.1807e-04 12 8 8 10 0 0 17.71 15.00 1.61 -0.03417 -0.04292 8 1 1 4 0 4000.000 22.09 15.00 19.05 -1461 4886 -8904 3203 -1019 -2829 -254 -66 9021 -50 -195 -10831 3817 -5636 -930 -456 6526 1665 2443 8570 6278 724 530 773 3646 -5205 -4385 697 -7973 -2607 3580 -4022 1839 3762 3985 450 -3290 -999 4234 -4897 -2115 8084 -818 1720 1148 4581 5412 1505 -3563 -5723 256 -10691 9378 -12973 256 6184 5417 -1112 2014 1655 3766 -9076 -2690 3818 7743 184 1997 3757 -4034 -3405 2995 4917 544 -287 2041 -3462 91 4973 -4273 866 674 2980 -530 -6146 7559 -379 -898 7865 3900 2371 848 -3727 -2807 5912 20700 3779 -3567 -639 3297 -9110 3020 -6062 235 2479 363 -6050 7255 -4134 -6115 -4602 7730 -4998 1702 4280 -10097 8363 10088 2694 -415 11799 -10323 -838 -12702 3324 2872 -865 -6649 -4940 50 3489 -1304 4198 8681 7476 -5657 -3200 766 -440 1808 1606 -2158 994 1606 -968 4189 1843 -37 -1175 -3604 -1120 -1365 4411 -9597 3183 -1077 -3106 -277 -73 8964 -53 -204 -12411 3725 -5949 -933 -458 6228 1718 2571 8506 6358 773 567 832 3855 -5989 -4989 747 -8951 -2659 3401 -4153 1848 3893 4223 490 -3654 -1071 4260 -5363 -2270 7963 -891 1857 1259 4866 5645 1606 -3924 -6248 255 -11562 8279 -14484 262 6171 5545 -1216 2122 1739 3893 -10718 -2990 3970 7644 191 2003 3662 -4189 -3446 2826 4583 536 -289 2025 -3552 87 4492 -4187 804 630 2742 -505 -6236 6797 -369 -873 6963 3567 2202 807 -3790 -2877 5518 16304 3414 -3360 -569 2756 -8408 2476 -5554 212 2297 349 -6131 6345 -3960 -5965 -4512 6874 -5111 1649 4067 -11054 7716 9277 2673 -418 10355 -10999 -799 -13641 3103 2705 -846 -6890 -5009 48 3280 -1262 3758 7346 6346 -5482 -3112 734 -432 1758 1580 -2210 990 1600 -992 4075 1810 -36 -1120 -3467 -1061 SO 20190713T095911.0Z 7133.416100 271 1 32.01 2 89.09 60.00 119.55 270.95 0.00 1 0.00 1 0 15 2.453e-02 2.458e-02 2.241e-02 2.227e-02 1.396515e+04 1.555681e+03 8.550907e+02 -6.000000e+00 1.292191e+03 286.61 -2.00 20.00 -2.00 505.38 0.00e+00 2.990940e-03 6.042494e-04 1.397527e-04 -6.000000e+00 6.776390e-04 286.61 -2.00 20.00 -2.00 500.48 0.00e+00 1.578038e+00 4.309481e-01 1.003156e-01 -6.000000e+00 4.713612e-01 233.04 -2.00 3.57 -2.00 502.07 0.00e+00 18.734 0.128 489.00 513.00 1 8.6608e+00 3.2957e-02 3.3096e-02 -6.0000e+00 3.6066e-02 6.3198e-02 8.4463e-03 2.8749e-03 -6.0000e+00 9.5193e-03 2.0621e-05 3.5430e-04 1.6086e-03 8.0380e-05 -6.0000e+00 1.9056e-03 1.2270e-02 -1.1368e-04 12 8 8 10 0 0 -2.51 15.00 2.90 0.01227 0.01473 8 1 1 4 0 4000.000 22.09 15.00 19.06 -3401 -1663 -4129 240 -2659 1124 -2473 1297 -179 -3183 821 -3444 1097 -4189 1009 -902 842 -748 -157 1463 2381 -1969 4946 -1612 1545 5082 4415 -565 1357 308 -5878 998 -2704 5198 -225 1802 1483 967 -1534 405 2919 -1149 546 -696 -3442 4681 101 2244 -3692 210 -2835 995 -2593 175 4384 1045 1554 577 3643 -703 2605 -590 1780 -2362 103 3647 1008 38 -96 1017 1855 -3164 183 -591 -166 -456 -1811 640 -1965 -1293 -1649 -859 102 3354 -7463 2959 -2427 4370 410 5421 -3010 -271 1956 1190 263 1531 -2373 -352 -3577 331 41 -4077 3650 1834 856 -3046 272 -3536 5000 -329 241 -476 1586 462 -3527 3780 3459 -2268 392 2044 691 1811 125 -861 -599 3492 938 1653 332 3169 -2705 -813 -1388 306 -407 1024 703 -417 1776 -3306 -263 -1278 -2662 -283 1606 1492 3285 -5460 -616 -4877 -3156 -1565 -4160 239 -2781 1159 -2684 1362 -189 -3388 830 -3580 1073 -4263 974 -894 838 -783 -168 1532 2471 -2130 5010 -1755 1644 5210 4540 -601 1359 300 -6056 975 -2836 5292 -246 1913 1555 1006 -1616 418 2959 -1227 582 -761 -3898 4895 110 2341 -4001 212 -2856 946 -2544 171 4290 1090 1635 614 3733 -748 2703 -636 1878 -2582 109 3631 1012 38 -95 980 1768 -3194 181 -601 -169 -454 -1774 603 -1883 -1226 -1579 -822 97 3137 -7858 2821 -2422 4038 391 4929 -3005 -270 1915 1147 247 1362 -2119 -301 -3094 271 34 -3644 3213 1736 835 -3072 261 -3459 4511 -319 237 -475 1556 459 -3637 3678 3448 -2409 401 2010 670 1701 120 -845 -589 3309 913 1588 324 3014 -2663 -768 -1310 283 -384 983 690 -418 1772 -3508 -273 -1345 -2851 -297 1644 1507 3180 -5606 -598 -4991 SO 20190713T100313.2Z 7133.418903 275 1 10.45 2 88.46 60.69 120.26 271.62 0.00 1 0.00 1 0 22 1.187e-02 1.168e-02 2.547e-03 2.536e-03 1.965615e+04 1.770348e+02 1.263417e+03 -6.000000e+00 6.254649e+02 286.61 -2.00 20.00 -2.00 505.46 0.00e+00 3.664965e-03 6.915063e-05 2.082367e-04 -6.000000e+00 3.279772e-04 286.61 -2.00 20.00 -2.00 501.04 0.00e+00 1.727173e+00 4.764743e-02 1.270647e-01 -6.000000e+00 2.281844e-01 233.04 -2.00 3.57 -2.00 502.54 0.00e+00 17.171 0.099 489.00 513.00 1 5.8089e+00 3.6385e-03 3.0216e-02 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