File name: Pandora103s1_Downsview_20190726_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T044724.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190726_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190726 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190726T100649.1Z 7146.421401 211 1 32.15 2 89.76 62.80 41.63 128.53 0.00 1 0.00 1 0 19 4.224e-02 4.164e-02 3.660e-02 3.618e-02 3.579262e+03 2.197161e+03 2.348368e+02 -6.000000e+00 2.229148e+03 287.05 -2.00 20.00 -2.00 505.27 0.00e+00 2.599219e-03 9.747832e-04 1.344928e-04 -6.000000e+00 1.168194e-03 287.05 -2.00 20.00 -2.00 500.17 0.00e+00 1.890043e+00 7.074789e-01 3.269545e-02 -6.000000e+00 8.101221e-01 232.66 -2.00 3.57 -2.00 501.79 0.00e+00 19.978 0.155 489.00 513.00 1 8.9905e+00 5.4062e-02 3.5753e-02 -6.0000e+00 6.2011e-02 1.2451e-01 1.4211e-02 2.0418e-03 -6.0000e+00 1.6341e-02 1.2459e-05 -1.1879e-03 2.7504e-03 4.0677e-05 -6.0000e+00 3.2785e-03 -2.3705e-02 1.8356e-04 12 8 8 10 0 0 4.23 15.00 3.22 -0.02371 -0.03194 8 1 1 4 0 4000.000 22.19 15.00 19.11 -5145 -1271 -979 -748 6037 4824 -98 2508 -2864 2510 3536 1911 -5481 2230 -4473 -3458 -3125 -185 -2180 4050 -4134 2433 2936 2402 -547 464 -2740 -6047 5338 1872 -632 9285 6275 -2935 241 2506 -2559 1791 823 -3776 325 -1873 5787 -7251 -419 -2058 -390 -1849 153 3240 -1277 1959 -518 3565 -1934 6229 -876 -2623 3627 8610 -5296 90 -2921 9175 -1235 7717 -7487 -5173 -2048 -1593 -6865 7743 4806 -3137 -2027 1297 3386 -1694 1940 3126 -1300 -5955 9483 -6533 5722 -3024 5393 -1055 4352 -2662 8689 -4458 6902 4138 1608 -1075 -7482 879 1382 -2926 3204 623 7217 2519 -7315 -1110 -2232 5320 -8055 -42 -4424 3738 -6673 -374 2782 256 1192 7580 -38 5044 -1259 6233 -607 111 -7529 -1289 4420 -3188 4388 -7913 -1384 4156 1115 -163 -793 -6697 2874 1402 6160 1952 4580 -5375 -2580 3224 720 2668 963 4217 -6437 -1350 -5123 -1255 -1006 -792 6096 5036 -109 2733 -3255 2650 3645 1973 -5971 2226 -4751 -3661 -3366 -200 -2461 4300 -4746 2617 3144 2605 -614 514 -3118 -7000 5306 1850 -636 8586 6181 -3313 269 2706 -2855 1889 865 -4132 344 -2047 5946 -8570 -467 -2325 -428 -2026 161 3205 -1276 1855 -500 3382 -2015 6180 -945 -2876 3712 8348 -5908 95 -3207 8906 -1307 7327 -8093 -5411 -2049 -1557 -7034 6938 4492 -3223 -2063 1250 3110 -1611 1768 2812 -1232 -5940 8155 -6634 5219 -3008 4920 -1019 3978 -2611 7714 -4597 6458 3936 1534 -1029 -7418 781 1190 -2580 2674 547 6240 2374 -7629 -1074 -2139 4645 -8015 -40 -4421 3504 -6999 -370 2679 254 1185 7055 -37 4637 -1206 5477 -574 106 -7719 -1244 4030 -3111 3991 -8122 -1306 3631 990 -145 -716 -6589 2637 1320 5604 1863 4264 -5534 -2602 3083 704 2516 895 3677 -6159 -1242 SO 20190726T101115.0Z 7146.424479 215 1 32.01 2 89.05 63.56 41.01 129.83 0.00 1 0.00 1 0 15 2.049e-02 2.035e-02 1.516e-02 1.510e-02 4.601255e+03 9.039005e+02 3.308231e+02 -6.000000e+00 1.081279e+03 287.05 -2.00 20.00 -2.00 505.23 0.00e+00 1.808739e-03 4.086665e-04 7.251336e-05 -6.000000e+00 5.667095e-04 287.05 -2.00 20.00 -2.00 500.44 0.00e+00 1.140759e+00 2.921113e-01 2.996291e-02 -6.000000e+00 3.936592e-01 232.66 -2.00 3.57 -2.00 502.00 0.00e+00 18.641 0.126 489.00 513.00 1 8.3355e+00 2.2399e-02 3.1749e-02 -6.0000e+00 3.0124e-02 9.3623e-02 5.8440e-03 1.8624e-03 -6.0000e+00 7.9532e-03 3.0931e-05 1.0760e-04 1.1404e-03 4.2624e-05 -6.0000e+00 1.5920e-03 7.4972e-03 -1.1457e-04 12 8 8 10 0 0 7.46 15.00 9.17 0.00750 0.00824 8 1 1 4 0 4000.000 22.19 15.00 19.12 -3168 -2306 -3603 -1855 -922 178 2547 3758 -964 -392 -877 -1231 -717 -5795 -3010 580 -2907 -287 -460 2869 -1136 69 1814 1542 2592 2812 1938 825 792 -2905 -3214 355 1495 2070 1979 662 -71 -1846 826 -2029 -829 713 963 1694 1206 820 2089 4318 1846 -170 -1602 -1420 -4460 37 1143 -438 681 2384 -914 1079 1842 3927 267 3481 283 1132 -1733 -2406 -775 -2016 -1850 -740 -2482 79 209 -1253 2054 -2973 -1175 -1534 8 -323 1737 -1351 130 -1339 3929 1134 -735 -905 923 4048 1683 2502 1879 -2474 3164 751 -1745 -3770 -3705 -2011 1896 369 1623 -1907 -779 -588 -2579 -833 -945 1908 -1184 4977 2630 2342 2367 1732 1659 -1198 -269 824 -1412 1335 1417 836 -687 -1664 872 -1100 -1317 388 -2487 -5567 -2635 -767 -38 2582 1000 437 -167 1969 -968 426 1144 1024 -3827 166 -3232 -867 -2893 -2153 -3562 -1867 -938 183 2607 3822 -1019 -403 -896 -1245 -709 -5955 -3000 563 -2984 -298 -490 2956 -1217 73 1889 1624 2719 2935 2033 864 796 -2911 -3212 347 1497 2166 2119 711 -76 -1979 851 -2142 -871 746 1019 1806 1304 889 2212 4403 1892 -172 -1590 -1376 -4428 36 1147 -461 722 2486 -978 1128 1923 4052 287 3606 298 1160 -1798 -2489 -779 -2015 -1839 -735 -2548 80 214 -1274 1967 -2951 -1139 -1492 7 -316 1673 -1359 131 -1372 3810 1126 -743 -919 931 4052 1750 2554 1886 -2532 2980 705 -1639 -3550 -3508 -1928 1841 350 1535 -1846 -731 -541 -2417 -783 -908 1809 -1170 4652 2523 2272 2323 1711 1614 -1176 -256 765 -1350 1259 1339 795 -664 -1612 827 -1068 -1257 356 -2315 -5299 -2456 -723 -37 2448 977 433 -167 1937 -989 431 1147 1012 -3855 156 -3100 -821 SO 20190726T101529.0Z 7146.427419 219 1 32.01 2 88.37 64.28 40.43 131.10 0.00 1 0.00 1 0 22 1.990e-02 1.959e-02 7.875e-03 7.853e-03 5.200394e+03 4.734142e+02 3.468343e+02 -6.000000e+00 1.049944e+03 287.05 -2.00 20.00 -2.00 505.33 0.00e+00 2.352749e-03 2.130139e-04 1.082100e-04 -6.000000e+00 5.503505e-04 287.05 -2.00 20.00 -2.00 500.74 0.00e+00 1.325429e+00 1.488864e-01 4.166236e-02 -6.000000e+00 3.819958e-01 232.66 -2.00 3.57 -2.00 502.26 0.00e+00 16.927 0.094 489.00 513.00 1 7.8652e+00 1.1418e-02 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