File name: Pandora103s1_Downsview_20190730_L2Fit_fwvt1c9d20181123p1-8.txt File generation date: 20241101T044736.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v9d20190627.txt Level 1 file used: Pandora103s1_Downsview_20190730_L1_smca1c9d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190730 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1621 1770 Nominal wavelengths inside fitting window [nm]: 492.1189 492.2400 492.3612 492.4823 492.6035 492.7246 492.8457 492.9668 493.0878 493.2089 493.3299 493.4509 493.5719 493.6929 493.8139 493.9348 494.0557 494.1767 494.2975 494.4184 494.5393 494.6601 494.7810 494.9018 495.0226 495.1433 495.2641 495.3848 495.5056 495.6263 495.7470 495.8676 495.9883 496.1089 496.2296 496.3502 496.4708 496.5913 496.7119 496.8324 496.9530 497.0735 497.1940 497.3144 497.4349 497.5553 497.6757 497.7961 497.9165 498.0369 498.1572 498.2776 498.3979 498.5182 498.6385 498.7588 498.8790 498.9992 499.1195 499.2396 499.3598 499.4800 499.6001 499.7203 499.8404 499.9605 500.0806 500.2006 500.3207 500.4407 500.5607 500.6807 500.8007 500.9206 501.0406 501.1605 501.2804 501.4003 501.5202 501.6400 501.7599 501.8797 501.9995 502.1193 502.2391 502.3588 502.4785 502.5983 502.7180 502.8377 502.9573 503.0770 503.1966 503.3162 503.4358 503.5554 503.6750 503.7945 503.9140 504.0335 504.1530 504.2725 504.3920 504.5114 504.6308 504.7503 504.8696 504.9890 505.1084 505.2277 505.3470 505.4663 505.5856 505.7049 505.8242 505.9434 506.0626 506.1818 506.3010 506.4202 506.5393 506.6584 506.7776 506.8967 507.0157 507.1348 507.2538 507.3729 507.4919 507.6109 507.7298 507.8488 507.9677 508.0867 508.2056 508.3245 508.4433 508.5622 508.6810 508.7998 508.9186 509.0374 509.1562 509.2749 509.3937 509.5124 509.6311 509.7498 509.8684 509.9871 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190730T101103.0Z 7150.424340 302 1 32.01 2 89.74 64.17 71.14 77.52 0.00 1 0.00 1 0 71 1.005e+00 4.954e-01 6.345e-01 4.194e-01 2.287830e+04 3.098872e+04 1.265895e+02 -6.000000e+00 5.413267e+04 287.12 -2.00 20.00 -2.00 505.35 0.00e+00 -1.342892e-02 1.136082e-02 9.035193e-04 -6.000000e+00 2.872074e-02 287.12 -2.00 20.00 -2.00 500.26 0.00e+00 -5.764875e+00 8.063041e+00 3.342086e-01 -6.000000e+00 2.004992e+01 232.51 -2.00 3.57 -2.00 501.95 0.00e+00 19.949 0.155 489.00 513.00 1 1.2183e+01 6.0579e-01 4.7302e-02 -6.0000e+00 1.5444e+00 2.2854e-01 1.5858e-01 5.5421e-03 -6.0000e+00 4.0243e-01 8.2271e-07 -7.3121e-03 2.7706e-02 2.5700e-04 -6.0000e+00 7.9705e-02 -1.7447e-01 1.7387e-03 12 8 8 10 0 0 4.35 15.00 14.62 -0.17447 -0.22519 8 1 1 4 0 4000.000 22.19 15.00 19.16 -31459 46282 -50948 571 36224 -23602 177464 4830 -8574 -6308 103316 38694 200835 -2356 252901 66597 44530 -4197 -24895 33748 14216 -38819 30358 29941 64784 124227 8520 28368 19625 -1149 -36952 228320 -20211 90349 231231 18714 5838 169928 114355 116140 -20605 45271 26314 119844 8820 86842 -29043 1971 88767 33923 -18198 -30938 170097 -19571 90848 -36341 58889 41395 5656 -27728 262919 -27465 900000 4912 224168 14639 101433 43138 26479 77330 89779 505656 24760 20083 -28132 89773 21380 -26895 44459 146809 -26461 179615 -1871 104715 100106 66532 -47454 172652 -40629 202879 248539 20383 72752 21353 4880 -30555 52227 -20628 238904 34602 41076 226646 102505 3204 900000 -11792 -6776 7336 107033 7768 37608 -15038 -43821 70485 900000 73041 900000 42458 67148 -17041 97942 2405 -27670 6486 131210 -12648 3667 22128 1643 101193 -22293 91181 -17630 276336 -2548 900000 14068 11047 -48741 85065 1 14559 -12044 10932 8049 19486 138416 -36669 30958 900000 -45250 33115 -93882 663 30689 -35814 72867 5748 -11496 -8175 48255 32351 82463 -2813 103842 42573 35984 -5556 -40929 32087 16258 -72832 29589 29267 45519 51008 9923 26931 19402 -1342 -60598 93749 -29935 49876 94944 19966 6923 69773 48043 47687 -29661 35251 24511 49208 9697 45953 -44387 2214 43593 26595 -22417 -42025 69842 -24655 42801 -57103 38389 31577 5956 -39754 107955 -39766 900000 5228 92044 13778 42473 30678 21733 39396 41144 207623 21500 18590 -40730 42557 18594 -36317 30738 60280 -36137 73750 -2104 45325 46161 42067 -86992 70891 -69443 83303 102051 20041 43033 19286 4859 -40279 30957 -23792 98094 23920 27819 93061 46104 3853 900000 -16675 -8932 8268 47845 8733 31863 -20474 -76805 41879 900000 43199 900000 34304 42359 -22721 43357 2506 -38247 6540 53875 -15102 3728 18716 1682 41550 -27331 38679 -20435 113464 -2651 900000 13021 10658 -84055 42862 1 14272 -15085 10978 8240 17681 56834 -54101 24188 900000 SO 20190730T101523.0Z 7150.427350 306 1 32.01 2 89.04 64.92 70.41 78.18 0.00 1 0.00 1 0 46 4.870e-01 2.963e-01 3.750e-01 2.789e-01 -6.528899e+02 1.692916e+04 1.147975e+03 -6.000000e+00 2.565913e+04 287.12 -2.00 20.00 -2.00 505.48 0.00e+00 1.118210e-02 7.886901e-03 2.555240e-04 -6.000000e+00 1.346496e-02 287.12 -2.00 20.00 -2.00 500.30 0.00e+00 -2.740382e-02 5.762212e+00 3.181396e-01 -6.000000e+00 9.406930e+00 232.51 -2.00 3.57 -2.00 502.01 0.00e+00 18.611 0.126 489.00 513.00 1 1.1242e+01 4.4245e-01 3.9644e-02 -6.0000e+00 7.1878e-01 1.4099e-01 1.1227e-01 4.4682e-03 -6.0000e+00 1.9164e-01 1.4166e-06 9.4307e-03 2.1278e-02 1.7145e-04 -6.0000e+00 3.7934e-02 5.4236e-01 -3.8748e-03 12 9 8 11 256 0 61.06 15.00 8.57 0.54236 0.60778 8 1 1 4 0 4000.000 22.19 15.00 19.16 35085 -4830 -26958 -25543 -1807 -10028 100881 -24639 -3594 -31223 12088 14728 -19456 10780 29108 18488 25531 11095 32419 46624 -13333 40257 2142 36085 -764 37922 -21967 33932 -465 19642 29779 113482 17516 66997 -24572 -20413 -23611 22103 -21648 57334 48282 -4753 -26191 11125 32209 11104 25939 -13932 -13933 18723 49270 -32589 75506 32898 99502 10949 41495 23774 38517 46850 81555 -23482 26060 -11369 81071 -23152 3878 21828 56505 7187 58083 36339 41070 -7295 43879 -10593 4113 194611 4150 20458 -39074 26785 59034 150754 55578 36215 -34932 61475 733 196178 -24242 -8669 94947 71035 10740 34024 27050 34998 86522 26043 27786 -11810 -22074 -17636 106276 15441 10728 15791 95255 19164 36331 31084 93474 6120 -21238 -14914 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233 32113 5020 31114 4596 24864 6376 20542 2597 29745 -630 -64750 11366 15552 43225 -594 -3044 25822 -2651 7872 SO 20190730T101940.0Z 7150.430324 310 1 32.01 2 88.34 65.65 69.67 78.84 0.00 1 0.00 1 0 15 2.385e-01 1.986e-01 2.287e-01 2.031e-01 1.313757e+04 1.471517e+04 1.701596e+02 -6.000000e+00 1.258030e+04 287.12 -2.00 20.00 -2.00 505.11 0.00e+00 -3.798220e-03 5.414678e-03 1.443555e-04 -6.000000e+00 6.599278e-03 287.12 -2.00 20.00 -2.00 499.63 0.00e+00 3.753985e+00 4.121855e+00 2.429487e-01 -6.000000e+00 4.597104e+00 232.51 -2.00 3.57 -2.00 501.26 0.00e+00 16.851 0.093 489.00 513.00 1 1.1116e+01 3.1555e-01 3.2791e-02 -6.0000e+00 3.5154e-01 9.0801e-02 8.2295e-02 4.2637e-03 -6.0000e+00 9.3237e-02 2.0436e-06 -1.0145e-02 1.4737e-02 6.1979e-05 -6.0000e+00 1.8587e-02 3.1316e-02 -5.0865e-04 12 8 8 10 0 0 2.15 15.00 21.99 0.03132 -0.03906 8 1 1 4 0 4000.000 22.19 15.00 19.16 -391 14825 10333 -19778 10920 -3435 36999 8719 30137 31168 35098 -19763 13999 15295 16507 2473 3633 -25305 25260 5829 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