File name: Pandora103s1_Downsview_20190804_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T044722.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190804_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190804 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190804T101621.0Z 7155.428021 347 1 32.01 2 89.74 66.02 125.96 33.79 0.00 1 0.00 1 0 28 7.915e-02 7.787e-02 7.175e-02 7.010e-02 6.489444e+03 4.621345e+03 4.474964e+02 -6.000000e+00 4.179429e+03 287.22 -2.00 20.00 -2.00 505.20 0.00e+00 4.346208e-03 1.897255e-03 3.000456e-04 -6.000000e+00 2.194268e-03 287.22 -2.00 20.00 -2.00 499.88 0.00e+00 1.269670e+00 1.408552e+00 4.918161e-02 -6.000000e+00 1.531538e+00 232.32 -2.00 3.57 -2.00 501.53 0.00e+00 19.949 0.155 489.00 513.00 1 9.7281e+00 1.0771e-01 3.6268e-02 -6.0000e+00 1.1705e-01 1.6396e-01 2.8288e-02 2.1183e-03 -6.0000e+00 3.1151e-02 6.0471e-06 2.9978e-03 5.2488e-03 8.3878e-05 -6.0000e+00 6.1764e-03 -5.6021e-02 4.0545e-04 12 8 8 10 0 0 -12.45 15.00 7.28 -0.05602 -0.03523 8 1 1 4 0 4000.000 22.29 15.00 19.30 -5765 6180 -9599 4601 17688 10361 -15989 5290 1460 6140 6372 -3781 659 9161 3600 -9106 -443 -12962 1203 -10245 1896 813 -887 -3567 -503 5554 476 -16621 2674 -3698 16149 -2484 13292 3405 -470 6326 -2117 8715 -2848 11329 17968 3204 2012 3423 -2288 9129 -164 -5412 -2725 14380 -7857 -2781 -16811 3891 4808 -2136 12592 11314 -10515 -3629 1104 3893 -1875 6116 -4912 -2078 -72 193 16499 787 5545 -6940 6344 -5071 691 -2594 7771 2990 -6393 -6259 2889 1404 12476 -850 -10555 2421 -9822 11038 14521 2170 -15320 1395 1659 16150 -10136 338 9797 -541 -4878 8058 543 3511 -1720 -4527 -7961 -1465 3968 2945 9462 2638 4070 -1266 -1247 12780 3867 -8827 3864 215 1824 -8790 762 -4464 13244 5119 -1962 -1798 -911 12307 -5844 -3258 4569 3290 -17119 -7077 683 14959 -8111 10158 -5316 11301 3232 8561 -1507 17603 -6468 1842 -3180 14621 -10539 -12349 -5941 5753 -10787 4701 16323 10446 -21270 5785 1653 6536 6620 -4277 702 8822 3621 -10357 -467 -15832 1321 -12743 2085 903 -999 -4135 -571 5965 535 -21914 2852 -4002 14000 -2583 12069 3549 -529 6712 -2400 8755 -3158 10831 16128 3349 2157 3669 -2626 9418 -184 -6310 -3044 13278 -8691 -2843 -19356 3681 4652 -2299 12041 11044 -12647 -4049 1174 4060 -2078 6260 -5545 -2240 -75 196 14163 773 5118 -7241 5872 -5323 696 -2670 7035 2767 -6414 -6229 2630 1308 10463 -814 -11250 2291 -10433 9500 11984 2014 -16915 1331 1614 13693 -10868 318 8190 -485 -4446 6314 452 2876 -1536 -4374 -8198 -1413 3573 2621 7803 2349 3655 -1218 -1215 10943 3618 -9369 3666 213 1765 -9246 714 -4309 10672 4518 -1871 -1710 -860 10181 -5737 -3135 4044 2871 -17853 -6623 589 11452 -7982 8500 -5220 9548 2965 7462 -1455 14165 -6570 1711 -3028 11328 -10169 -12105 SO 20190804T102043.0Z 7155.431053 351 1 32.01 2 89.02 66.77 125.55 34.96 0.00 1 0.00 1 0 29 5.688e-02 5.471e-02 5.562e-02 5.440e-02 6.076444e+03 3.567423e+03 6.188100e+02 -6.000000e+00 3.003446e+03 287.22 -2.00 20.00 -2.00 505.18 0.00e+00 3.421482e-03 1.471651e-03 7.915656e-05 -6.000000e+00 1.577203e-03 287.22 -2.00 20.00 -2.00 499.72 0.00e+00 1.433394e+00 1.087808e+00 1.881774e-02 -6.000000e+00 1.101945e+00 232.32 -2.00 3.57 -2.00 501.38 0.00e+00 18.574 0.125 489.00 513.00 1 9.6662e+00 8.3063e-02 3.1483e-02 -6.0000e+00 8.4191e-02 1.6673e-01 2.1977e-02 1.8691e-03 -6.0000e+00 2.2451e-02 7.8440e-06 1.0005e-02 4.0690e-03 6.2067e-05 -6.0000e+00 4.4380e-03 6.9761e-04 -5.7321e-05 12 8 8 10 0 0 -6.14 15.00 2.36 0.00070 0.07009 8 1 1 4 0 4000.000 22.29 15.00 19.30 -1808 -5866 4199 -2628 -44 -5625 5451 -6331 1564 43 -2080 -3124 7153 -27 3277 7405 -3083 -467 -2885 5576 7618 11658 -4145 1378 6707 -476 -993 4865 2935 -188 1361 -2970 2357 -4058 -2878 -2546 4082 -412 -2985 -12268 11831 -7486 443 2174 -3352 -2246 -1633 -683 -407 -2377 878 -1120 -1578 -2599 4465 -2367 2552 4360 -6258 -7518 3960 5766 6113 6825 10010 -4788 -4852 3840 -6548 6758 -2498 -241 1449 2093 3741 2802 138 5735 54 -4348 8143 -4940 -4530 -3170 13591 806 1991 -8928 1569 592 679 6295 15981 1882 10027 -5885 2333 -7312 2565 19182 2604 -11641 9550 3707 245 -2650 998 -3236 -6498 1492 -6374 -490 -14268 -6368 2469 -2521 10145 6879 8780 -4575 -12349 5522 -3063 3849 4538 4948 8344 2029 20 2971 5804 -11363 -8187 -2483 -8479 32 -630 -2912 4756 4917 561 1590 2363 2264 -1585 -916 292 -2798 10155 -768 -1827 -6302 4252 -2956 -49 -6770 6005 -7877 1790 49 -2371 -3551 7222 -28 3354 7303 -3413 -518 -3374 6040 8046 11838 -4896 1550 7219 -549 -1145 5249 3119 -197 1377 -3152 2434 -4675 -3376 -2966 4383 -455 -3334 -14865 11386 -8770 487 2381 -3914 -2595 -1859 -759 -443 -2559 883 -1118 -1562 -2634 4378 -2571 2694 4534 -7174 -8657 4081 5886 6233 6880 9663 -5227 -5192 3725 -6945 6174 -2469 -234 1400 2044 3622 2693 133 5098 51 -4201 6994 -4856 -4439 -3086 11389 768 1866 -9228 1455 554 638 5715 13444 1805 8673 -5783 2057 -6876 2134 13269 2106 -11021 7683 3316 231 -2552 910 -3007 -6185 1334 -6282 -463 -15573 -6470 2303 -2479 8926 6271 7757 -4505 -12831 4725 -2842 3384 3982 4318 7049 1811 18 2634 4933 -11107 -7632 -2167 -7840 28 -567 -2712 4155 4332 516 1451 2152 2069 -1501 -851 261 -2491 7816 -660 SO 20190804T102500.0Z 7155.434028 355 1 32.01 2 88.31 67.50 125.13 36.10 0.00 1 0.00 1 0 22 4.286e-02 4.171e-02 4.368e-02 4.276e-02 7.202039e+03 2.903989e+03 3.110955e+02 -6.000000e+00 2.263773e+03 287.22 -2.00 20.00 -2.00 505.22 0.00e+00 1.478913e-04 1.162206e-03 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