File name: Pandora103s1_Downsview_20190806_L2Fit_fwvt1c10d20181123p1-8.txt File generation date: 20241101T044702.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c10p1-8 Local principal investigator: Vitoli Fiolitov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 103 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora103_OF_v6d20171016.txt Instrument calibration file used: Pandora103s1_CF_v10d20190801.txt Level 1 file used: Pandora103s1_Downsview_20190806_L1_smca1c10d20181123p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20190806 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: FieldAna 3rd VP - WinterReference but for LabData 2017 but L7 from 2023 First and last pixel inside fitting window: 1620 1769 Nominal wavelengths inside fitting window [nm]: 492.0103 492.1315 492.2527 492.3739 492.4950 492.6162 492.7373 492.8584 492.9795 493.1006 493.2216 493.3426 493.4637 493.5847 493.7057 493.8266 493.9476 494.0685 494.1894 494.3103 494.4312 494.5521 494.6730 494.7938 494.9146 495.0354 495.1562 495.2770 495.3977 495.5185 495.6392 495.7599 495.8806 496.0012 496.1219 496.2425 496.3631 496.4837 496.6043 496.7249 496.8454 496.9660 497.0865 497.2070 497.3275 497.4480 497.5684 497.6888 497.8093 497.9297 498.0500 498.1704 498.2907 498.4111 498.5314 498.6517 498.7720 498.8922 499.0125 499.1327 499.2529 499.3731 499.4933 499.6135 499.7336 499.8537 499.9739 500.0940 500.2140 500.3341 500.4541 500.5742 500.6942 500.8142 500.9341 501.0541 501.1740 501.2940 501.4139 501.5338 501.6536 501.7735 501.8933 502.0132 502.1330 502.2528 502.3725 502.4923 502.6120 502.7318 502.8515 502.9711 503.0908 503.2105 503.3301 503.4497 503.5693 503.6889 503.8085 503.9280 504.0476 504.1671 504.2866 504.4061 504.5255 504.6450 504.7644 504.8838 505.0032 505.1226 505.2420 505.3613 505.4807 505.6000 505.7193 505.8385 505.9578 506.0770 506.1963 506.3155 506.4347 506.5539 506.6730 506.7922 506.9113 507.0304 507.1495 507.2685 507.3876 507.5066 507.6257 507.7447 507.8637 507.9826 508.1016 508.2205 508.3394 508.4583 508.5772 508.6961 508.8149 508.9338 509.0526 509.1714 509.2902 509.4089 509.5277 509.6464 509.7651 509.8838 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20190806T101832.0Z 7157.429537 351 1 32.00 2 89.74 66.80 142.31 4.75 0.00 1 0.00 1 0 22 2.329e-02 2.293e-02 2.231e-02 2.214e-02 8.651391e+03 1.480033e+03 7.160889e+02 -6.000000e+00 1.229897e+03 287.26 -2.00 20.00 -2.00 505.31 0.00e+00 3.354007e-03 6.003268e-04 1.741829e-04 -6.000000e+00 6.461621e-04 287.26 -2.00 20.00 -2.00 500.26 0.00e+00 2.319004e+00 4.361907e-01 3.853654e-02 -6.000000e+00 4.525764e-01 232.24 -2.00 3.57 -2.00 501.86 0.00e+00 19.944 0.155 489.00 513.00 1 8.4786e+00 3.3289e-02 3.5801e-02 -6.0000e+00 3.4547e-02 9.0940e-02 8.7486e-03 2.2111e-03 -6.0000e+00 9.2706e-03 1.9885e-05 -5.0830e-04 1.6493e-03 7.8514e-05 -6.0000e+00 1.8204e-03 -3.3311e-03 -8.3500e-05 12 8 8 10 0 0 -12.63 15.00 2.93 -0.00333 -0.00686 8 1 1 4 0 4000.000 22.19 15.00 19.16 900000 -3375 -1560 1401 -2148 -310 1020 3122 -1167 -44 -1268 -1136 1 868 -2545 3736 -4921 -1932 -1185 1521 3928 1462 3665 2025 -2256 1680 -1888 -792 672 615 2356 -835 2307 102 826 -2560 -1004 -1617 -903 1178 -973 2606 1149 -731 1621 3982 2361 -236 -2198 472 -859 509 -757 -5282 -2213 -431 -163 -835 1870 573 -265 1402 -450 335 1960 763 -1478 -1727 419 834 -361 1716 -1923 807 -449 -2840 995 872 2454 -3917 -1554 1898 -291 198 -2279 -1123 2046 4417 822 -166 933 3484 -3670 5237 486 4393 3591 3449 -2911 -2287 -1253 -962 -5347 2570 -1221 -1291 -580 -1351 -3699 -1611 -800 2301 474 1495 -1895 -1137 -619 1181 3877 -685 727 -2467 2171 -2149 2281 1873 3755 -3824 929 783 420 -2539 -71 -4321 1412 -1208 2290 -244 328 241 3010 2508 7748 -1413 -429 1482 -6874 -1091 -4757 2541 900000 -3209 -1501 1369 -2244 -324 1077 3284 -1285 -48 -1355 -1196 1 869 -2601 3584 -5171 -2012 -1267 1622 4090 1557 3818 2146 -2513 1815 -2105 -871 718 631 2286 -831 2253 106 887 -2900 -1109 -1768 -969 1223 -1027 2676 1211 -795 1750 4235 2550 -258 -2414 495 -885 500 -737 -5347 -2224 -444 -172 -902 1970 607 -282 1473 -485 359 2054 797 -1545 -1778 418 817 -351 1630 -1907 790 -453 -2933 969 826 2255 -3800 -1468 1746 -275 187 -2228 -1099 1944 4077 779 -158 879 3238 -3738 4948 473 3996 3193 2979 -2606 -1986 -1058 -815 -4868 2284 -1181 -1267 -560 -1289 -3545 -1515 -762 2169 461 1449 -1904 -1136 -621 1183 3794 -690 708 -2422 2002 -2078 2143 1773 3495 -3834 884 748 404 -2462 -65 -4123 1266 -1123 2120 -236 320 238 2929 2461 7260 -1455 -438 1482 -7342 -1070 -4703 2318 SO 20190806T102255.1Z 7157.432582 355 1 32.20 2 89.01 67.56 142.25 6.44 0.00 1 0.00 1 0 29 2.260e-02 2.199e-02 2.929e-03 2.910e-03 1.007569e+04 1.880301e+02 6.203422e+02 -6.000000e+00 1.193360e+03 287.26 -2.00 20.00 -2.00 505.51 0.00e+00 4.698371e-03 8.010805e-05 2.240339e-04 -6.000000e+00 6.265771e-04 287.26 -2.00 20.00 -2.00 501.06 0.00e+00 1.426877e+00 5.471504e-02 8.856304e-02 -6.000000e+00 4.376589e-01 232.24 -2.00 3.57 -2.00 502.60 0.00e+00 18.549 0.124 489.00 513.00 1 6.5119e+00 4.1697e-03 3.2639e-02 -6.0000e+00 3.3440e-02 -2.2502e-02 1.0806e-03 2.5297e-03 -6.0000e+00 8.9152e-03 1.8110e-04 9.5621e-04 2.1529e-04 8.7135e-05 -6.0000e+00 1.7632e-03 1.4396e-02 -1.2403e-04 12 8 8 10 0 0 -17.84 15.00 10.51 0.01440 0.02103 8 1 1 4 0 4000.000 22.19 15.00 19.17 -8261 -7181 -5445 -2906 -856 -586 705 1684 1835 1253 102 -836 -1603 -2636 -2806 -3276 -2559 -415 825 1550 1204 2003 1779 1227 1888 2674 2110 1779 943 -2104 -3463 -3477 -2750 339 2278 3018 1883 1613 1179 121 -437 913 1263 2725 3020 3339 3423 2343 1620 375 -1026 -2159 -3647 -3312 -1570 744 1772 2017 2181 1749 1977 2798 2876 2682 2324 1805 83 -154 -596 -1322 -2170 -1891 -1632 -701 233 -421 -875 -2014 -2804 -2364 -2788 -1791 -1363 -1220 -670 -330 -472 -454 -161 -302 282 936 1868 3088 2789 2317 1304 35 -1618 -3548 -4315 -3885 -2151 924 1554 1132 -141 -1854 -2059 -1699 -191 393 1461 2591 3044 3348 3214 3631 2436 1337 232 128 -296 928 1205 1325 1639 -13 192 642 520 -1120 -1795 -2792 -3790 -2729 -1190 -219 796 919 376 49 696 781 1348 518 365 -2734 -4671 -4963 -7129 -6221 -4811 -2625 -783 -547 666 1600 1748 1187 96 -784 -1495 -2445 -2585 -3033 -2380 -387 789 1503 1171 1933 1726 1203 1863 2641 2094 1769 930 -2047 -3306 -3324 -2657 332 2297 3070 1917 1626 1182 121 -442 924 1295 2804 3155 3220 3297 2259 1553 357 -1047 -2163 -3647 -3308 -1592 707 1721 1983 2143 1718 1939 2750 2854 2677 2319 1785 82 -150 -580 -1278 -2084 -1813 -1579 -685 230 -417 -852 -1936 -2688 -2246 -2661 -1709 -1305 -1173 -651 -324 -465 -445 -156 -293 273 915 1859 3066 2726 2207 1218 32 -1477 -3231 -3906 -3545 -2003 886 1552 1149 -144 -1890 -2075 -1723 -195 409 1530 2708 3182 3506 3424 3925 2673 1462 251 135 -312 975 1283 1416 1757 -14 209 700 567 -1216 -1924 -3003 -4108 -2978 -1321 -246 896 1052 404 53 755 852 1466 567 393 -2955 -5023 -5336 SO 20190806T102703.4Z 7157.435456 359 1 32.86 2 88.32 68.27 142.17 8.04 0.00 1 0.00 1 0 22 1.501e-02 1.470e-02 7.547e-04 7.496e-04 1.551274e+04 5.005155e+01 1.004850e+03 -6.000000e+00 7.928434e+02 287.26 -2.00 20.00 -2.00 505.46 0.00e+00 4.854828e-03 2.059675e-05 2.585449e-04 -6.000000e+00 4.165040e-04 287.26 -2.00 20.00 -2.00 501.18 0.00e+00 1.375410e+00 1.412374e-02 1.097765e-01 -6.000000e+00 2.916681e-01 232.24 -2.00 3.57 -2.00 502.64 0.00e+00 16.806 0.092 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